Multi-layer electrode structure, and method of manufacturing same
View Patent ↗A multi-layer electrode structure is provided comprised of a plurality of electrode layers composed of a binder and an electrode material and coated on a current-collecting member, each of the electrode layers including a macromolecular substance wherein a first electrode layer in contact with the current-collecting member and the second electrode layer in contact with the first electrode layer are formed of different constituents or have different proportions of the same constituent. A method of forming the multi-layer electrode structures as well as a battery and double-layer capacitor formed from the multi-layer electrode structures are also disclosed.
1. A multi layer electrode structure comprising a plurality of electrode layers at least comprised of a binder made of a macromolecular substance and an electrode material and coated on a current-collecting material, wherein:
a first electrode layer in contact with said current-collecting material and a second electrode layer in contact with said first electrode layer are formed of different constituents or have different proportions of the same constituent;
said first electrode layer is thinner than said second electrode layer; and
said first electrode layer has a stronger adhesive strength than said second electrode layer relative to said current-collecting material, thereby attaining effective adhesive properties and low electrical resistance of said first electrode layer;
said binder of said first-electrode layer comprises an ion-conducting polymer; and
said binder of said second electrode layer comprises a polymer prone to form fibrils.
2. A multi-layer electrode structure according to claim 1 , wherein at least said electrode layers further include a powdered electrically-conducting substance.
3. The multilayer electrode structure according to claim 1 , wherein said electrode material is coated with an ion-conducting polymer.
4. The multi-layer electrode structure according to claim 1 , wherein the percentage by weight of binder used in said first electrode layer is greater than the percentage by weight of binder used in said second electrode layer.
5. A multi-layer electrode structure according to claim 1 , wherein at least one of said electrode layers further includes a powdered electrically-conducting substance.
6. The multi-layer electrode structure according to claim 1 , wherein said ion conducting polymer is a polymer which can dissolve at least lithium salt at a concentration of at least 0.1M (moles/l), said polymer containing the lithium salt at a concentration of at least 0.1M having an electrical conductivity of 10 −8 S (siemens)/cm at room temperature.