IP Library Granted Patent US 7,122,069
Granted Patent B2
US 7,122,069 · App. 09/804,876 · Granted Oct 17, 2006

Mo-Cu composite powder

Assignee: Osram Sylvania Inc.
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Quick Facts
Patent No.
US 7,122,069
App. No.
09/804,876
Granted
Oct 17, 2006
Kind
B2
Abstract

A Mo—Cu composite powder is provided which is comprised of individual finite particles each having a copper phase and a molybdenum phase wherein the molybdenum phase substantially encapsulates the copper phase. The composite powder may be consolidated by conventional P/M techniques and sintered without copper bleedout according to the method described herein to produce Mo—Cu pseudoalloy articles having very good shape retention, a high sintered density, and a fine microstructure.

Claims (13)

1. A molybdenum-copper composite powder comprising individual finite particles each having a copper phase and a molybdenum phase, the individual finite particles further having a sintered molybdenum network wherein the voids in the network are filled with copper and the molybdenum phase substantially encapsulates the copper phase.

2. The composite powder of claim 1 wherein the individual particles have a size of about 0.5 μm to about 1.5 μm.

3. The composite powder of claim 2 wherein the composite powder comprises agglomerates of the finite particles.

4. The composite powder of claim 3 wherein the agglomerates have a size of about 15 μm to about 25 μm.

5. The composite powder of claim 1 wherein the powder contains from about 2 wt. % to about 40 wt. % copper.

6. The composite powder of claim 1 , wherein the powder has the color of unalloyed molybdenum powder.

7. A method of making a Mo—Cu composite powder comprising:

(a) reducing a CuMoO 4 -based composite oxide powder in a first stage to form an intimate mixture of metallic copper and molybdenum oxides without the formation of low-melting-point cuprous molybdate phases; and

(b) reducing the intimate mixture in a second stage at a temperature and for a time sufficient to reduce the molybdenum oxides to molybdenum metal.

8. The method of claim 7 wherein the first stage reduction is performed at a temperature from about 250° C. to about 400° C.

9. The method of claim 8 wherein the second stage reduction is performed at a temperature from about 700° C. to about 950° C.

10. The method of claim 7 wherein the low-melting-point cuprous molybdate phases are Cu 6 Mo 4 O 15 and Cu 2 Mo 3 O 10 .

11. The method of claim 7 wherein the Mo—Cu composite powder is passivated in nitrogen after the second stage reduction.

Assignments (4)
MERGER Recorded Oct 31, 2008
From: GLOBAL TUNGSTEN, LLC
To: GLOBAL TUNGSTEN & POWDERS CORP.
Reel/Frame 021763/0241 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 29, 2008
From: OSRAM SYLVANIA INC.
To: GLOBAL TUNGSTEN & POWDERS CORP.
Reel/Frame 021744/0744 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 28, 2008
From: OSRAM SYLVANIA, INC.
To: GLOBAL TUNGSTEN, LLC
Reel/Frame 021744/0231 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 21, 2001
From: DORFMAN, LEONID P.; SCHEITHAUER, MICHAEL J.; HOUCK, DAVID L.; SPITSBERG, ANNA T.; DANN, JEFFREY N.
To: OSRAM SYLVANIA INC.
Reel/Frame 011838/0489 →
Continuity (2)
Provisional Application 6019302300 · Mar 29, 2000
Related Publication 20020005086A1 · Jan 17, 2002