Metallocene compound, olefin polymerization catalyst containing the compound, and method for producing an olefin polymer by use of the catalyst
The present invention provides a metallocene compound which produces an olefin polymer having a high molecular weight with a high stereoregularity. The metallocene compound has the following formula (1): Q(C 5 H 4-m R 1 m )(C 5 H 4-n R 2 n )MXY (1) wherein (C 5 H 4-m R 1 m ) and (C 5 H 4-n R 2 n ) each independently represent a cyclopentadienyl group; C 5 H 4-m and C 5 H 4-n each independently represent a cyclopentadienyl ring; m represents an integer of 1-3; n represents an integer of 2 or 3; R 1 and R 2 are each independently a substituent bonded respectively to C 5 H 4-m and C 5 H 4-n , and represent a hydrocarbon group of 1-20 carbon atoms, a silicon-containing hydrocarbon group of 1-20 carbon atoms or a heteroaromatic group; each R 1 m and each R 2 n may be the same or different; one pair of R 2 's in the R 2 n are bonded to each other to form at least one ring; Q represents a divalent group for cross-linking (C 5 H 4-m R 1 m ) and (C 5 H 4-n R 2 n ); M represents a titanium atom, a zirconium atom or a hafnium atom; and X and Y are the same or different and each a hydrogen atom, a halogen atom or a hydrocarbon group.
1. A metallocene compound selected from the group consisting of dimethylsilylene bis(2-(2-(5-methyl)-furyl)-indenyl) zirconium dichloride, dimethylsilylene bis(2-(2-(5-t-butyl)-furyl)-indenyl) zirconium dichloride, dimethylsilylene bis(2-(2-(5-trimethylsilyl)-furyl)-indenyl zirconium dichloride, dimethylsilylene bis(2-(2-(5-phenyl)-furyl)-indenyl) zirconium dichloride, dimethylsilylene bis(2-(2-(5-methyl)-thienyl)-indenyl) zirconium dichloride, dimethylsilylene bis-(2-(2-(5-t-butyl)-thienyl)-indenyl) zirconium dichloride, dimethylsilylene bis(2-(2-(5-trimethylsilyl)-thienyl)-indenyl) zirconium dichloride, dimethylsilylene bis(2-(2-(5-phenyl)-thienyl)-indenyl) zirconium dichloride, dimethylsilylene bis(2-(2-(5-methyl)-furyl)-4-phenyl)-indenyl) zirconium dichloride, dimethylsilylene bis(2-(2-(5-t-butyl)-furyl)-4-phenyl)-indenyl) zirconium dichloride, dimethylsilylene bis(2-(2-(5-trimethylsilyl)-furyl)-4-phenyl)-indenyl) zirconium dichloride, dimethylsilylene bis(2-(2-(5-phenyl)-furyl)-4-phenyl)-indenyl) zirconium dichloride, dimethylsilylene bis(2-(2-(5-methyl)-thienyl)-4-phenyl)-indenyl), zirconium dichloride, dimethylsilylene bis(2-(2-(5-t-butyl)-thienyl)-4-phenyl)-indenyl) zirconium dichloride, dimethylsilylene bis(2-(2-(5-trimethylsilyl)-thienyl)-4-phenyl)-indenyl) zirconium dichloride, dimethylsilylene bis(2-(2-(5-phenyl)-thienyl)-4-phenyl)-indenyl) zirconium dichloride, dimethylsilylene bis(2-(2-(5-methyl)-furyl)-4,5-benzoindenyl) zirconium dichloride, dimethylsilylene bis(2-(2-(5-t-butyl)-furyl)-4,5-benzoindenyl) zirconium dichloride, dimethylsilylene bis(2-(2-(5-trimethylsilyl)-furyl)-4,5-benzoindenyl) zirconium dichloride, dimethylsilylene bis(2-(2-(5-phenyl)-furyl)-4,5-benzoindenyl) zirconium dichloride, dimethylsilylene bis(2-(2-(5-methyl)-thienyl)-4,5-benzoindenyl) zirconium dichloride, dimethylsilylene bis(2-(2-(5-t-butyl)-thienyl)-4,5-benzoindenyl) zirconium dichloride, dimethylsilylene bis(2-(2-(5-trimethylsilyl)-thienyl)-4,5-benzoindenyl) zirconium dichloride, dimethylsilylene bis(2-(2-(5-phenyl)-thienyl)-4,5-benzoindenyl) zirconium dichloride, dimethylsilylene bis(2-(2-(5-methyl)-furyl)-4-phenyl-dihydroazulenyl) zirconium dichloride, dimethylsilylene bis(2-(2-(5-t-butyl)-furyl)-4-phenyl-dihydroazulenyl) zirconium dichloride, dimethylsilylene bis(2-(2-(5-trimethylsilyl)furyl)-4-phenyl-dihydroazulenyl) zirconium dichloride, dimethylsilylene bis(2-(2-(5-phenyl)-furyl)-4-phenyl-dihydroazulenyl) zirconium dichloride, dimethylsilylene bis(2-(2-(5-methyl)-thienyl)-4-phenyl-dihydroazulenyl) zirconium dichloride, dimethylsilylene bis(2-(2-(5-t-butyl)-thienyl)-4-phenyl-dihydroazulenyl) zirconium dichloride, dimethylsilylene bis(2-(2-(5-trimethylsilyl)-thienyl)-4-phenyl-dihydroazulenyl) zirconium dichloride and dimethylsilylene bis(2-(2-(5-phenyl)-thienyl)-4-phenyl-dihydroazulenyl) zirconium dichloride.
2. The metallocene compound according to claim 1 , which is selected from the group consisting of dimethylsilylene bis(2-(2-(5-methyl)-furyl)-indenyl) zirconium dichloride, dimethylsilylene bis(2-(2-(5-t-butyl)-furyl)-indenyl) zirconium dichloride, dimethylsilylene bis(2-(2-(5-trimethylsilyl)-furyl)-indenyl zirconium dichloride, and dimethylsilylene bis(2-(2-(5-phenyl)-furyl)-indenyl) zirconium dichloride.
3. The metallocene compound according to claim 1 , which is selected from the group consisting of dimethylsilylene bis(2-(2-(5-methyl)-thienyl)-indenyl) zirconium dichloride, dimethylsilylene bis-(2-(2-(5-t-butyl)-thienyl)-indenyl) zirconium dichloride, dimethylsilylene bis(2-(2-(5-trimethylsilyl)-thienyl)-indenyl) zirconium dichloride, and dimethylsilylene bis-(2-(2-(5-phenyl)-thienyl)-indenyl) zirconium dichloride.
4. The metallocene compound according to claim 1 , which is selected from the group consisting of dimethylsilylene bis(2-(2-(5-methyl)-furyl)-4-phenyl-indenyl) zirconium dichloride, dimethylsilylene bis(2-(2-(5-t-butyl)-furyl)-4-phenyl-indenyl) zirconium dichloride, dimethylsilylene bis(2-(2-(5-trimethylsilyl)-furyl)-4-phenyl-indenyl) zirconium dichloride, and dimethylsilylene bis(2-(2-(5-phenyl)-furyl)-4-phenyl-indenyl) zirconium dichloride.
5. The metallocene compound according to claim 1 , which is selected from the group consisting of dimethylsilylene bis(2-(2-(5-methyl)-thienyl)-4-phenyl-indenyl), zirconium dichloride, dimethylsilylene bis(2-(2-(5-t-butyl)-thienyl)-4-phenyl-indenyl) zirconium dichloride, dimethylsilylene bis(2-(2-(5-trimethylsilyl)-thienyl)-4-phenyl-indenyl) zirconium dichloride, and dimethylsilylene bis(2-(2-(5-phenyl)-thienyl)-4-phenyl-indenyl) zirconium dichloride.
6. The metallocene compound according to claim 1 , which is selected from the group consisting of, dimethylsilylene bis(2-(2-(5-methyl)-furyl)-4,5-benzoindenyl) zirconium dichloride, dimethylsilylene bis(2-(2-(5-t-butyl)-furyl)-4,5-benzoindenyl) zirconium dichloride, dimethylsilylene bis(2-(2-(5-trimethylsilyl)-furyl)-4,5-benzoindenyl) zirconium dichloride, and dimethylsilylene bis(2-(2-(5-phenyl)-furyl)-4,5-benzoindenyl) zirconium dichloride.
7. The metallocene compound according to claim 1 , which is selected from the group consisting of dimethylsilylene bis(2-(2-(5-methyl)-thienyl)-4,5-benzoindenyl) zirconium dichloride, dimethylsilylene bis(2-(2-(5-t-butyl)-thienyl)-4,5-benzoindenyl) zirconium dichloride, dimethylsilylene bis(2-(2-(5-trimethylsilyl)-thienyl)-4,5-benzoindenyl) zirconium dichloride, and dimethylsilylene bis(2-(2-(5-phenyl)-thienyl)-4,5-benzoindenyl) zirconium dichloride.
8. The metallocene compound according to claim 1 , which is selected from the group consisting of dimethylsilylene bis(2-(2-(5-methyl)-furyl)-4-phenyl-dihydroazulenyl) zirconium dichloride, dimethylsilylene bis(2-(2-(5-t-butyl)-furyl)-4-phenyl-dihydroazulenyl) zirconium dichloride, dimethylsilylene bis(2-(2-(5-trimethylsilyl)furyl)-4-phenyl-dihydroazulenyl) zirconium dichloride, and dimethylsilylene bis(2-(2-(5-phenyl)-furyl)-4-phenyl-dihydroazulenyl) zirconium dichloride.
9. The metallocene compound according to claim 1 , which is selected from the group consisting of dimethylsilylene bis(2-(2-(5-methyl)-thienyl)-4-phenyl-dihydroazulenyl) zirconium dichloride, dimethylsilylene bis(2-(2-(5-t-butyl)-thienyl)-4-phenyl-dihydroazulenyl) zirconium dichloride, dimethylsilylene bis(2-(2-(5-trimethylsilyl)-thienyl)-4-phenyl-dihydroazulenyl) zirconium dichloride, and dimethylsilylene bis(2-(2-(5-phenyl)-thienyl)-4-phenyl-dihydroazulenyl) zirconium dichloride.