Magnetic recording medium with Cr underfilm
View Patent ↗A magnetic recording medium was a high normalized coercive force and superior thermal stability. The magnetic recording medium comprises a non-magnetic base material, and a ferromagnetic metal layer of cobalt based alloy formed on top of this base material with a metal underlayer disposed therebetween, and displays a coercive force Hc of at least 2000 (Oe) and an anisotropic magnetic field Hk grain of at least 10,000 (Oe). Furthermore, magnetic recording media in which the aforementioned metal underlayer and/or the ferromagnetic metal layer are fabricated in a film fabrication chamber with an ultimate vacuum at the 10 −9 Torr level are preferred. A magnetic recording medium according to the present invention can be ideally applied to hard disks, floppy disks, and magnetic tapes and the like.
1. A magnetic recording medium comprising:
a non-magnetic base material;
a ferromagnetic metal layer of a CoCrPtB alloy formed on top of said non-magnetic base material; and
a metal underlayer disposed between said base material and said ferromagnetic metal layer, wherein,
a coercive force Hc is at least 2000 (Oe),
an anisotropic magnetic field Hk grain is at least 10,000(Oe), and
said metal underlayer incorporates an underfilm of either one of Cr and a Cr alloy comprising Mo and/or W,
wherein a lattice misfit of said metal underlayer and said ferromagnetic metal layer, as determined by an equation (y−x)/(x/2+y/2)·100(%), in which x represents a length obtained by multiplying by square root of 2 a lattice constant of said metal underlayer and y represents a c axis length of a crystal lattice of said ferromagnetic metal layer, is a value from 0.5% to 2.5%, and
an axial length ratio a/b of an interatomic distance a in a direction of a normal line to said ferromagnetic metal layer relative to an interatomic distance b in a direction within a plane of said ferromagnetic metal layer is within a range from 1.002 to 1.008.
2. A magnetic recording medium according to claim 1 , wherein said metal underlayer incorporates an underfilm of either one of i) Cr and ii) a Cr alloy comprising Mo and/or W, and at least one element selected from a group consisting of V, Nb, Hf, Zr, Ti, Mn, Ta, Ru, Re, Os, Ir, Rh, Pd, Pt, P, B, Si, Ge, N and O.
3. A magnetic recording medium according to claim 1 , wherein a film thickness of said metal underlayer is within a range from 3 nm to 20 nm.
4. A magnetic recording medium according to claim 1 , wherein said lattice misfit of said metal underlayer and said ferromagnetic metal layer is a value from 0.5% to 1.5%.
5. A magnetic recording medium according to claim 1 , wherein said metal underlayer comprises a layered structure of two or more underfilms with different lattice constants.
6. A magnetic recording medium according to claim 5 , wherein said metal underlayer is a two layered construction with a second underfilm layered on top of a first underfilm, and a film thickness ratio t 2 /t 1 of a film thickness t 1 of said first underfilm and a film thickness t 2 of said second underfilm is within a range from 0.2 to 5.0.
7. A magnetic recording medium according to claim 6 , wherein a film thickness of said first underfilm is within a range from 1.5 nm to 8.5 nm.
8. A magnetic recording medium according to claim 6 , wherein a film thickness of said second underfilm is within a range from 1.5 nm to 8.5 nm.
9. A magnetic recording medium according to claim 1 , wherein said metal underlayer and said ferromagnetic metal layer are formed in a film fabrication chamber with an ultimate vacuum at a 10 −9 Torr level, using a film fabrication gas with an impurity concentration of no more than 1 ppb.
10. A magnetic recording medium according to claim 9 , wherein said metal underlayer comprises a layered structure of two or more underfilms with different lattice constants.
11. A magnetic recording device comprising a magnetic recording medium according to claim 1 , a drive section for driving said magnetic recording medium, and a magnetic head for carrying out recording and playback of magnetic information, wherein said magnetic head performs recording and playback of magnetic information on a moving said magnetic recording medium.
12. A magnetic recording device according to claim 11 , wherein said metal underlayer comprises a layered structure of two or more underfilms with different lattice constants.
13. A magnetic recording medium, comprising:
a non-magnetic base material;
a metal underlayer formed on top of said non-magnetic base material and incorporating an underfilm of either one of Cr and a Cr alloy incorporating Mo or W; and
a ferromagnetic metal layer of a CoCrPtB alloy formed on top of said non-magnetic base material and said metal underlayer so that said metal underlayer is disposed between said base material and said ferromagnetic metal layer, wherein,
at a same time, a coercive force Hc is at least 2000 (Oe), and an anisotropic magnetic field Hk grain is at least 10,000 (Oe),
a lattice misfit of said metal underlayer and said ferromagnetic metal layer, as determined by an equation (y−x)/(x/2+y/2)·100(%), in which x represents a length obtained by multiplying by square root of 2 a lattice constant of said metal underlayer and y represents a c axis length of a crystal lattice of said ferromagnetic metal layer, is a value from 0.5% to 2.5%, and
an axial length ratio a/b of an interatomic distance a in a direction of a normal line to said ferromagnetic metal layer relative to an interatomic distance b in a direction within a plane of said ferromagnetic metal layer is within a range from 1.002 to 1.008.
14. The magnetic recording medium of claim 13 , wherein, said underfilm comprises the Cr alloy incorporating Mo.
15. The magnetic recording medium of claim 13 , wherein, said underfilm comprises the Cr alloy incorporating W.
16. The magnetic recording medium of claim 13 , wherein, said underfilm comprises the Cr alloy incorporating Mo and W.