IP Library Granted Patent US 7,030,060
Granted Patent B1
US 7,030,060 · App. 10/031,225 · Granted Apr 18, 2006

Rest-breaking composition and use thereof

Assignee: Akzo Nobel N.V.
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Quick Facts
Patent No.
US 7,030,060
App. No.
10/031,225
Granted
Apr 18, 2006
Kind
B1
Abstract

The invention relates to a composition useful for the breaking of rest in deciduous fruit species such as apple species and grape species comprising an organic nitrogen-containing compound having a molecular weight of 60 to 300 with the exception of urea and dinitro-ortho-cresol, an inorganic nitrate rest-breaking agent, and a surfactant. Preferably, the organic nitrogen-containing compound is a choline salt such as choline chloride, the inorganic nitrate rest-breaking agent is selected from the group consisting of potassium nitrate, calcium nitrate, ammonium nitrate, calcium ammonium nitrate, urea ammonium nitrate, zinc ammonium nitrate, and mixtures thereof, and the surfactant is an alkoxylated amine such as Armoblen ®*, and Berol®* compound or an alkoxylated quaternary ammonium compound.

Claims (17)

1. A composition useful for the breaking of rest in deciduous fruit species comprising an organic nitrogen-containing compound selected from the group consisting of ethylenediamine, (C 1 –C 3 )alkylated ethylenediamines, (carboxymethyl)tri-(C 1 –C 3 )-alkylammonium salts, (2-hydroxyethyl)tri(C 1 –C 3 )alkylammonium or choline salts, (2-hydroxypropyl)tri(C 1 –C 3 )alkylammonium salts, (2-hydroxybutyl)tri(C 1 –C 3 )alkylammonium salts, and mixtures thereof, an inorganic nitrate rest-breaking agent, and a surfactant.

2. The composition of claim 1 wherein the organic nitrogen-containing compound is selected from the group consisting of (2-hydroxyethyl)tri(C 1 –C 3 )alkylammonium salts, (2-hydroxypropyl)tri(C 1 –C 3 )alkylammonium salts, and (2-hydroxybutyl)tri(C 1 –C 3 )-alkylammonium salts, and mixtures thereof.

3. The composition of claim 2 wherein the organic nitrogen-containing compound is a (2-hydroxyethyl)trimethylammonium or choline salt.

4. The composition of claim 3 wherein the organic nitrogen-containing compound is choline chloride.

5. The composition of claim 1 wherein the inorganic nitrate rest-breaking agent is selected from the group consisting of potassium nitrate, calcium nitrate, ammonium nitrate, calcium ammonium nitrate, urea ammonium nitrate, zinc ammonium nitrate, and mixtures thereof.

6. The composition of claim 5 , wherein the inorganic nitrate rest-breaking agent is selected from the group consisting of calcium nitrate, calcium ammonium nitrate, urea ammonium nitrate, and mixtures thereof.

7. The composition of claim 1 wherein the surfactant is an alkoxylated amine or alkoxylated quaternary ammonium compound.

8. The composition of claim 7 wherein the surfactant is an alkoxylated amine.

9. A method for breaking the rest in deciduous fruit species which comprises applying to said species a rest breaking composition of claim 1 .

10. The method of claim 9 wherein the deciduous fruit species is selected from the group consisting of apple species and grape species.

11. The method of claim 9 wherein the organic nitrogen-containing compound is selected from the group consisting of (2-hydroxyethyl)tri(C 1 –C 3 )alkylammonium or choline salts, (2-hydroxypropyl)tri(C 1 –C 3 )alkylammonium salts, and (2-hydroxybutyl)tri(C 1 –C 3 )-alkylammonium salts, and mixtures thereof.

12. The method of claim 9 wherein the organic nitrogen-containing compound is a (2-hydroxyethyl)trimethylammonium or choline salt.

13. The method of claim 12 wherein the organic nitrogen-containing compound is choline chloride.

14. The method of claim 9 wherein the inorganic nitrate rest-breaking agent is selected from the group consisting of potassium nitrate, calcium nitrate, ammonium, calcium ammonium nitrate, urea ammonium nitrate, zinc ammonium nitrate, and mixtures thereof.

15. The method of claim 14 wherein the inorganic nitrate rest-breaking agent is selected from the group consisting of calcium nitrate, calcium ammonium nitrate, urea ammonium nitrate, and mixtures thereof.

16. The method of claim 9 wherein the surfactant is an alkoxylated amine or alkoxylated quaternary ammonium compound.

17. The method of claim 16 wherein the surfactant is an alkoxylated amine.

Assignments (6)
TERMINATION AND RELEASE OF SECURITY INTEREST IN PATENTS Recorded Jun 29, 2018
From: BANK OF AMERICA, N.A., AS ADMINISTRATIVE AGENT
To: BALCHEM CORPORATION
Reel/Frame 046464/0737 →
SECURITY INTEREST Recorded Jun 27, 2018
From: BALCHEM CORPORATION
To: JPMORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 046221/0207 →
NOTICE OF GRANT OF SECURITY INTEREST IN PATENTS Recorded May 8, 2014
From: BALCHEM CORPORATION
To: BANK OF AMERICA, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 032854/0635 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 4, 2008
From: BALCHEM ITALIA S.R.L.
To: BALCHEM CORPORATION
Reel/Frame 020594/0973 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 7, 2007
From: AKZO NOBEL CHEMICALS N.V.
To: BALCHEM ITALIA S.R.L.
Reel/Frame 019817/0945 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 18, 2002
From: MCDONALD, BRIAN P.; WORKEL, HENNIE A.
To: AKZO NOBEL N.V.
Reel/Frame 012709/0106 →
Priority Claims (1)
EP 99202342 · Jul 16, 1999 · regional