Clear, polymeric gel composition and method for producing the same
Disclosed is a clear, crosslinked, polymeric gel composition that is the reaction product of a microemulsion containing (a) from 1-70 wt. %, preferably from 1-40 wt. %, and more preferably from 10-25 wt. % of an anhydride functionalized polymer, (b) from 0.1-40 wt. %, preferably from 0.1-20 wt. %, and most preferably from 0.5-5 wt. % of a cross-linking agent, (c) from 0.01-50 wt. %, preferably from 0.1-20 wt. %, and more preferably from 0.5-10 wt. % surfactant, (d) from 0.01-30 wt. %, preferably from 0.1-10 wt. %, and more preferably from 0.1-5 wt. % water, and (e) from 10.0-95.0 wt. % of a hydrophobic liquid, based on the total weight of the polymeric gel composition. The gel composition is prepared by combining the anhydride functionalized polymer, the cross-linking agent, the surfactant, the water, and the hydrophobic liquid-form a microemulsion and then gelling the microemulsion.
1. A crosslinkcd, polymeric gel composition comprising the reaction product of a microemulsion containing:
(a) from 1-70 wt. % of an anhydride functionalized polymer;
(b) from 0:140 wt. % of a cross-linking agent;
(c) from 0.01-50% wt. % surfactant;
(d) from 0.01-30 wt. % water and
(e) from 10-95 wt. % of a hydrophobic liquid, based on the total weight of the polymeric gel composition;
wherein said composition is substantially clear.
2. The polymeric gel composition of claim 1 wherein the anhydride functionalized polymer is present in an amount from 1-40 wt. %, the cross-linking agent is present in an amount from 0.1-20 wt. %, the surfactant is present in an amount from 0.1-20 wt. %, and the water is present in an amount from 0.1-10 wt. %.
3. The polymeric gel composition of claim 1 wherein the anhydride functionalized polymer is present in an amount from 10-25 wt. %, the cross-linking agent is present in an amount from 0.5-5 wt %, the surfactant is present in an amount from 0.5-10 wt. %, and the water is present in an amount from 0.1-5 wt %.
4. The polymeric gel composition of claim 1 wherein the combined proportion of (d) and (c) equals at least 30 wt. %, based on the total weight of the polymeric gel composition.
5. The polymeric gel composition of claim 1 wherein the anhydride functionalized polymer is a maleinized polybutadiene polymer, a maleinized polyisoprene polymer, a maleinized polybutadiene/styrene polymer or a mixture thereof.
6. The polymeric gel composition of claim 1 wherein the cross-linking agent is water soluble.
7. The polymeric gel composition of claim 1 wherein the cross-linking agent is a polyamine compound.
8. The polymeric gel composition of claim 1 wherein the surfactant is an anionic or a nonionic surfactant.
9. The polymeric gel composition of claim 1 wherein the microemulsion further comprises a water soluble colorant, a water soluble dye, a water soluble pH color indicator or a water soluble pigment.
10. The polymeric gel composition of claim 1 wherein the microemulsion further comprises a water soluble fragrance or flavor material.
11. A clear, crosslinked, polymeric gel composition comprising the reaction product of a microemulsion containing:
(a) from 140 wt. % of an anhydride functionalized polymer selected from maleinized polybutadiene polymers, maleinized polyisoprene polymers, maleinized polybutadiene/styrene polymers or mixtures thereof;
(b) from 0.1-20 wt. % of a polyamine cross-linking agent;
(c) from 0.1-20% wt % anionic or cationic surfactant;
(d) from 0.1-10 wt. % water, and
(e) from 10—95 wt. % of a hydrophobic liquid perfume, a hydrophobic liquid insecticide or a hydrophobic liquid insect repellant, based on the total weight of the polymeric gel composition, with the combined proportion of (d) and (e) equaling at least 30 wt. %, based on the total weight of the polymeric gel composition.
12. The method of claim 11 wherein the anhydride functionalized polymer is present in an amount from 10-25 wt. %, the cross-linking agent is present in an amount from 0.5-5 wt. %, the surfactant is present in an amount from 0.5-10 wt. %, and the water is present in an amount from 0.1-5 wt. %.