Reduction of N2O emissions
View Patent ↗A method for the selective catalyst reduction of nitrous oxide (N 2 O) in the presence of a solid catalyst, with the addition of a saturated hydrocarbon as reducing agent. The catalyst used is a promoted, iron-containing zeolite. As a result, it is possible to increase the conversion of (N 2 O) compared to unpromoted iron-containing zeolite catalysts. The promoted catalyst is active at temperatures below 350° C. Furthermore, it has been found that the iron-containing zeolite catalysts which are promoted with precious metal also give low emissions of CO and residual hydrocarbons. The catalyst is also very active under high process pressures and in the presence of sulphur.
1. Method for the selective catalytic reduction of nitrous oxide (N 2 O) in the presence of a solid catalyst, with the addition of a saturated hydrocarbon as a reducing agent, wherein the catalyst used is an iron-containing zeolite promoted with at least one precious metal selected from the group consisting of ruthenium, rhodium, palladium and gold; the catalyst thereby comprising a zeolite which contains at least one combination of metals selected from the group consisting of iron and ruthenium, iron and rhodium, iron and palladium and iron and gold, for the catalytic reduction of nitrous oxide.
2. The method according to claim 1 , wherein the catalyst is promoted with a combination of two or more precious metals selected from the group consisting of ruthenium, rhodium, palladium and gold.
3. The method according to claim 1 , wherein the reducing agent used is natural gas or methane (CH 4 ) or propane (C 3 H 8 ) or LPG (C 3 H 8 /C 4 H 10 ).
4. The method according to claim 3 , wherein a combination of reducing agents is used.
5. The method according to claim 1 , wherein the concentration of the reducing agent is set in such a way that the hydrocarbon/N 2 O molar ratio is in the range from 0.2 to 20.
6. The method according to claim 5 , wherein the molar ratio of hydrocarbon to N 2 O ranges from 0.5 to 5.
7. The method according to claim 1 , wherein the reduction takes place at an inlet temperature of less than 400° C.
8. The method according to claim 1 , wherein the reduction results in an emission of carbon monoxide (CO) and of hydrocarbon, which is in each case separately less than 100 ppmv.
9. The method according to claim 1 , wherein the reduction takes place at a pressure between 1 and 50 bar absolute.
10. Method for the selective catalytic reduction of nitrous oxide (N 2 O) from an industrial gas stream containing N 2 O, O 2 , H 2 O, NO x and optionally sulfur, which comprises:
providing a catalyst comprising an iron-containing zeolite promoted with at least one precious metal selected from the group consisting of ruthenium, rhodium, palladium and gold; the catalyst thereby comprising a zeolite which contains at least one combination of metals selected from the group consisting of iron and ruthenium, iron and rhodium, iron and palladium and iron and gold; and
contacting the gas stream with the catalyst in the presence of a saturated hydrocarbon as a reducing agent for the catalytic reduction of nitrous oxide.
11. The method according to claim 10 , wherein the catalyst is promoted with a combination of two or more precious metals selected from the group consisting of ruthenium, rhodium, palladium and gold.
12. The method according to claim 10 , wherein the reduction agent used is natural gas or methane (CH 4 ) or propane (C 3 H 8 ) or LPG (C 3 H 8 /C 4 /H 10 ).
13. The method according to claim 12 , wherein a combination of reducing agents is used.
14. The method according to claim 10 , wherein the concentration of the reducing agent is set in such a way that the hydrocarbon/N 2 O molar ratio is in the range from 0.2 to 20.
15. The method according to claim 14 , wherein the molar ratio of hydrocarbon to N 2 O ranges from 0.5 to 5.
16. The method according to claim 10 , wherein the reduction takes place at an inlet temperatures of less than 400° C.
17. The method according to claim 10 , wherein the reduction results in an emission of carbon monoxide (CO) and of hydrocarbon, which is in each case separately less than 100 ppmv.
18. The method according to claim 10 , wherein the reduction takes place at a pressure between 1 and 50 bar absolute.