Planar optical waveguide assembly and method of preparing same
View Patent ↗A method of preparing a planar optical waveguide assembly, comprising the steps of: (i) applying a silicone composition to a surface of a substrate to form a silicone film; (ii) exposing at least one selected region of the silicone film to radiation having a wavelength of from 150 to 800 nm to produce a partially exposed film having at least one exposed region and at least one non-exposed region; (iii) removing the non-exposed region of the partially exposed film with a developing solvent to form a patterned film; and (iv) heating the patterned film for an amount of time sufficient to form at least one silicone core having a refractive index of from 1.3 to 1.7 at 23° C. for light having a wavelength of 589 nm; wherein the substrate has a refractive index less than the refractive index of the silicone core. A planar optical waveguide assembly prepared according to the method of the invention.
1. A planar optical waveguide assembly prepared by a method comprising the steps of:
(i) applying a silicone composition to a surface of a substrate to form a silicone film, wherein the silicone composition comprises;
(A) an organopolysiloxane containing an average of at least two silicon-bonded alkenyl groups per molecule,
(B) an organosilicon compound containing an average of at least two silicon-bonded hydrogen atoms per molecule in a concentration sufficient to cure the composition, and
(C) a catalytic amount of a photoactivated hydrosilylation catalyst;
(ii) exposing at least one selected region of the silicone film to radiation having a wavelength of from 150 to 800 nm to produce a partially exposed film having at least one exposed region and at least one non-exposed region;
(iii) removing the non-exposed region of the partially exposed film with a developing solvent to form a patterned film; and
(iv) heating the patterned film for an amount of time sufficient to form at least one silicone core having a refractive index of from 1.3 to 1.7 at 23° C. for light having a wavelength of 589 nm; wherein the substrate has a refractive index less than the refractive index of the silicone core.
2. The planar optical waveguide assembly according to claim 1 , wherein the organopolysiloxane is an organopolysiloxane resin.
3. The planar optical waveguide assembly according to the method of claim 1 , wherein the method further comprises (v) covering the substrate and the silicone core with a curable polymer composition to form a polymer film and (vi) curing the polymer film to form a clad layer, wherein the clad layer has a refractive index less than the refractive index of the silicone core.
4. A planar optical waveguide assembly, prepared by a method comprising the steps of:
(i) applying a silicone composition to a surface of a substrate to form a silicone film, wherein the silicone composition comprises;
(A) an organopolysiloxane containing an average of at least two silicon-bonded alkenyl groups per molecule.
(B) an organosilicon compound containing an average of at least two silicon-bonded hydrogen atoms per molecule in a concentration sufficient to cure the composition, and
(C) a catalytic amount of a photoactivated hydrosilylation catalyst;
(ii) exposing at least one selected region of the silicone film to radiation having a wavelength of from 150 to 800 nm to produce a partially exposed film having at least one exposed region and at least one non-exposed region;
(iii) heating the partially exposed film for an amount of time such that the exposed region is substantially insoluble in a developing solvent and the non-exposed region is soluble in the developing solvent;
(iv) removing the non-exposed region of the heated film with the developing solvent to form a patterned film; and
(v) heating the patterned film for an amount of time sufficient to form at least one silicone core having a refractive index of from 1.3 to 1.7 at 23° C. for light having a wavelength of 589 nm; wherein the substrate has a refractive index less than the refractive index of the silicone core.
5. The planar optical waveguide assembly according to claim 4 , wherein the organopolysiloxane is an organopolysiloxane resin.
6. The planar optical waveguide assembly according to claim 4 , wherein the method further comprises (vi) covering the substrate and the silicone core with a curable polymer composition to form a polymer film and (vii) curing the polymer film to form a clad layer, wherein the clad layer has a refractive index less than the refractive index of the silicone core.