Copper alloy foil
View Patent ↗For a three-layer flexible board, there is provided a copper alloy foil that requires no roughening processing, that has good adhesion with an adhesive containing an epoxy resin, that can be laminated to form a copper-clad laminate, that has a low surface roughness, and that has high conductivity and strength. The copper alloy of the foil contains at least one of 0.01-2.0 weight percent Cr and 0.01-1.0 weight percent Zr or contains 1.0-4.8 weight percent Ni and 0.2-1.4 weight percent Si. Good adhesion of the copper alloy foil to a resin substrate with an adhesive containing an epoxy resin is obtained by setting the thickness of the anticorrosive coating to less than 3 nm; the surface roughness of the copper alloy foil is below 2 μm expressed as ten-point average surface roughness (Rz); and, without roughening processing, the 180° C. peel strength, after adhesion of the copper alloy foil to the board film by means of an adhesive containing an epoxy resin, is greater than 8.0 N/cm.
1. Copper alloy foil for lamination with a resin substrate, the copper alloy foil consisting of at least one of 0.01-2.0 weight percent Cr and 0.01-1.0 weight percent Zr, a balance to total 100 weight percent being copper and unavoidable impurities, said copper alloy foil having an anticorrosive coating of thickness less than 3 nm, said copper alloy foil having a surface exhibiting no artificial roughening and having a surface roughness less than 2 μm, expressed as ten-point average surface roughness, tensile strength at least 620 N/mm 2 and conductivity at least 64% IACS, and 180° peel strength between the copper alloy foil and an adhesive containing an epoxy resin bonding the copper alloy foil to a resin substrate is at least 8.9 N/cm.
2. Copper alloy foil according to claim 1 , wherein said anticorrosive coating consists essentially of at least one nitrogen-containing organic compound which forms a chelate with said copper.
3. Copper alloy foil according to claim 2 , wherein said organic compound is selected from the group consisting of benzotriazole and imidazole.
4. Copper alloy foil according to 1 , wherein said resin of said resin foil is a polyimide.
5. A laminate consisting essentially of a copper alloy foil according to claim 1 , and a resin substrate laminated thereon.
6. A laminate consisting essentially of the laminate according to claim 5 , and a resin-containing adhesive, bonding said copper alloy foil to said resin substrate.
7. The laminate of claim 6 , wherein said resin of said resin-containing adhesive consists essentially of an epoxy.
8. Copper alloy foil for lamination with a resin substrate, the copper alloy foil consisting of 0.01-2.0 weight percent Cr and 0.01-1.0 weight percent Zr, a balance to total 100 weight percent being copper and unavoidable impurities, said copper alloy foil having an anticorrosive coating of thickness less than 3 nm, said copper alloy foil having a surface exhibiting no artificial roughening and having a surface roughness less than 2 μm, expressed as ten-point average surface roughness, tensile strength at least 620 N/mm 2 and conductivity at least 64% IACS, and 180° peel strength between the copper alloy foil and an adhesive containing an epoxy resin bonding the copper alloy foil to a resin substrate is at least 8.9 N/cm.
9. Copper alloy foil according to claim 8 , wherein said anticorrosive coating consists essentially of at least one nitrogen-containing organic compound which forms a chelate with said copper.
10. Copper alloy foil according to claim 9 , wherein said organic compound is selected from the group consisting of benzotriazole and imidazole.
11. Copper alloy foil according to claim 8 , wherein said resin of said resin foil is a polyimide.
12. A laminate consisting essentially of a copper alloy foil according to claim 8 , laminated with a resin substrate.
13. A laminate consisting essentially of the copper alloy foil according to claim 8 , a resin substrate laminated thereto, and a resin-containing adhesive, bonding said copper alloy foil to said resin substrate.
14. The laminate of claim 13 , wherein said resin of said resin-containing adhesive consists essentially of an epoxy.
15. Copper alloy foil for lamination with a resin substrate, the copper alloy foil consisting of 0.01-2.0 weight percent Cr, with a balance to total 100 weight percent being copper and unavoidable impurities, said copper alloy foil having an anticorrosive coating of thickness less than 3 nm, said copper alloy foil having a surface exhibiting no artificial roughening and having a surface roughness less than 2 μm, expressed as ten-point average surface roughness, tensile strength at least 620 N/mm 2 and conductivity at least 64% IACS, and 180° peel strength between the copper alloy foil and an adhesive containing an epoxy resin bonding the copper alloy foil to a resin substrate is at least 8.9 N/cm.
16. Copper alloy foil according to claim 15 , wherein said anticorrosive coating consists essentially of at least one nitrogen-containing organic compound which forms a chelate with said copper.
17. Copper alloy foil according to claim 16 , wherein said organic compound is selected from the group consisting of benzotriazole and imidazole.
18. Copper alloy foil according to claim 15 , wherein said resin of said resin foil is a polyimide.
19. A laminate consisting essentially of a copper alloy foil according to claim 15 , laminated with a resin substrate.
20. A laminate consisting essentially of the copper alloy foil according to claim 15 , a resin substrate laminated thereto, and a resin-containing adhesive, bonding said copper alloy foil to said resin substrate.
21. The laminate of claim 20 , wherein said resin of said resin-containing adhesive consists essentially of an epoxy.
22. Copper alloy foil for lamination with a resin substrate, the copper alloy foil consisting of 0.01-1.0 weight percent Zr, with a balance to total 100 weight percent being copper and unavoidable impurities, said copper alloy foil having an anticorrosive coating of thickness less than 3 nm, said copper alloy foil having a surface exhibiting no artificial roughening and having a surface roughness less than 2 μm, expressed as ten-point average surface roughness, tensile strength at least 620 N/mm 2 and conductivity at least 64% IACS, and 180° peel strength between the copper alloy foil and an adhesive containing an epoxy resin bonding the copper alloy foil to a resin substrate is at least 8.9 N/cm.
23. Copper alloy foil according to claim 22 , wherein said anticorrosive coating consists essentially of at least one nitrogen-containing organic compound which forms a chelate with said copper.
24. Copper alloy foil according to claim 23 , wherein said organic compound is selected from the group consisting of benzotriazole and imidazole.
25. Copper alloy foil according to claim 22 , wherein said resin of said resin foil is a polyimide.
26. A laminate consisting essentially of a copper alloy foil according to claim 22 , laminated with a resin substrate.
27. A laminate consisting essentially of the copper alloy foil according to claim 22 , a resin substrate laminated thereto, and a resin-containing adhesive, bonding said copper alloy foil to said resin substrate.
28. The laminate of claim 27 , wherein said resin of said resin-containing adhesive consists essentially of an epoxy.