Water-repellent and soil-resistant finish for textiles
The present invention is directed to polymeric treatment preparations for textiles and other fibrous substrates that impart water and oil repellency to fibers, yarns, textiles, or other fibrous substrates. More particularly, this invention comprises an aqueous solution, emulsion or suspension of (a) a fluorinated polymer that contains reactive groups that can complex with metal atoms that have a formal charge of 2 or greater, and (b) one or more metal atoms that have a formal charge of 2 or greater. The invention is further directed to the process for treating fibrous substrates with textile preparations in one step that provide water/soil repellency that is durable to repeated cleanings and to abrasion. This invention is further directed to the yarns, fibers, fabrics, textiles, webs, finished goods, or nonwovens (encompassed herein under the terms “textiles” and “fibrous substrates”) treated with the textile-reactive water- and soil-resistant preparation of the invention. Such fibrous substrates exhibit a greatly improved, durable water and soil repellency or resistance, even after multiple launderings.
1. A copolymer comprising i) an acid-containing monomer, ii) a metal-containing monomer, and iii) a fluorinated monomer, said copolymer incorporating metal atoms with a formal charge of 2 or greater.
2. A copolymer according to claim 1 wherein said fluorinated monomer has the structure:
wherein:
m is 0 to 2;
n is 0 or 1;
o is 1 or 2;
A is —SO 2 —, —N(W)—SO 2 —, —CONH—, —CH 2 —, or —CF 2 —;
R is a linear, branched, or cyclic fully- or partially-fluorinated hydrocarbon;
W is hydrogen or C 1 -C 4 lower alkyl; and
X is acrylate (H 2 C═CHCO 2 —), methacrylate (H 2 C═C(CH 3 )CO 2 —), or a carbon—carbon double bond (H 2 C═CH—).
3. A copolymer according to claim 1 wherein said metal-containing monomer is selected from the group consisting of calcium acrylate, magnesium acrylate, aluminum acrylate, chromium acrylate, calcium styrene sulfonate, magnesium styrene sulfonate, aluminum styrene sulfonate, and chromium styrene sulfonate.
4. A copolymer according to claim 1 wherein said acid-containing monomer is selected from the group consisting of acrylic acid, methacrylic acid, maleic anhydride, maleic acid, crotonic acid, itaconic acid, and mixtures thereof.
5. A copolymer according to claim 1 wherein said copolymer comprises at least one block of said acid-containing monomers and at least one block of said fluorinated monomers.
6. A copolymer according to claim 1 wherein said copolymer comprises at least one block of hydrophilic monomers, which hydrophilic monomers are concentrated to one end of the copolymer.
7. A copolymer comprising i) an acid-containing monomer or an acid-containing monomer precomplexed with metal atoms having a formal charge of 2 or greater, and ii) a fluorinated monomer, said copolymer having reactive groups that can coordinately bind with metal atoms having a formal charge of 2 or greater if the metal atom is not already precomplexed in the acid-containing monomer.
8. A copolymer according to claim 7 wherein said fluorinated monomer has the structure:
wherein:
m is 0 to 2;
n is 0 or 1;
o is 1 or 2;
A is —SO 2 —, —N(W)—SO 2 —, —CONH—, —CH 2 —, or —CF 2 —;
R is a linear, branched, or cyclic fully- or partially-fluorinated hydrocarbon;
W is hydrogen or C 1 -C 4 lower alkyl; and
X is acrylate (H 2 C═CHCO 2 —), methacrylate (H 2 C═C(CH 3 )CO 2 —), or a carbon—carbon double bond (H 2 C═CH—).
9. A copolymer according to claim 7 wherein said acid-containing monomer is selected from the group consisting of acrylic acid, methacrylic acid, maleic anhydride, maleic acid, crotonic acid, itaconic acid, and mixtures thereof.
10. A copolymer according to claim 7 wherein said copolymer is a diblock copolymer comprising at least one block of said acid-containing monomers and at least one block of said fluorinated monomers.
11. A copolymer according to claim 7 wherein said copolymer is a diblock copolymer comprising at least one block of hydrophilic monomers, which hydrophilic monomers are concentrated to one end of the copolymer.