Releasable microcapsule and adhesive curing system using the same

1. An uncured adhesive comprising a resin component, a hardener component, and a microencapsulated accelerator component, wherein the microencapsulated accelerator component comprises an infrared absorber, an accelerator and a wall that covers substantially the entire surface of the accelerator, wherein the wall isolates the accelerator from the resin component and the hardener component.

2. An uncured adhesive comprising a resin component, a hardener component, and a microencapsulated accelerator component, wherein the microencapsulated accelerator component comprises an infrared absorber, an accelerator and a wall that covers substantially the entire surface of the accelerator, wherein the wall comprises a polymer selected from the group consisting of polyurethane, polystyrene, polyisocyanate, gelatin, a low melting temperature polymer, a wax and mixtures thereof.

3. An uncured adhesive comprising a resin component, a hardener component, and a microencapsulated accelerator component, wherein the microencapsulated accelerator component comprises an infrared absorber, an accelerator and a wall that covers substantially the entire surface of the accelerator, wherein the wall comprises the infrared absorber.

4. The uncured adhesive as set forth in claim 1 wherein the infrared absorber is encapsulated by the wall.

5. An uncured adhesive comprising a resin component, a hardener component, and a microencapsulated accelerator component, wherein the microencapsulated accelerator component comprises an infrared absorber, an accelerator and a wall that covers substantially the entire surface of the accelerator, wherein the infrared absorber is selected from the group consisting of carbon black, an infrared absorbing dye and mixtures thereof.

6. The uncured adhesive as set forth in claim 5 comprising between about 0.1 and about 10 percent by weight of carbon black.

7. The uncured adhesive as set forth in claim 5 comprising between about 1 and about 2 percent by weight of carbon black.

8. The uncured adhesive as set forth in claim 5 comprising between about 1 and about 10 percent by weight of an infrared absorbing dye.

9. The uncured adhesive as set forth in claim 5 comprising between about 1 and about 2 percent by weight of an infrared absorbing dye.

10. The uncured adhesive as set forth in claim 1 wherein the resin component comprises a liquid epoxy resin selected from the group consisting of polyglycidyl ethers of polyhydric phenols, polyglycidyl esters of polycarboxylic acids, alicyclic epoxy compounds, polyglycidyl ethers of polyhydric alcohols, polyglycidyl compounds of polyvalent amines and mixtures thereof.

11. The uncured adhesive as set forth in claim 10 wherein the liquid epoxy resin is a bisphenol epoxy resin.

12. The uncured adhesive as set forth in claim 11 wherein the liquid epoxy resin is a bisphenol A epoxy resin.

13. The uncured adhesive as set forth in claim 1 wherein the resin component comprises a solid resin that comprises a base compound and a functional group, wherein the base compound is selected from the group consisting of phenoxy resin, polyvinyl acetal, polyamide, polyester, polyurethane, ethylene-vinyl acetate copolymer, acrylic esters, acrylonitrile-butadiene rubber, styrene-butadiene rubber, styrene-isoprene rubber, styrene-ethylene-butylene copolymer and mixtures thereof, and the functional group is selected from the group consisting of a carboxyl group, a hydroxyl group, a vinyl group, an amino group, an epoxy group and mixtures thereof.

14. The uncured adhesive as set forth in claim 1 wherein the hardener component is selected from the group consisting of an aliphatic amine, an aromatic amine, an anhydride, a thiol, an alcohol, a phenol, an isocyanates, a boron complex, an inorganic acid and mixtures thereof.

15. The uncured adhesive as set forth in claim 14 wherein the hardener component is an anhydride selected from the group consisting of a maleic anhydride, a phthalic anhydride, a succinic anhydride, a nadic methyl anhydride and mixtures thereof.

16. The uncured adhesive as set forth in claim 1 wherein the accelerator comprises nitrogen.

17. The uncured adhesive as set forth in claim 16 wherein the accelerator comprises an amine group.

18. The uncured adhesive as set forth in claim 16 wherein the accelerator comprises an imidazole group.

19. An uncured adhesive comprising a resin component, a hardener component, and a microencapsulated accelerator component, wherein the microencapsulated accelerator component comprises an infrared absorber, an accelerator and a wall that covers substantially the entire surface of the accelerator, wherein the accelerator comprises nitrogen and is selected from the group consisting of imidazole, 2-methylimidazole, 2-ethylimidazole, 4-methylimidazole, 1-benzyl-2-methyl imidizole, 1-cyanoethyl-2-phenyl-4, 5-dihydroxymethyl imidazole, 2-phenyl-4, 5-dihydroxymethyl imidazole, a difunctional mercaptan, stannous octoate, urea and mixtures thereof.

20. The uncured adhesive as set forth in claim 16 wherein the accelerator comprises between about 0.1 and about 2 percent by weight of the uncured adhesive.

21. The uncured adhesive as set forth in claim 6 wherein the accelerator comprises between about 0.3 and about 1 percent by weight of the uncured adhesive.

22. A method of curing an adhesive, the method comprising:

exposing an uncured adhesive to infrared energy that is absorbed by an infrared absorber so that a wall covering substantially an entire surface of an accelerator disintegrates thereby allowing the accelerator to facilitate a curing reaction;

wherein the uncured adhesive comprises a resin component, a hardener component, and a microencapsulated accelerator component; and

wherein the microencapsulated accelerator component comprises the wall, the infrared absorber, and the accelerator.

23. The method as set forth in claim 22 wherein the wall comprises a polymer selected from the group consisting of polyurethane, polystyrene, polyisocyanate, gelatin, a low melting temperature polymer, a wax and mixtures thereof.

24. The method as set forth in claim 22 wherein the infrared absorber is substantially uniformly constituted throughout the wall.

25. The method as set forth in claim 22 wherein the infrared absorber is encapsulated by the wall.

26. The method as set forth in claim 22 wherein the infrared absorber is selected from the group consisting of carbon black, an infrared absorbing dye and mixtures thereof.

27. The method as set forth in claim 26 wherein the microencapsulated accelerator component comprises between about 0.1 and about 10 percent by weight of carbon black.

28. The method as set forth in claim 26 wherein the microencapsulated accelerator component comprises between about 1 and about 2 percent by weight of carbon black.

29. The method as set forth in claim 26 wherein the microencapsulated accelerator component comprises between about 1 and about 10 percent by weight of an infrared absorbing dye.

30. The method as set forth in claim 26 wherein the microencapsulated accelerator component comprises between about 1 and about 2 percent by weight of an infrared absorbing dye.

31. The method as set forth in claim 22 wherein the resin component comprises a liquid epoxy resin selected from the group consisting of polyglycidyl ethers of polyhydric phenols, polyglycidyl esters of polycarboxylic acids, alicyclic epoxy compounds, polyglycidyl ethers of polyhydric alcohols, polyglycidyl compounds of polyvalent amines and mixtures thereof.

32. The method as set forth in claim 31 wherein the liquid epoxy resin is a bisphenol epoxy resin.

33. The method as set forth in claim 32 wherein the liquid epoxy resin is a bisphenol A epoxy resin.

34. The method as set forth in claim 22 wherein the resin component comprises a solid resin that comprises a base compound and a functional group, wherein the base compound is selected from the group consisting of phenoxy resin, polyvinyl acetal, polyamide, polyester, polyurethane, ethylene-vinyl acetate copolymer, acrylic esters, acrylonitrile-butadiene rubber, styrene-butadiene rubber, styrene-isoprene rubber, styrene-ethylene-butylene copolymer and mixtures thereof, and the functional group is selected from the group consisting of a carboxyl group, a hydroxyl group, a vinyl group, an amino group, an epoxy group and mixtures thereof.

35. The method as set forth in claim 22 wherein the hardener component is selected from the group consisting of an aliphatic amine, an aromatic amine, an anhydride, a thiol, an alcohol, a phenol, an isocyanates, a boron complex, an inorganic acids and mixtures thereof.

36. The method as set forth in claim 35 wherein the hardener component is an anhydride selected from the group consisting of a maleic anhydride, a phthalic anhydride, a succinic anhydride, a nadic methyl anhydride and mixtures thereof.

37. The method as set forth in claim 22 wherein the accelerator comprises nitrogen.

38. The method as set forth in claim 37 wherein the accelerator comprises an amine group.

39. The method as set forth in claim 37 wherein the accelerator comprises an imidazole group.

40. The method as set forth in claim 37 wherein the accelerator is selected from the group consisting of imidazole, 2-methylimidazole, 2-ethyl, 4-methylimidazole, 1-benzyl-2-methyl imidizole, 1-cyanoethyl-2-phenyl-4, 5-dihydroxymethyl imidazole, 2-phenyl-4,5-dihydroxymethyl imidazole, a difunctional mercaptan, stannous octoate, urea and mixtures thereof.

41. The method as set forth in claim 37 wherein the accelerator comprises between about 0.1 and about 2 percent by weight of the uncured adhesive.

42. The method as set forth in claim 37 wherein the accelerator comprises between about 0.3 and about 1 percent by weight of the uncured adhesive.