Low temperature polyimide adhesive compositions and methods relating thereto
View Patent ↗The present invention relates to a polyimide adhesive composition having a polyimide derived from an aromatic dianhydride and a diamine component, where the diamine component is preferably about 50 to 90 mole % of an aliphatic diamine and about 10 to 50 mole % of an aromatic diamine. In one embodiment, the aliphatic diamine has the structural formula H 2 N—R—NH 2 wherein R is hydrocarbon from C 4 to C 16 and the polyimide adhesive has a glass transition temperature in the range of from 150° C. to 200° C. The present invention also relates to compositions comprising the polyimide adhesive of the present invention, including polyimide metal-clad laminate useful as flexible circuit when metal traces are formed out of the metal used in flexible, rigid, or flex-rigid circuit applications.
1. A polyimide adhesive composition comprising:
a polylimide base polymer synthesized by contacting an aromatic dianhydride with a diamine component, the diamine component comprising about 50 to about 90 mole % aliphatic diamine and about 10 to about 50 mole % aromatic diamine, wherein the aliphatic diamine is hexamethylene diamine (HMD), wherein the aromatic diamine is 1,3-bis-(4-aminophenoxy) benzene, and wherein the aromatic dianhydride is a combination of 3,3′,4,4′-benzophenone tetracarboxylic dianhydride (BTDA) and 3,3′,4,4′-biphenyl tetracarboxylic dianhydride (BPDA), said polyimide base polymer having a glass transition temperature from about 150, 160, 170, 180, or 185 to about 190, 195, 197 or 200° C.
2. A polyimide adhesive composition according to claim 1 , wherein the polyimide adhesive is a film and wherein the z-axis coefficient of thermal expansion of said film, as determined by ASTM Method IPC-650 2.4.41, is between and including any two of the following numbers, 80, 85, 90, 95, 100, 105, 110, 115, 120, 125, 130, 135, 140, 145, or 150 ppm/° C.
3. A polyimide adhesive composition according to claim 1 , wherein the glass transition temperature of the polyimide adhesive is in the range of 165° C. to 185° C.
4. A polyimide adhesive composition according to claim 1 , wherein the aromatic dianhydride component is 70 to 95 mole % 3,3′,4,4′-biphenyltetracarboxylic dianhydride (BPDA) and 5 to 30 mole % 3,3′,4,4′-benzophenonetetracarboxylic dianhydride (BTDA), and wherein the diamine component is 60 to 80 mole % hexamethylene diamine (HMD) and 20 to 40 mole % 1,3-bis-(4-aminophenoxy) benzene (APB-134, RODA).
5. A polyimide adhesive composition according to claim 1 , wherein the polyimide adhesive is a film and wherein the z-axis coefficient of thermal expansion of said film, as determined by ASTM Method IPC-650 2.4.41, is less than 120 ppm/° C.
6. A composition useful for packaging electronic circuits, wherein a polyimide adhesive in accordance with claim 1 is a component of said composition, said composition being a chip on lead (“COL”) package, a chip on flex (“COF”) package, a lead on chip (“LOC”) package, a multi-chip module (“MCM”) package, a ball grid array (“BGA” or “μ-BGA”) package, chip scale package (“CSP”) or a tape automated bonding (“TAB”) package.
7. A polyimide adhesive composite in accordance with claim 1 , wherein the polyimide base polymer has a loss tangent value of less than 0.010 at 10 GHz.
8. A polyimide adhesive composition in accordance with claim 1 further comprising a filler material selected from the group consisting of alumina, silica, boron nitride, silicon carbide, clay, diamond, dicalcium phosphate, aluminum nitride, titanium dioxide, polyaniline, polythiophene, polypyrrole, polyphenylenevinylene, polydialkylfluorenes, carbon black, and graphite.