Process for the synthesis of BrSF5
View Patent ↗A process for producing BrSF 5 includes providing a first reactant including a metal fluoride of fluorine and a metal M selected from the group consisting of alkali metals, alkaline earth metals, and Ag, providing a second reactant including BrF 3 , combining the first reactant and the second reactant to form a mixture, wherein the first reactant and the second reactant are allowed to contact for a period of time sufficient to produce MBrF 4 in an amount stoichiometrically equivalent to a quantity of BrF 3 , and providing a third reactant including SF 4 , wherein the third reactant reacts with MBrF 4 . The process for producing BrSF 5 can further include providing a fourth reactant including Br 2 , wherein the fourth reactant is provided before, during and/or after providing the first reactant, the second reactant and/or the third reactant. BrSF 5 is produced in a yield of from about 50% to about 99.99% based on the amount of SF 4 .
1. process for producing BrSF 5 , said process comprising:
providing a first reactant comprising a metal fluoride MF, wherein the metal M is selected from the group consisting of alkali metals, alkaline earth metals, and Ag;
providing a second reactant comprising BrF 3 ;
combining the first reactant and the second reactant to form a mixture, wherein the first reactant and the second reactant are allowed to contact for a period of time sufficient to produce MBrF 4 in an amount stoichiometrically equivalent to a quantity of BrF 3 ; and
providing a third reactant comprising SF 4 , wherein the third reactant reacts with MBrF 4 to produce BrSF 5 .
2. The process of claim 1 , wherein the metal fluoride is a metal fluoride mixture comprising at least two different metal fluorides.
3. The process of claim 1 , wherein the metal is a member selected from the group consisting of Cs, K, Ba, Rb, Na and Sr.
4. The process of claim 1 , further comprising providing a fourth reactant comprising Br 2 , wherein the fourth reactant is provided before, during and/or after providing the first reactant, the second reactant and/or the third reactant.
5. The process of claim 4 , wherein the metal fluoride is at least one of CsF and KF.
6. The process of claim 4 , wherein the period of time of the combining step is less than 6 days.
7. The process of claim 4 , wherein the first reactant, the second reactant, the third reactant, and the fourth reactant are provided at a temperature of about −200° C. to about 150° C.
8. The process of claim 1 , wherein the third reactant reacts with MBrF 4 at a first reaction temperature of about −20° C. to about 150° C.
9. The process of claim 8 , wherein the first reaction temperature is about 20° C. to about 120° C.
10. The process of claim 8 , wherein the first reaction temperature is about 20° C. to about 100° C.
11. The process of claim 4 , wherein the third reactant reacts with MBrF 4 and Br 2 at a second reaction temperature of about −20° C. to about 150° C.
12. The process of claim 11 , wherein the second reaction temperature is about 20° C. to about 120° C.
13. The process of claim 11 , wherein the second reaction temperature is about 20° C. to about 100° C.
14. The process of claim 1 , wherein the metal fluoride is provided in a metal fluoride amount stoichiometrically equivalent to or up to 50 times the quantity of BrF 3 .
15. The process of claim 1 , wherein SF 4 is provided in a SF 4 amount less than stoichiometrically equivalent to the amount of MBrF 4 , and wherein a stoichiometric ratio of a SF 4 to MBrF 4 is 3:1.
16. The process of claim 4 , wherein Br 2 is provided in a Br 2 amount stoichiometrically equivalent to or up to 50 times the amount of MBrF 4 , thereby increasing selectivity of BrSF 5 formation.
17. The process of claim 1 , wherein the first reactant is treated to be at least 90% by weight of the metal fluoride.
18. The process of claim 1 , wherein the second reactant is treated to be at least 50% by weight of BrF 3 , up to 50% by weight of Br 2 , and up to 15% by weight of HF.
19. The process of claim 4 , wherein the fourth reactant is treated to be at least 90% by weight of Br 2 .
20. The process of claim 1 , wherein the third reactant is treated to be at least 85% by weight of SF 4 and not more than 15% contaminants, the contaminants including HF.
21. The process of claim 1 , wherein the metal fluoride is produced in a reaction of SF 4 with MBrF 4 and Br 2 and is replenished when depleted.
22. The process of claim 4 , wherein BrSF 5 is produced in a yield of from about 50% to about 99.99% based on the amount of SF 4 .
23. The process of claim 4 , wherein the first reactant, the second reactant, the third reactant, and the fourth reactant are provided simultaneously.
24. The process of claim 1 , wherein MBrF 4 ionizes to form a (BrF 4 ) − anion, and the (BrF 4 ) − anion selectively oxidizes SF 4 to produce BrSF 5 .
25. A process for producing BrSF 5 , said process comprising:
providing a first reactant comprising a metal fluoride MF, wherein the metal M is selected from the group consisting of alkali metals, alkaline earth metals and Ag;
providing a second reactant comprising BrF 3 ;
combining the first reactant and the second reactant to form a mixture, wherein the first reactant and the second reactant are allowed to contact for a period of time sufficient to produce MBrF 4 ; and
providing a third reactant comprising SF 4 , wherein the third reactant reacts with MBrF 4 to produce BrSF 5 ;
wherein the first reactant, the second reactant and the third reactant are provided in any order consecutively or simultaneously, and Br 2 is present in an amount stoichiometrically less than a quantity of said BrF 3 .
26. The process of claim 25 , wherein the period of time is sufficient to produce MBrF 4 in an amount stoichiometrically equivalent to the quantity of said BrF 3 .
27. The process of claim 25 , wherein the metal fluoride is a metal fluoride mixture comprising at least two different metal fluorides.
28. The process of claim 25 , wherein the metal is a member selected from the group consisting of Cs, K, Ba, Rb, Na, and Sr.
29. A method for synthesizing BrSF 5 comprising combining Br 2 , BrF 3 , and a metal fluoride MF, wherein the metal M is selected from the group consisting of Cs and K, to form a preliminary reaction mixture, reacting the preliminary reaction mixture for a preliminary reaction period, and adding SF 4 to the preliminary reaction mixture after the preliminary reaction period to produce a yield of BrSF 5 during a reaction period of less than 144 hours.
30. The method of claim 29 , wherein the metal M is selected from the group consisting of Cs, K, Ba, Rb, Na, Sr, and Ag.
31. The method of claim 30 , wherein the metal fluoride and BrF 3 are allowed to contact for a period of time sufficient to produce MBrF 4 in an amount stoichiometrically equivalent to a quantity of said BrF 3 .
32. The method of claim 29 , wherein the reaction period is less than 36 days and the yield of BrSF 5 is at least 50% at room temperature.
33. The method of claim 32 , wherein the yield of BrSF 5 is at least 88.2%.