Security sheet comprising a transparent or translucent layer
The invention relates to a coated sheet of security paper which includes security elements and has a high print rendition and a high resistance to circulation, which sheet is characterized in that at least one of its sides is coated with a transparent or translucent coating comprising at least one colloidal silica and at least one transparent or translucent elastomeric binder. In particular, the binder is a polyurethane. The invention also relates to the process for manufacturing the said sheet and to a banknote obtained from this sheet.
1. A coated sheet of security paper comprising cellulose fibers, cotton fibers, synthetic fibers or mixtures thereof, security elements and has a high print quality and a high resistance to circulation, at least one side of said sheet is coated with a coating comprising at least one fumed silica and at least one transparent or translucent elastomeric binder, characterized in that the coating is transparent or translucent and comprises:
30 to 50 parts by dry weight of colloidal silica,
50 to 70 parts by dry weight of said elastomeric binder, the sum of the silica and binder making up a total of 100.
2. The sheet according to claim 1 , characterized in that the elastomeric binder is selected from the group consisting of polyurethanes in the form of stabilized aqueous dispersions.
3. The sheet according to claim 2 , characterized in that said polyurethane is chosen from high-hardness polyurethanes.
4. The sheet according to claim 1 , characterized in that said coating comprises approximately 40 parts of the said silica and approximately 60 parts of the said binder, by dry weight, the sum of the parts of these components making up a total of 100.
5. The sheet according to claim 1 , characterized in that said coating includes a crosslinking agent.
6. A banknote paper comprising a security sheet according to claim 1 .
7. The sheet according to claim 5 , characterized in that said crosslinking agent is a polyaziridine.
8. A coated sheet of security paper comprising cellulose fibers, cotton fibers, synthetic fibers or mixtures thereof, security elements and has a high print quality and a high resistance to circulation, at least one side of said sheet is coated with a coating comprising at least one silica and at least one transparent or translucent elastomeric binder, characterized in that the coating is transparent or translucent and comprises:
30 to 50 parts by dry weight of colloidal silica,
50 to 70 parts by dry weight of said elastomeric binder, the sum of the silica and binder making up a total of 100; characterized in that the weight of the coating deposited is between 1 and 15 g/m2 per side by dry weight.
9. The sheet according to claim 8 , characterized in that the weight of the coating deposited is between 1 and 10 g/m 2 per side by dry weight.
10. The sheet according to claim 9 , characterized in that the weight of the coating deposited is between 2 and 7 g/m 2 per side by dry weight.
11. The sheet according to claim 8 , characterized in that the weight of the coating deposited is between 2 and 7 g/m 2 per side by dry weight, the coating includes a crosslinking agent which is a polyaziridine, the binder is an elastomeric polyurethane, and the silica is a fumed silica.
12. The sheet according to claim 8 , characterized in that the weight of the coating deposited is between 2 and 7 g/m 2 per side by dry weight and the binder is an elastomeric polyurethane and wherein said coating comprises approximately 40 parts of the said silica and approximately 60 parts of the said binder, by dry weight, the sum of the parts of these components making up a total of 100.
13. The sheet according to claim 1 , wherein the sheet is a paper based on cotton fibres and contains a wet-strength agent.
14. The banknote paper of claim 6 , wherein the paper is a paper based on cotton fibres.
15. The sheet according to claim 1 , wherein the sheet is a paper based on cellulose fibers.
16. A banknote paper comprising a sized security sheet according to claim 1 , with intaglio printing thereon.
17. A banknote paper comprising a sized security sheet according to claim 8 , with intaglio printing thereon, wherein the weight of the coating deposited is between 2 and 7 g/m 2 per side by dry weight and is contiguous to the sheet, the coating contains a crosslinking agent which is a polyaziridine, the binder is an elastomeric polyurethane, and the silica is a fumed silica.
18. The sheet according to claim 1 , wherein the sheet is a paper based on cellulose fibers, cotton fibers or a mixture thereof.
19. The sheet according to claim 8 , characterized in that said silica has a specific surface area, measured according to the BET method (DIN 66 131 standard), of between 300 and 400 m 2 /g.