IP Library Granted Patent US 7,060,662
Granted Patent B2
US 7,060,662 · App. 10/365,582 · Granted Jun 13, 2006

Antifoam agent and method for use in automatic transmission fluid applications involving high pressure pumps

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Quick Facts
Patent No.
US 7,060,662
App. No.
10/365,582
Granted
Jun 13, 2006
Kind
B2
Abstract

The present invention relates to the use of a high level of a silicon-containing antifoam agent in automatic transmission fluid (“ATF”) applications. More specifically, the invention relates to a formulation and method for the reduction or elimination of pump whine that occurs in high-pressure pumps used to circulate transmissions fluids in vehicles. The invention also relates to fully formulated ATFs, to transmissions lubricated with such ATFs, and to vehicles containing transmissions lubricated with such ATFs.

Claims (63)

1. An automatic transmission fluid, comprising an antifoam-effective amount of a silicon-containing antifoamant, such that the total amount of silicon in the automatic transmission fluid provided by the antifoamant is at least 30 ppm.

2. The fluid of claim 1 , wherein said fluid has less than 0.01 weight percent of 85% phosphoric acid.

3. The fluid of claim 1 , wherein the silicon-containing antifoamant comprises a mixture of polydimethylsiloxane and fluorosilicone antifoamant.

4. The fluid of claim 1 , further comprising an acrylate polymer antifoamant.

5. The fluid of claim 4 , wherein the acrylate polymer antifoamant is selected from the group consisting of a polymethacrylate, a polyacrylate, a dispersant polymethacrylate, a dispersant polyacrylate, and a mixture thereof.

6. The fluid of claim 1 , wherein the silicon-containing antifoamant is a mixture of polydimethylsiloxane and fluorosilicone antifoamant, and further comprising an acrylate polymer antifoamant, wherein the weight ratio of the fluorosilicone antifoamant to the acrylate antifoamant is from about 3:1 to about 1:4.

7. An automotive transmission fluid comprising:

N-aliphatic alkyl-substituted

 0.08 to 0.30 weight percent;

diethanolamine

Phosphorylated and boronated

 2.5 to 5.0 weight percent;

ashless dispersant

Sulfurized fatty oil friction modifier

 0.60 to 1.20 weight percent;

Copper corrosion inhibitor

 0.02 to 0.10 weight percent;

Silicone antifoamant

 0.02 to 0.10 weight percent;

Nonylated diphenyl amine

 0.15 to 0.45 weight percent;

Ca(OH) 2 salt of sulfurized alkyl

 0.02 to 0.10 weight percent;

phenate (TBN 150)

Octanoic acid

 0.02 to 0.10 weight percent;

3-decyloxypropylamine

 0.02 to 0.10 weight percent;

Ethylene oxide-propylene oxide

0.005 to 0.10 weight percent;

block copolymer

Alkyl polyoxyalkylene ether

 0.02 to 0.10 weight percent;

Acrylate polymer

0.015 to 0.060 weight percent;

Diluent oil

greater than 0.10 weight percent;

wherein the silicone antifoamant imparts greater than 30 ppm silicon to the

fluid.

8. An automatic transmission fluid, comprising:

a) an oil of lubricating viscosity having a 100° C. kinematic viscosity of 2–10 cSt;

b) sufficient weight percent of 2,5-dimercapto-1,3,4-thiadiazole (DMTD) and/or derivatives or precursors thereof to provide the fluid with antiwear properties;

c) a silicon-containing antifoam agent which imparts greater than 30 ppm silicon to the fluid; and

d) an acrylate, methacrylate, polyacrylate, polymethacrylate, or copolymer or terpolymer thereof.

9. The fluid of claim 8 , wherein the silicon-containing antifoam agent comprises a mixture of polydimethylsiloxane and fluorosilicone antifoamant.

10. An automatic transmission lubricated with a lubricating oil comprising the fluid of claim 1 .

11. An automatic transmission lubricated with a lubricating oil comprising the automatic transmission fluid of claim 7 .

12. The automatic transmission of claim 10 , wherein the transmission is a continuously variable transmission.

13. A method of treating an automatic transmission having space between moving parts,

comprising directly injecting into said space in said transmission a fluid composition comprising at least one silicone antifoam agent wherein the silicone antifoam agent imparts greater than 30 ppm silicon to the fluid.

14. The method of claim 13 , wherein the composition further comprises a carrier oil.

15. A method of reducing pump whine in an automatic transmission, comprising lubricating the transmission with a fluid comprising an oil having kinematic viscosity of 2–10 cSt at 100° C.; and an effective amount of a silicon-containing antifoam agent, such that the total amount of silicon in the automatic transmission fluid provided by the antifoam agent is at least 30 ppm, wherein the amount of pump whine is reduced relative to the pump whine produced in a transmission not lubricated with a fluid containing at least 30 ppm silicon provided by an antifoam agent.

16. The method of claim 15 , wherein the total amount of silicon in the automatic transmission fluid provided by the antifoam agent is greater than 50 ppm.

17. The method of claim 15 , wherein the total amount of silicon in the automatic transmission fluid provided by the antifoam agent is 50 to 70 ppm.

18. A method to decrease aeration in an automotive transmission fluid in an automotive transmission by aiding the release of entrained bubbles in said fluid, said method comprising lubricating the transmission with a transmission fluid comprising a mixture of polydimethylsiloxane and fluorosilicone antifoam agents, wherein the total amount of silicon in the automatic transmission fluid provided by the antifoam agents is greater than 30 ppm.

19. A method for reducing foaming of a hydrocarbon oil used as a transmission lubricating and power transmitting fluid in a vehicle, said method comprising injecting directly into said oil in a transmission a composition comprising an insoluble antifoam agent and an inert carrier oil, wherein the antifoam agent imparts greater than 30 ppm silicon to the fluid.

20. The method of claim 19 , wherein the antifoam agent is a silicon-containing material selected from the group consisting of fluorosilicones, polydimethylsiloxane, phenyl-methyl polysiloxane, linear siloxanes, cyclic siloxanes, branched siloxanes, silicone polymers and copolymers, and organo-silicone copolymers, and wherein the silicone provided by the antifoam agent is present in the fluid at an amount greater than 30 ppm.

21. The method of claim 20 , wherein the injecting occurs into the transmission case, a sump, a fluid pump, a fill tube, a dipstick, a service port, a torque converter, a valve body, an accumulator, or a hydraulic line.

22. A vehicle comprising a transmission lubricated with a lubricant comprising the fluid of claim 1 .

23. A vehicle lubricated by the method of claim 13 .

24. A vehicle lubricated by the method of claim 15 .

25. A vehicle lubricated by the method of claim 18 .

26. A vehicle lubricated by the method of claim 19 .

Assignments (19)
RELEASE OF SECURITY INTEREST Recorded Nov 7, 2014
From: WILMINGTON TRUST COMPANY
To: GM GLOBAL TECHNOLOGY OPERATIONS LLC
Reel/Frame 034189/0065 →
RELEASE OF SECURITY INTEREST Recorded Aug 15, 2011
From: SUNTRUST BANK
To: AFTON CHEMICAL CORPORATION/CHEVRON TEXACO/GENERAL MOTORS (JOINTLY OWNED)
Reel/Frame 026751/0334 →
CHANGE OF NAME Recorded Feb 10, 2011
From: GM GLOBAL TECHNOLOGY OPERATIONS, INC.
To: GM GLOBAL TECHNOLOGY OPERATIONS LLC
Reel/Frame 025780/0902 →
SECURITY AGREEMENT Recorded Nov 8, 2010
From: GM GLOBAL TECHNOLOGY OPERATIONS, INC.
To: WILMINGTON TRUST COMPANY
Reel/Frame 025327/0262 →
RELEASE OF SECURITY INTEREST Recorded Nov 4, 2010
From: UAW RETIREE MEDICAL BENEFITS TRUST
To: GM GLOBAL TECHNOLOGY OPERATIONS, INC.
Reel/Frame 025311/0725 →
RELEASE OF SECURITY INTEREST Recorded Nov 4, 2010
From: UNITED STATES DEPARTMENT OF THE TREASURY
To: GM GLOBAL TECHNOLOGY OPERATIONS, INC.
Reel/Frame 025245/0347 →
SECURITY AGREEMENT Recorded Aug 28, 2009
From: GM GLOBAL TECHNOLOGY OPERATIONS, INC.
To: UAW RETIREE MEDICAL BENEFITS TRUST
Reel/Frame 023161/0911 →
SECURITY AGREEMENT Recorded Aug 27, 2009
From: GM GLOBAL TECHNOLOGY OPERATIONS, INC.
To: UNITED STATES DEPARTMENT OF THE TREASURY
Reel/Frame 023156/0001 →
RELEASE OF SECURITY INTEREST Recorded Aug 21, 2009
From: CITICORP USA, INC. AS AGENT FOR BANK PRIORITY SECURED PARTIES; CITICORP USA, INC. AS AGENT FOR HEDGE PRIORITY SECURED PARTIES
To: GM GLOBAL TECHNOLOGY OPERATIONS, INC.
Reel/Frame 023127/0273 →
RELEASE OF SECURITY INTEREST Recorded Aug 20, 2009
From: UNITED STATES DEPARTMENT OF THE TREASURY
To: GM GLOBAL TECHNOLOGY OPERATIONS, INC.
Reel/Frame 023124/0470 →
SECURITY AGREEMENT Recorded Apr 16, 2009
From: GM GLOBAL TECHNOLOGY OPERATIONS, INC.
To: CITICORP USA, INC. AS AGENT FOR BANK PRIORITY SECURED PARTIES; CITICORP USA, INC. AS AGENT FOR HEDGE PRIORITY SECURED PARTIES
Reel/Frame 022553/0399 →
SECURITY AGREEMENT Recorded Feb 4, 2009
From: GM GLOBAL TECHNOLOGY OPERATIONS, INC.
To: UNITED STATES DEPARTMENT OF THE TREASURY
Reel/Frame 022201/0448 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 14, 2009
From: GENERAL MOTORS CORPORATION
To: GM GLOBAL TECHNOLOGY OPERATIONS, INC.
Reel/Frame 022102/0789 →
SECURITY AGREEMENT Recorded Feb 14, 2007
From: AFTON CHEMICAL CORPORATION/CHEVRON TEXACO/GENERAL MOTORS (JOINTLY OWNED)
To: SUNTRUST BANK
Reel/Frame 018891/0173 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 7, 2004
From: ETHYL CORPORATION
To: AFTON CHEMICAL CORPORATION
Reel/Frame 015231/0858 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 7, 2004
From: MUCHMORE, ROBERT A.; SARKAR, REUBEN
To: GENERAL MOTORS CORPORATION
Reel/Frame 015228/0248 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 7, 2004
From: DEWEERDT, MARC; GRANGER, STEDE
To: CHEVRON U.S.A. INC.
Reel/Frame 015228/0296 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 7, 2004
From: ROLLIN, ANTHON J.; TERSIGNI, SAMUEL H.
To: ETHYL CORPROATION
Reel/Frame 015231/0838 →
SECURITY INTEREST Recorded Jun 24, 2004
From: ETHYL CORPORATION
To: SUNTRUST BANK, AS ADMINISTRATIVE AGENT
Reel/Frame 014782/0348 →