IP Library Granted Patent US 6,936,541
Granted Patent B2
US 6,936,541 · App. 10/402,168 · Granted Aug 30, 2005

Method for planarizing metal interconnects

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Quick Facts
Patent No.
US 6,936,541
App. No.
10/402,168
Granted
Aug 30, 2005
Kind
B2
Abstract

A method for planarizing metal interconnects of a semiconductor wafer includes the steps of polishing the semiconductor wafer with a polishing solution and a polishing pad to planarize the metal interconnects. The polishing solution has by weight percent, 0.15 to 5 benzotriazole, 0 to 1 abrasive, 0 to 10 polymeric particles, 0 to 5 polymer-coated particles and balance water at a pH of less than 5 and a removal rate-pressure sensitivity (d r /d p ) of at least 750 (Å/min/psi). The polishing simultaneously accelerates removal of projecting metal from the metal interconnects with the polishing pad providing a first pressure that increases removal rate of the projecting metal; and it inhibits removal of recessed metal from the metal interconnects with the polishing pad providing a second pressure that decreases removal of the recessed metal.

Claims (16)

1. A method for planarizing metal interconnects of a semiconductor wafer comprising the steps of:

a) polishing the semiconductor wafer with a polishing solution and a polishing pad to planarize the metal interconnects, the metal interconnects being a nonferrous metal selected from the group consisting of copper, copper-base alloys, silver and silver-base alloys and the polishing solution having by weight percent, 0.15 to 5 benzotriazole, 0 to 1 abrasive, 0 to 10 polymeric particles, 0 to 5 polymer-coated particles and balance water at a pH of less than 5 and a removal rate-pressure sensitivity d r /d p of at least 750 Å/min/psi;

b) accelerating removal of projecting metal from the metal interconnects with the polishing pad providing a first pressure that increases removal rate of the projecting metal; and

c) inhibiting removal of recessed metal from the metal interconnects with the polishing pad providing a second pressure that decreases removal of the recessed metal and wherein the accelerating and inhibiting steps occur in a simultaneous manner.

2. The method of claim 1 wherein the polishing follows a first-step polishing step that removes a top layer of the metal interconnects.

3. The method of claim 1 including the additional step of finishing the metal interconnects by polishing at a reduced pressure with the polishing solution of step a) to remove residual nonferrous metal from the metal interconnects.

4. The method of claim 1 wherein the polishing solution has a removal rate-pressure sensitivity of least 1,000 Å/min/psi to reduce dishing of the metal interconnects during the polishing.

5. The method of claim 1 including the additional step of complexing the nonferrous metal removed from the metal interconnects.

6. A method for planarizing metal interconnects of a semiconductor wafer comprising the steps of:

a) polishing the semiconductor wafer with a polishing solution and a polishing pad to planarize the metal interconnects, the metal interconnects being a nonferrous metal selected from the group consisting of copper, copper-base alloys, silver and silver-base alloys and the polishing solution having by weight percent, 0.2 to 2 benzotriazole, 0 to 20 oxidizer, 0 to 20 complexing agent, 0 to 0.5 abrasive, 0 to 5 polymeric particles, 0 to 2.5 polymer-coated particles and balance water at a pH of less than 4 and a removal rate-pressure sensitivity d r /d p of at least 1000 Å/min/psi;

b) accelerating removal of projecting metal from the metal interconnects with the polishing pad providing a first pressure that increases removal rate of the projecting metal; and

c) inhibiting removal of recessed metal from the metal interconnects with the polishing pad providing a second pressure that decreases removal of the recessed metal and wherein the accelerating and inhibiting steps occur in a simultaneous manner.

7. The method of claim 6 wherein the polishing follows a first-step polishing step that removes a top layer of the metal interconnects.

8. The method of claim 6 including the additional step of finishing the metal interconnects by polishing at a reduced pressure with the polishing solution of step a) to remove residual nonferrous metal from the metal interconnects.

9. The method of claim 6 wherein the nonferrous is selected from the group consisting of copper and copper-base alloys and the polishing solution has a removal rate-pressure sensitivity of least 1,500 Å/min/psi to reduce dishing of the metal interconnects during the polishing.

10. The method of claim 6 including the additional step of complexing the nonferrous metal removed from the metal interconnects.

Assignments (2)
CHANGE OF NAME Recorded Jun 15, 2004
From: RODEL HOLDINGS, INC.
To: ROHM AND HAAS ELECTRONIC MATERIALS CMP HOLDINGS, INC.
Reel/Frame 014725/0685 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 6, 2003
From: BLAN, JINRU; GHOSH, TIRTHANKAR; THOMAS, TERENCE M.
To: RODEL HOLDINGS, INC.
Reel/Frame 013716/0093 →