Electrolyte creepage barrier for liquid electrolyte fuel cells
A dielectric assembly for electrically insulating a manifold or other component from a liquid electrolyte fuel cell stack wherein the dielectric assembly includes a substantially impermeable dielectric member over which electrolyte is able to flow and a barrier adjacent the dielectric member and having a porosity of less than 50% and greater than 10% so that the barrier is able to measurably absorb and chemically react with the liquid electrolyte flowing on the dielectric member to form solid products which are stable in the liquid electrolyte. In this way, the barrier inhibits flow or creepage of electrolyte from the dielectric member to the manifold or component to be electrically insulated from the fuel cell stack by the dielectric assembly.
1. A liquid electrolyte fuel cell system comprising:
a liquid electrolyte fuel cell stack;
a manifold member facing a surface of said liquid electrolyte fuel cell stack;
a dielectric assembly situated between said manifold member and said surface of said liquid electrolyte fuel cell stack, said dielectric assembly including a substantially impermeable dielectric member over which electrolyte is able to flow and a barrier adjacent the dielectric member and having a porosity of less than 50% and greater than 10% so that the barrier is able to measurably absorb and chemically react with the liquid electrolyte flowing on the dielectric member to form solid products which are stable in the liquid electrolyte,
said dielectric member including: opposing surfaces adapted to face, respectively, the manifold and the fuel-cell stack; and opposing sides connecting the opposing surfaces; and
said barrier including at least one of a first barrier segment embedded in one of the opposing sides of said dielectric member and a second barrier segment embedded in the other of the opposing sides of said dielectric member.
2. A liquid electrolyte fuel cell system in accordance with claim 1 , wherein:
said liquid electrolyte is carbonate.
3. A liquid electrolyte fuel-cell system in accordance with claim 1 , further comprising:
a first porous gasket situated between said face of said fuel-cell and said dielectric assembly.
4. A liquid electrolyte fuel-cell system in accordance with claim 3 , further comprising:
a second porous gasket situated between said dielectric assembly and said manifold.
5. A liquid electrolyte fuel-cell system in accordance with claim 4 , wherein:
each of said first and second gaskets has a porosity greater than 70% and a mean pore size greater that 10 um.
6. A liquid electrolyte fuel-cell system in accordance with claim 1 , wherein
said barrier comprises a ceramic material.
7. A liquid electrolyte fuel-cell system in accordance with claim 6 , wherein:
said dielectric member comprises a ceramic material.
8. A liquid electrolyte fuel-cell system in accordance with claim 1 , wherein:
said barrier comprises one of CaAl 2 O 4 , MgAl 2 O 3 , Al 2 O 3 and calcium aluminate cement.
9. A liquid electrolyte fuel-cell system in accordance with claim 1 , wherein:
said dielectric member has the shape of a frame.
10. A liquid electrolyte fuel-cell system in accordance with claim 1 , wherein:
said barrier includes said first and second barrier segments embedded, respectively, in the one and other opposing sides of said dielectric member.
11. A liquid electrolyte fuel-cell system in accordance with claim 10 , wherein:
said barrier further comprises a barrier layer disposed on the surface of said dielectric member adapted to face said manifold.
12. A liquid electrolyte fuel-cell system in accordance with claim 10 , wherein:
said dielectric member has the shape of a frame.
13. A liquid electrolyte fuel cell system in accordance with claim 1 , wherein:
said dielectric member has the shape of a frame; and
said frame includes a plurality of segments joined at a joint and said barrier is situated in the area of said joint.
14. A liquid electrolyte fuel cell system in accordance with claim 13 , wherein:
said joint includes a keyway area for receiving a key for joining said segments.
15. A liquid electrolyte fuel cell system in accordance with claim 14 , wherein: said barrier is on the surface of the keyway area facing the manifold.
16. A liquid electrolyte fuel-cell system comprising:
a liquid electrolyte fuel cell stack;
a manifold member facing a surface of said liquid electrolyte fuel cell stack;
a dielectric assembly situated between said manifold member and said surface of said liquid electrolyte fuel cell stack, said dielectric assembly including a substantially impermeable dielectric member over which electrolyte is able to flow and a barrier adjacent the dielectric member and having a porosity of less than 50% and greater than 10% so that the barrier is able to measurably absorb and chemically react with the liquid electrolyte flowing on the dielectric member to form solid products which are stable in the liquid electrolyte,
said dielectric member has the shape of a frame; and
said frame includes a plurality of segments joined at a joint, said joint including a keyway for receiving a key for joining said segments and said barrier is situated only on a surface of the keyway.
17. A liquid electrolyte fuel-cell system in accordance with claim 16 , wherein: said barrier is on the surface of the keyway facing the manifold.