Process and apparatus for providing gas for isotopic ratio analysis

1. A process for providing gas for isotopic ratio analysis, comprising the steps of:

a) generating gas from an analysis substance dissolved in a liquid eluate from a liquid chromatograph,

b) subsequently separating the gas from the liquid eluate, wherein the gas is conveyed to an isotope ratio mass spectrometer for isotopic ratio analysis.

2. The process according to claim 1 , characterized in that the gas is generated using a catalyst.

3. The process according to claim 1 , characterized in that the gas is separated from the eluate at a membrane in a gas separating unit.

4. The process according to claim 1 , characterized in that a carrier gas is added to the gas and they are fed together for isotopic ratio analysis.

5. The process according to claim 1 , characterized in that carrier gas is added to the liquid eluate.

6. The process according to claim 1 , characterized in that the analysis substance is an organic substance and the generated gas is CO 2 .

7. The process according to claim 1 , characterized in that the gas is generated chemically.

8. The process according to claim 1 or 7 , characterized in that the gas is generated physically.

9. An Apparatus for providing gas for isotopic ratio analysis, comprising:

a) a liquid chromatograph, said liquid chromatograph generating a liquid eluate;

b) a gas generating unit coupled to the liquid chromatograph, said gas generating unit for generating gas from an analysis substance present in the liquid eluate, and

c) a gas separating unit coupled to said gas generating unit for separating the gas from the liquid eluate, and configured to supply the separated gas to an isotope ratio mass spectrometer for isotopic ratio analysis of the gas.

10. The apparatus according to claim 9 , characterized in that the liquid chromatograph contains no separating column and consists only of pump and injection unit.

11. The apparatus of claim 9 further comprising a gas feed unit coupling said separating unit to an isotope ratio mass spectrometer for isotopic ratio analysis of the gas.

12. The apparatus of claim 9 wherein the gas generating unit further comprises a feed unit configured to provide a reagent and a reaction zone coupled to the feed unit.

13. The apparatus of claim 12 wherein said reaction zone further comprises a thermal or irradiation treatment device.

14. A process of analyzing a substance in an isotope ratio mass spectrometer, where the substance is present in a liquid eluate received from a liquid chromatograph, characterized in that: the substance while present in the liquid eluate is converted to a gas, the gas is separated from the liquid elute, and said separated gas is analyzed in an isotope ratio mass spectrometer to determine the isotope ratio of the gas.

15. The process of claim 14 wherein the substance is an organic sample, and further comprising the steps of adding a persulphate solution to the liquid eluate to convert the organic substance to CO 2 gas, separating the CO 2 gas from the liquid eluate and conveying the CO 2 gas to an isotope ratio mass spectrometer for isotopic ratio analysis of the CO 2 gas.