Pigment for use in inkjet recording medium coatings and methods
Pigment suitable for use in coating compositions for inkjet recording media. Surfaces of an inorganic particulate are interacted with a water-soluble polyvalent metal salt in an aqueous medium. The treated particle surfaces have a significant cationic surface charge imparted to them. The salt is a salt of a metal of Group II or Group III of the Periodic Table. Inkjet recording media treated with a coating composition containing the above pigment provide high density, fast-drying, and non-feathering ink images with suitable water fastness, while the coating compositions also offer cost advantages and improved rheology at higher pigment levels over coatings based on silica pigments.
1. A method for making a pigment composition for ink recording media, comprising:
i) blending an inorganic particulate and a water-soluble polyvalent metal salt effective that the water-soluble polyvalent metal salt contacts surfaces of the inorganic particulate to provide a surface treated inorganic particulate having a cationic surface charge on the contacted surfaces, wherein the salt is a salt of a metal of Group II or Group III of the Periodic Table;
ii) mixing, in an aqueous composition, the surface treated inorganic particulate and a cationic polymer comprising a quaternary amine compound.
2. The method of claim 1 , wherein the blending step comprises mixing an aqueous slurry of the inorganic particulate and the water-soluble polyvalent metal salt.
3. The method of claim 1 , wherein the blending step comprising dry blending of the inorganic particulate and particles comprising the water-soluble polyvalent metal salt.
4. A method for making a pigment composition for ink recording media, comprising:
a) providing a first slurry containing an inorganic particulate dispersed in an aqueous medium;
b) adding water-soluble polyvalent metal salt to the first slurry with mixing in an amount and manner effective to provide a second slurry wherein the water-soluble polyvalent metal salt contacts surfaces of the inorganic particulate to provide a surface treated inorganic particulate having a cationic surface charge on the contacted surfaces, wherein the salt is a salt of a metal of Group II or Group III of the Periodic Table;
c) mixing the second slurry containing the surface treated inorganic particulate and a cationic polymer comprising a quaternary amine compound in an aqueous medium to provide a pigment composition.
5. The method according to claim 4 , wherein the pigment composition contains about 45% to about 70% by weight of the surface treated inorganic particulate.
6. The method according to claim 4 , wherein the cationic polymer comprises an epichlorohydrin polyamine.
7. The method according to claim 4 , wherein the inorganic particulate being added to the first slurry in an amount of approximately 1% to approximately 30% by weight.
8. The method according to claim 4 , wherein the inorganic particulate being added to the first slurry in an amount of approximately 20% to approximately 30% by weight.
9. The method according to claim 4 , wherein the polyvalent metal salt being added to the second slurry in amount of approximately 1% to approximately 30% by weight.
10. The method according to claim 4 , wherein the polyvalent metal salt being added to the second slurry in amount of approximately 3% to approximately 20% by weight.
11. The method according to claim 4 , further comprising drying the second slurry effective to provide a powder comprising the surface treated inorganic particulate.
12. The method according to claim 4 , wherein the inorganic particulate provided in the first slurry being selected from the group consisting of ground natural calcium carbonate, precipitated calcium carbonate, aluminum trihydrate, kaolin, and magnesium hydroxide, individually or a combination thereof.
13. The method according to claim 4 , wherein the inorganic particulate provided in the first slurry comprises calcium carbonate and the polyvalent metal salt comprises aluminum chlorohydrate.
14. The method according to claim 4 , wherein the inorganic particulate comprises calcium carbonate particles having a surface area of less than 15 m 2 /g.
15. A method for making a pigment composition for ink recording media, comprising:
1) blending an inorganic particulate and a cationic polymer comprising a quaternary amine compound to provide a first slurry;
2) combining the first slurry with a water-soluble polyvalent metal salt with mixing effective to provide a second slurry wherein the water-soluble polyvalent metal salt contacts surfaces of the inorganic particulate to provide a surface treated inorganic particulate having a cationic surface charge on the contacted surfaces, wherein the second slurry contains salt is a salt of a metal of Group II or Group III of the Periodic Table, wherein the second slurry contains at least about 45% by weight of said surface treated inorganic particulate.