IP Library Granted Patent US 6,946,498
Granted Patent B2
US 6,946,498 · App. 10/480,721 · Granted Sep 20, 2005

Coating composition and article coated with the composition

Assignee: Nippon Arc Co., Ltd.
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Quick Facts
Patent No.
US 6,946,498
App. No.
10/480,721
Granted
Sep 20, 2005
Kind
B2
Abstract

A coating composition comprising (1) an anionic surfactant comprising a sulfonic acid salt, (2) a sol of fine inorganic oxide particles, (3) a silicon compound having one acryl or methacryl group and a hydrolyzable group or a product of hydrolysis of the compound, (4) a compound having at least two photopolymerizable unsaturated groups, and (5) a photopolymerization initiator; and a coated article obtained by applying the coating composition to a base and then photocuring the coating. The coated article combines antifogging properties with abrasion resistance sufficient for practical use.

Claims (21)

1. A coating composition comprising:

(1) an anionic surfactant comprising a sulfonic acid salt;

(2) inorganic oxide microparticles;

(3) a silicon compound, having one acryl group or methacryl group and a hydrolyzable group, or a hydrolysate of the compound;

(4) a compound having at least two photopolymerizable unsaturated groups; and

(5) a photopolymerization initiator.

2. The coating composition as set forth in claim 1 wherein, as non-volatile matter,

the content of said component of (1) is 3 to 10% by weight,

the content of said component of (2) is 30 to 70% by weight,

the content of said component of (3) is 2 to 20% by weight,

the content of said component of (4) is 8 to 64% by weight,

and the content of said component of (5) with respect to 100 weight parts of the total of said components of (1) to (4) is 1 to 100 weight parts.

3. The coating composition as set forth in claim 1 , wherein the anionic surfactant comprising a sulfonic acid salt is at least one surfactant selected from the group consisting of: dialkyl sulfosuccinic acid ester salts, alkyl sulfosuccinic acid dibasic salts, polyoxyethylene alkyl sulfosuccinic acid dibasic salts, sulfosuccinic acid half-ester salts, alkyl sulfoacetic acid salts, alkene (C 8 to C 30 ) monosulfonic acid salts, hydroxyalkane (C 8 to C 24 ) monosulfonic acid salts, N-acylmethyltaurine salts, secondary higher alcohol ethoxysulfates, sulfuric acid ester salts of aliphatic acid alkylolamides, higher alcohol sulfuric acid ester salts, secondary higher alcohol sulfuric acid ester salts, polyoxyethylene alkyl ether sulfuric acid salts, and monoglyceride sulfates.

4. The coating composition as set forth in claim 1 , wherein the inorganic oxide microparticles are microparticles of an oxide of at least one element selected from the group consisting of silicon (Si), aluminum (Al), tin (Sn), antimony (Sb), tantalum (Ta), cerium (Ce), lanthanum (La), iron (Fe), zinc (Zn), tungsten (W), zirconium (Zr), indium (In), and titanium (Ti).

5. The coating composition as set forth in claim 1 , wherein a particle size of the inorganic oxide microparticles is in the range of 1 to 100 nm.

6. The coating composition as set forth in claim 1 , wherein the inorganic oxide microparticles are surface modified by an organosilicon compound or organic compound.

7. The coating composition as set forth in claim 1 , wherein the silicon compound having one acryl group or methacryl group and a hydrolyzable group, or a hydrolysate of the compound is a silicon compound or hydrolysate thereof that is expressed by the general formula:

R 1 R 2 a Si(OR 3 ) 3-a

(where R 1 is a group containing one acryl or methacryl group with 2 to 12 carbon atoms, R 2 is an alkyl group, aryl group, alkenyl group, halogenated alkyl group, or halogenated aryl group with 1 to 6 carbon atoms, the R 3 of the hydrolyzable group OR 3 is hydrogen atoms, or an alkyl group, acyl group, or alkylacyl group with 1 to 4 carbon atoms, and a=0, 1, or 2).

8. The coating composition as set forth in claim 1 , wherein the compound having at least two photopolymerizable unsaturated groups is a compound having at least two functional groups selected from the group consisting of the acryl and methacryl groups, vinyl group, aryl group, epoxy group, thiol group, an episulfide group.

9. An article obtained by coating the coating composition as set forth in claim 1 onto a base and performing photo-curing.

Assignments (4)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 19, 2014
From: SDC TECHNOLOGIES - ASIA, LTD.
To: SDC TECHNOLOGIES, INC.
Reel/Frame 033565/0619 →
CHANGE OF NAME Recorded Jun 27, 2014
From: NIPPON ARC CO., LTD.
To: SDC TECHNOLOGIES-ASIA LTD.
Reel/Frame 033251/0925 →
CHANGE OF NAME Recorded Oct 6, 2005
From: NIPPON ARC CO., LTD.
To: SDC TECHNOLOGIES-ASIA LTD.
Reel/Frame 016851/0363 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 12, 2003
From: KAYANOKI, HISAYUKI
To: NIPPON ARC CO., LTD
Reel/Frame 015306/0368 →
Priority Claims (1)
JP 2001-179080 · Jun 13, 2001 · national
Continuity (1)
Related Publication 20040167280A1 · Aug 26, 2004