IP Library Granted Patent US 7,361,695
Granted Patent B2
US 7,361,695 · App. 10/486,776 · Granted Apr 22, 2008

Process to manufacture flexible polyurethane foams

Assignee: Dow Global Technologies Inc.
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Quick Facts
Patent No.
US 7,361,695
App. No.
10/486,776
Granted
Apr 22, 2008
Kind
B2
Abstract

The present invention is to the production of flexible polyurethane foam in the absence of an amine catalyst. The reactivity of the foam forming system can be controlled by the addition of an autocatalytic polyol containing a tertiary amine where the amount of autocatalytic polyol comprises less than 5 percent by weight of the total polyol.

Claims (10)

1. A process for producing a polyurethane foam comprising the steps of:

providing at least one organic polyisocyanate;

providing a first polyol compound, wherein said polyol having a functionality in the range of 2 to 8 and a hydroxyl number in the range of 20 to 100;

providing an autocatalytic polyol compound having a functionality in the range of 2 to 8 and a hydroxyl number in the range of 15 to 200, wherein said autocatalytic polyol compound comprising at least one tertiary amine group, and said autocatalytic polyol being an amine initiated polyol obtained by alkoxylation of at least one initiator molecule selected from the group consisting of 3,3′-diamino-N-methyldipropylamine, 2,2′-diamino-N-methyldiethylamine, 2,3-diamino-N-methyl-ethyl-propylamine, 3,3′-diamino-N-methyldipropylamine or a mixture thereof;

continuously merging together said organic polyisocyanate, said first polyol, and said autocatalytic polyol compound in the presence of a blowing agent and optionally one or more additives;

optimizing the reaction conditions via adjusting the weight percent ratio of said autocatalytic polyol compound to said first polyol compound in a range of 1:99 weight percent to 5:95 weight percent, based on the total weight of said autocatalytic polyol compound and said first polyol compound; and

thereby producing a flexible polyurethane foam.

2. The process of claim 1 wherein the process is a continuous process for the production of slabstock foam.

3. The process according to claim 1 , wherein the initiator for said first polyol compound being an organic dicarboxylic acid, a dihydric to octahydric alcohol, or dialkylene glycol.

4. The process according to claim 1 , wherein said initiator molecule is 3,3′-diamino-N-methyldipropylamine.

Assignments (7)
CHANGE OF NAME Recorded Aug 2, 2017
From: DOW GLOBAL TECHNOLOGIES INC.
To: DOW GLOBAL TECHNOLOGIES LLC
Reel/Frame 043408/0001 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 29, 2008
From: DOW CHEMICAL TAIWAN LIMITED
To: THE DOW CHEMICAL COMPANY
Reel/Frame 020579/0985 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 29, 2008
From: THE DOW CHEMICAL COMPANY
To: DOW GLOBAL TECHNOLOGIES INC.
Reel/Frame 020580/0001 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 29, 2008
From: COOPER, LANCE A.
To: THE DOW CHEMICAL COMPANY
Reel/Frame 020580/0299 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 29, 2008
From: TU, JOHNSON
To: DOW CHEMICAL TAIWAN LTD.
Reel/Frame 020580/0336 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 29, 2008
From: CASATI, FRANCOIS; SONNEY, JEAN-MARIE LOUIS
To: DOW (EUROPE) S.A.
Reel/Frame 020580/0450 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 29, 2008
From: DOW EUROPE GMBH
To: THE DOW CHEMICAL COMPANY
Reel/Frame 020580/0460 →
Continuity (1)
Related Publication 20040242718A1 · Dec 2, 2004