Ultra high strength steel composition, the process of production of an ultra high strength steel product and the product obtained
The present invention is related to a steel composition, a process for producing a steel product having said composition, and said steel product itself. According to the invention, a cold-rolled, possibly hot dip galvanized steel sheet is produced with thicknesses lower than 1 mm, and tensile strengths between 800 MPa and 1600 MPa, while the A80 elongation is between 5 and 17%, depending on the process parameters. The composition is such that these high strength levels may be obtained, while maintaining good formability and optimal coating quality after galvanising. The invention is equally related to a hot rolled product of the same composition, with higher thickness (typically about 2 mm) and excellent coating quality after galvanising.
1. A hot-rolled ultra high strength steel composition, said composition comprising:
Ti and N, wherein the concentration of N is between 0 and 100 parts per million (ppm mass);
Tifactor =(ppm Ti)−3.42(ppm N)+10 ppm, wherein the Tifactor is between 50 ppm and 400 ppm mass;
and further comprising:
C: between 1000 ppm and 2500 ppm mass
Mn: between 12000 ppm and 20000 ppm mass
Si: between 1500 ppm and 3000 ppm mass
P: between 280 ppm and 600 ppm mass
S: maximum 50 ppm mass
Al: maximum 1000 ppm mass
B: between 10 ppm and 35 ppm mass
Nb: between 200 ppm and 800 ppm mass
Cr: between 2500 ppm and 7500 ppm mass
Mo: between 1000 ppm and 2500 ppm mass
Ca: between 0 and 50 ppm mass
the remainder being substantially iron and incidental impurities;
wherein the hot-rolled ultra high strength steel composition is in sheet form and comprises a thickness between 0.3 mm and 2.0 mm, said steel composition comprising at least a bainitic and a martensitic phase wherein the phase distribution is such that the sum of the bainitic and martensitic phases is higher than 35%, and tensile strength between 1000 MPa and 1600 MPa.
2. The composition of claim 1 , Wherein the amount of carbon is between 1200 ppm and 2500 ppm.
3. The composition of claim 2 , wherein the amount of carbon is between 1200 ppm and 1700 ppm.
4. The composition of claim 3 , wherein the amount of carbon is between 1500 ppm and 1700 ppm.
5. The composition according to claim 1 , wherein the amount of phosphorus is between 500 ppm and 600 ppm.
6. The composition according to claim 1 , wherein the amount of phosphorus is between 280 ppm and 350 ppm.
7. The composition according to claim 1 , wherein the amount of niobium is between 250 ppm and 550 ppm.
8. The composition according to claim 1 , wherein the amount of niobium is between 450 ppm and 550 ppm.
9. The composition of claim 1 , wherein the composition comprises Ti and the concentration of Ti is between 40 ppm to 732 ppm.
10. The composition of claim 1 , wherein P is between 300 ppm and 600 ppm.
11. The composition of claim 1 , wherein P is between 310 ppm and 600 ppm.
12. The hot-rolled composition according to claim 1 , wherein said composition is futher cold-rolled and wherein the sum of bainitic and martensitic phases is higher than 40%.
13. A steel product produced in a process comprising a hot-rolling step, the product being produced from a steel composition comprising:
N, wherein the concentration of N is between 0 and 100 parts per million (ppm mass);
Tifactor =(ppm Ti)−3.42(ppm N)+10 ppm, wherein the Tifactor is between 50 ppm and 400 ppm mass;
and further comprising:
C : between 1000 ppm and 2500 ppm mass
Mn : between 12000 ppm and 20000 ppm mass
Si : between 1500 ppm and 3000 ppm mass
P : between 280 ppm and 600 ppm mass
S : maximum 50 ppm mass
Al : maximum 1000 ppm mass
B : between 10 ppm and 35 ppm mass
Nb : between 200 ppm and 800 ppm mass
Cr : between 2500 ppm and 7500 ppm mass
Mo : between 1000 ppm and 2500 ppm mass
Ca : between 0 and 50 ppm mass
the remainder being substantially iron and incidental impurities;
wherein said product is a steel sheet of thickness between 0.3 mm and 2.0 mm, said product comprising at least a bainitic phase and a martensitic phase wherein the phase distribution is such that the sum of bainitic and martensitic phases is higher than 35%, and tensile strength between 1000 MPa and 1600 MPa.
14. The product according to claim 13 , having a yield strength between 350 MPa and 1150 MPa and an elongation A80 between 5% and 17%.
15. The product according to claim 13 , having a yield strength between 550 MPa and 950 MPa and an elongation A80 between 5% and 17%.
16. The product according to claim 13 , having a bake hardening BH2 higher than 60 MPa in both longitudinal and transversal directions.
17. The product according to claim 13 , wherein the composition comprises Ti and the concentration of Ti is between 40 ppm to 732 ppm.
18. The product according to claim 13 , wherein P is between 300 ppm and 600 ppm.
19. The product according to claim 13 , wherein P is between 310 ppm and 600 ppm.
20. The product according to claim 13 , wherein said process further comprises a cold rolling step and wherein the sum of bainitic and martensitic phases is higher than 40%.
21. The product according to claim 13 , wherein said process comprises the steps of:
preparing a steel slab having a composition comprising:
N, wherein the concentration of N is between 0 and 100 ppm mass;
Tifactor =(ppm Ti)−3.42(ppm N)+10 ppm, wherein the Tifactor is between 50 ppm and 400 ppm mass;
and further comprising:
C : between 1000 ppm and 2500 ppm mass
Mn : between 12000 ppm and 20000 ppm mass
Si : between 1500 ppm and 3000 ppm mass
P : between 280 ppm and 600 ppm mass
S : maximum 50 ppm mass
Al : maximum 1000 ppm mass
B : between 10 ppm and 35 ppm mass
Nb : between 200 ppm and 800 ppm mass
Cr : between 2500 ppm and 7500 ppm mass
Mo : between 1000 ppm and 2500 ppm mass
Ca : between 0 and 50 ppm mass
the remainder being substantially iron and incidental impurities;
hot rolling said slab, wherein the finishing roiling temperature is higher than the Ar3 temperature, to form a hot-rolled substrate;
cooling the hot rolled substrate to a coiling temperature CT;
coiling said substrate at a coiling temperature CT comprised between 450° C. and 750° C.; and
pickling said substrate to remove oxides.
22. The product according to claim 21 , wherein said coiling temperature CT is higher than a bainite start temperature Bs.
23. The product according to claim 21 , wherein the process further comprises the step of re-heating said slab to at least 1000° C. before said hot rolling step.
24. The product according to claim 21 , wherein the process further comprises the steps of:
soaking said substrate at a temperature between 480° C. and 700° C., during less than 80 s,
cooling said substrate down to the temperature of a zinc bath at a cooling rate higher than 2° C./s,
hot dip galvanising said substrate in said zinc bath, and
final cooling said substrate to room temperature at a cooling rate higher than 2° C./s.
25. The product according to claim 21 , wherein the process is followed by a step of skinpass reduction of said substrate, with a maximum reduction of 2%.
26. The product according to claim 21 , wherein the process is followed by a step of electrolytic zinc coating.
27. The product according to claim 21 , wherein the process further comprises the steps of:
cold rolling said substrate to obtain a reduction of thickness,
annealing said substrate up to a maximum soaking temperature comprised between 720° C. and 860° C.,
cooling said substrate with a cooling rate higher than 2° C./s down to a temperature of maximum 460° C.,
holding said substrate said temperature of maximum 460° C. for a time less than 250s, and
final cooling said substrate to room temperature at a cooling rate higher than 2° C./s.
28. The product according to claim 21 , wherein the process further comprises the steps of:
cold rolling said substrate to obtain a reduction of thickness,
annealing said substrate up to a maximum soaking temperature comprised between 720° C. and 860° C.,
cooling said substrate with a cooling rate higher than 2° C./s to the temperature of a zinc bath,
hot dip galvanising said substrate in said zinc bath, and
final cooling said substrate to room temperature at a cooling rate higher than 2° C./s.
29. The product according to claim 21 , wherein the process further comprises the steps of:
cold rolling said substrate to obtain a reduction of thickness,
annealing said substrate up to a maximum soaking temperature comprised between 720° C. and 860° C.,
cooling said substrate with a cooling rate higher than 2 ° C./s down. to a temperature of maximum 200° C., and
final cooling said substrate to room temperature at a cooling rate higher than 2° C./s.
30. The product according to claim 29 , wherein the process is followed by a step of skinpass reduction of said substrate, with a maximum reduction of 2%.
31. The product according to claim 29 , wherein the process is followed by a step of electrolytic zinc coating.