Coated granular substances
The invention relates to a coated granular material, wherein the coating is a resin, comprising the reaction producing of at least one compound selected from the group consisting of cardol, cardanol or derivatives or oligomers of these compounds with an isocyanate component, and to a method for the preparation thereof. Water-soluble granular materials are suitable as substances to be coated. Examples of granular substances are fertilizers, crop protection agents, insecticides, pesticides, fungicides, drying agents and mixtures thereof. The substance coated according to the invention has advantageous properties since the resin can be applied in a selective and economical manner to the substrates due to its low tackiness. In particular, coated fertilizer granulates are advantageous in that, with regard to the applied amount of fertilizer, they can provide more nutrients to the plant. In addition, fertilizers can be provided that can provide nutrients to the plant over a longer period of time and continuously and they have an exact and reproducible release behavior according to the type of plant to be treated. Furthermore, the polyol component of the coating can be obtained from the renewable raw material cashew nut oil.
1. A granular material coated with a resin comprising the reaction product of:
(a) a polyol component, wherein the polyol component comprises a condensation product of:
(i) a phenol, wherein the phenol does not include a cardanol;
(ii) an aldehyde; and
(iii) cardanol; and
(b) an isocyanate component.
2. The coated granular material according to claim 1 , wherein the resin comprises the reaction product of:
(a) the polyol component;
(b) the isocyanate component; and
(c) a plasticizer containing hydroxyl groups and/or a diluting agent containing hydroxyl groups and/or further drying agents and/or molecular sieves and/or wetting additives and/or flow-control additives.
3. The coated granular material according to claim 1 , wherein the isocyanate component of the resin is an aliphatic, aromatic or heterocyclic isocyanate having at least 2 isocyanate groups in one molecule or oligomers or polymers thereof.
4. The coated granular material according to claim 3 , wherein the isocyanate component is toluene diisocyanate, diphenylmethane diisocyanate or an oligomer based thereon.
5. The coated granular material according to claim 1 , wherein the granular material is water-soluble.
6. The coated granular material according to claim 1 , selected from the group consisting of fertilizers, crop protection agents, insecticides, pesticides, fungicides, drying agents and suitable mixtures thereof.
7. The coated granular material according to claim 1 , wherein the granular material is an NPK fertilizer.
8. The coated granular material according to claim 1 , wherein the amount of the coating is 3 to 15 wt.-% based on the amount of the granular material.
9. The coated granular material according to claim 1 , wherein the grain size of the granular material is 1 to 10 mm.
10. A method for the preparation of a coated granular material as defined in claim 1 , comprising the steps of:
(a) providing a granular material;
(b) providing the polyol component and the isocyanate component;
(c) optionally mixing the polyol component and the isocyanate component;
(d) adding the mixture of step (c) or the polyol component and the isocyanate component as individual substances to the provided granular material and generating a coating on the granular material;
(e) curing the mixture of step (d); and
(f) optionally repeating steps (d) and (e) to apply the coating to the granular material in several cycles.
11. The method according to claim 10 , wherein 2 to 10 coating cycles are carried out.
12. The method according to claim 10 , wherein an amine catalyst is used for the curing in step (e).
13. The coated granular material according to claim 1 , wherein the resin comprises the reaction product of:
(a) the polyol component;
(b) the isocyanate component; and
(c) cardanol.
14. The coated granular material according to claim 1 , wherein the resin comprises the reaction product of:
(a) the polyol component;
(b) the isocyanate component; and
(c) oligomers which remain at the bottom of a reaction apparatus after cashew nut oil has been heated and cardol and cardanol have been distilled off.
15. The coated granular material according to claim 1 , wherein the polyol component comprises a condensation product of:
(i) phenol;
(ii) formaldehyde; and
(iii) cardanol.
16. A granular material coated with a resin comprising the reaction product of:
(a) a polyol component, wherein the polyol component comprises a condensation product of:
(i) a phenol; and
(ii) an aldehyde; and
(b) an isocyanate component; and
(c) cardanol.
17. The coated granular material according to claim 16 , wherein the condensation product of a phenol and an aldehyde comprises novolaks or benzyl ether resins.
18. The coated granular material according to claim 16 , wherein the resin comprises the reaction product of:
(a) the polyol component;
(b) the isocyanate component; and
(c) oligomers which remain at the bottom of a reaction apparatus after cashew nut oil has been heated and cardol and cardanol have been distilled off.
19. The coated granular material according to claim 16 , wherein the resin comprises the reaction product of:
(a) the polyol component;
(b) the isocyanate component;
(c) cardanol; and
(d) a plasticizer containing hydroxyl groups and/or a diluting agent containing hydroxyl groups and/or further drying agents and/or molecular sieves and/or wetting additives and/or flow-control additives.
20. The coated granular material according to claim 16 , wherein the isocyanate component comprises a mixture of oligomers and isomers on the basis of diphenylmethane diisocyanate.