Material for imparting thixotropy and pasty resin composition
Surface-treated calcium carbonate characterized by giving, upon analysis by the method of mercury penetration, a void diameter distribution curve which has a peak for the most probable void diameter at smaller than 0.03 μm and has a most probable void volume of 0.05 to 0.5 cm 3 /g; and a pasty resin composition containing the surface-treated calcium carbonate. The calcium carbonate preferably comprises one obtained by surface-treating calcium carbonate having a BET specific surface area of 10 to 100 m 2 /g with an unsaturated fatty acid (A) and a saturated fatty acid (B).
1. A material for imparting thixotropy comprising surface-treated calcium carbonate which results from surface treatment of calcium carbonate having a BET specific surface area of 10–100 m 2 /g with an unsaturated fatty acid (A) and a saturated fatty acid (B), characterized in that said material for imparting thixotropy exhibits a modal pore size peak at below 0.03 μm and a modal pore volume of 0.05–0.5 cm 3 /g on a pore size distribution curve derived from mercury porosimetry, and the (A)/(B) blending ratio of said unsaturated fatty acid (A) and saturated fatty acid (B) is 0.5–1.9.
2. The material for imparting thixotropy as recited in claim 1 , characterized in that said unsaturated fatty acid (A) and saturated fatty acid (B) are used in their metal salt or ester forms to effect the surface treatment.
3. The material for imparting thixotropy as recited in claim 1 , characterized in that said unsaturated fatty acid (A) and saturated fatty acid (B) have a carbon number of 6–31, respectively.
4. A paste resin composition containing surface-treated calcium carbonate which results from surface treatment of calcium carbonate having a BET specific surface area of 10–100 m 2 /g with an unsaturated fatty acid (A) and a saturated fatty acid (B), characterized in that said surface-treated calcium carbonate exhibits a modal pore size peak at below 0.03 μm and a modal pore volume of 0.05–0.5 cm 3 /g on a pore size distribution curve derived from mercury porosimetry, and the (A)/(B) blending ratio of said unsaturated fatty acid (A) and saturated fatty acid (B) is 0.5–1.9.
5. A paste resin composition as recited in claim 4 , characterized in that said unsaturated fatty acid (A) and saturated fatty acid (B) are used in their metal salt or ester forms to effect the surface treatment.
6. A paste resin composition as recited in claim 4 , characterized in that said unsaturated fatty acid (A) and saturated fatty acid (B) have a carbon number of 6–31, respectively.
7. The paste resin composition as recited in claim 4 , characterized as constituting a polyurethane sealant.
8. The paste resin composition as recited in claim 4 , characterized as constituting a modified silicone sealant.
9. The paste resin composition as recited in claim 4 , characterized as constituting a silicone sealant.
10. The paste resin composition as recited in claim 4 , characterized as constituting a polysulfide sealant.
11. The paste resin composition as recited in claim 4 , characterized as constituting a polyvinyl chloride sol.
12. The paste resin composition as recited in claim 4 characterized as constituting an acrylic sol.