Polarizing plate
View Patent ↗A polarizing plate has a polarizer and a protective film formed on at least one surface of the polarizer. The protective film is formed by curing an energy ray-curable composition that contains at least one of a first energy ray-polymerizing compound having a bisphenol residue, a second energy ray-polymerizing compound having a neopentylglycol group, a third energy ray-polymerizing compound having a trimethylolpropane group, and a fourth energy ray-polymerizing compound having a pentaerythritol group. In the polarizing plate, though the protective film is thin, the polarizer is protected from the influence of external moisture, etc., and therefore its polarizability is kept good even in high-temperature high-humidity environments.
1. A polarizing plate having a polarizer obtained from iodine-coloring a polyvinyl alcohol resin film, and a protective film directly formed on both surfaces of the polarizer, wherein the protective film has a thickness of 40 μm or less, and is formed by applying an energy ray-curable composition to the polarizer and irradiating the applied energy ray-curable composition with ultraviolet rays to polymerize and cure the energy ray-curable composition, wherein
the energy ray-curable composition comprises an energy ray-polymerizing compound having a neopentylglycol group in an amount of at least 40% by weight in terms of a resin solid content thereof,
selected from the group consisting of:
the polyvinyl alcohol is dyed only with iodine.
2. The polarizing plate according to claim 1 , wherein the energy ray-curable composition contains the first energy ray-polymerizing compound having a bisphenol residue.
3. The polarizing plate according to claim 2 , wherein the energy ray-curable composition comprises the energy ray-polymerizing compounds in an amount of 50% by weight in terms of the resin solid content thereof.
4. The polarizing plate according to claim 2 , wherein the energy ray-polymerizing compound having a bisphenol residue has a bisphenol A-type group.
5. The polarizing plate according to claim 2 , wherein the energy ray-polymerizing compound having a bisphenol group has a bisphenol F-type group.
6. The polarizing plate according to claim 1 , wherein the energy ray-curable composition further comprises an energy ray-polymerizing compound that comprises a polyester (meth)acrylate.
7. A liquid-crystal display device having a liquid crystal panel, and the polarizing plate of any of claim 1 provided on at least one surface of the liquid-crystal panel.
8. A polarizing plate having a polarizer obtained form iodine-coloring a polyvinyl alcohol resin film, and a protective film directly formed on both surfaces of the polarizer, wherein the protective film has a thickness of 40 μm or less, and is formed by applying and energy ray-curable composition to the polarizer and irradiating the applied energy ray-curable composition with ultraviolet rays to polymerize and cure the energy ray-curable composition, wherein,
the energy ray-curable composition that comprises at least one of (a) an energy ray-polymerizing compound having a neopentylglycol group, and (b) an energy ray-polymerizing compound having a pentaerythritol group,
the energy ray polymerizing compound having a neopentylglycol group is selected from the group consisting of:
the energy ray polymerizing compound having a pentaerithritol group is one of the following chemical formulae:
in which R represents a hydrogen atom or a methyl group,
the polyvinyl alcohol is dyed only with iodine, and
the energy ray-curable composition comprises an energy ray-polymerizing compound having a trimethylolpropane group in an amount of a least 60% by weight in terms of the resin solid content thereof.
9. The polarizing plate according to claim 8 , wherein the energy ray-curable composition further comprises and energy ray-polymerizing compound having a bisphenol residue.
10. The polarizing plate according to claim 9 , wherein the energy ray-curable composition comprises the energy ray-polymerizing compound having a bisphenol residue in an amount of at least 20% by weight in terms of the resin solid content thereof.
11. The polarizing plate according to claim 9 , wherein the energy ray-polymerizing compound having a bisphenol residue has a bisphenol A-type group.
12. The polarizing plate according to claim 9 , wherein the energy ray-polymerizing compound having a bisphenol group has a bisphenol F-type group.
13. The polarizing plate according to claim 8 , wherein the energy ray-curable composition further comprises and energy ray-polymerizing compound that comprises a polyester (meth) acrylate.
14. A liquid-crystal display device having a liquid crystal panel, and the polarizing plate of claim 8 , provided on at least one surface of the liquid-crystal panel.
15. A polarizing plate having a polarizer obtained from iodine-coloring a polyvinyl alcohol resin film, and a protective film directly formed on both surfaces of the polarizer, wherein the protective film has a thickness of 40 μm or less, and is formed by applying an energy ray-curable composition to the polarizer and irradiating the applied energy ray-curable composition with ultraviolet rays to polymerize and cure the energy ray-curable composition, wherein
the energy ray-curable composition consists of any energy ray-polymerizing compound having a pentaerythritol group selected from the group consisting of:
in which R represents a hydrogen atom or a methyl group, and
the polyvinyl alcohol is dyed only with iodine.