Coating of objects
The present invention relates to a process for the coating of objects made of valve metals or their alloys with a thin barrier layer consisting of the metal and an oxide ceramic layer provided thereon whose surface has been coated with fluoropolymers, characterized in that the fluoropolymers are introduced into the capillary system of the oxide ceramic layer in the form of a solution by vacuum impregnation, followed by removing the non-wetting portions of the solution and drying.
1. A process for the coating of objects made of valve metals selected from aluminum, magnesium, titanium, niobium and/or zirconium and their alloys with a thin barrier layer consisting of said metals and an oxide ceramic layer provided thereon whose surface has been coated with a solution containing dissolved fluoropolymers characterized in that the solution is introduced into a capillary system of the oxide ceramic layer by vacuum impregnation, followed by removing non-wetting portions of the solution and drying.
2. The process according to claim 1 , where said oxide ceramic layer comprises a densely sintered oxide ceramic layer disposed on the thin barrier layer and an oxide ceramic layer having a wide-meshed interlinked capillary system applied by plasma-chemical anodic oxidation to said densely sintered oxide ceramic layer.
3. The process according to claim 1 , wherein said oxide ceramic layer has a thickness of from 40 to 150 μm.
4. The process according to claim 1 , wherein the dissolved fluoropolymers of the solution are selected from fluorinated epoxide polymers and silyl ethers.
5. The process according to claim 1 , wherein said coating has a layer thickness of from 1 to 20 μm after the drying.
6. The process according to claim 5 , wherein the layer thickness is from 1 to 5 μm after the drying.
7. The process according to claim 1 , wherein the steps of introducing and drying the dissolved fluoropolymers are repeated several times.