Scintillation substances (variants)
View Patent ↗Inventions relates to scintillation substances and they may be utilized in nuclear physics, medicine and oil industry for recording and measurements of X-ray, gamma-ray and alpha-ray, nondestructive testing of solid states structure, three-dimensional positron-emission tomography and X-ray tomography and fluorography. Substances based on silicate comprising lutetium and cerium characterized in that compositions of substances are represented by chemical formulae Ce x Lu 2+2y−x Si 1−y O 5+y , Ce x Li q+p Lu 2−p+2−y−x−z A z Si 1−y O 5+y−p , Ce x Li q+p Lu 9.33−x−p−z □ 0.67 A z Si 6 O 26−p , where A is at least one element selected from group consisting of Gd, Sc, Y, La, Eu, Tb, x is value between 1×10 −4 f.units and 0.02 f.units., y is value between 0.024 f.units and 0.09 f.units, z is value does not exceeding 0.05 f.units, q is value does not exceeding 0.2 f.units, p is value does not exceeding 0.05 f.units. Achievable technical result is the scintillating substance having high density, high light yield, low afterglow, and low percentage loss during fabrication of scintillating elements.
1. A scintillation substance based on a silicate comprising a lutetium (Lu) and cerium (Ce) characterized in that the composition of the substance is represented by the chemical formula
Ce x Lu 2+2y−x Si 1−y O 5+y ,
x is a value between 1×10 −4 f.u. and 0.02 f.u.,
y is a value between 0.024 f.u. and 0.09 f.u.
2. A scintillation substance according to claim 1 , characterised in that the composition of the substance in the form of a single crystal is represented by the chemical formula
Ce x Lu 2.076−x Si 0.962 O 5.038 ,
x is a value between 1×10 −4 f.u. and 0.02 f.u.
3. A method of making the scintillating substance according to claim 1 , characterised in that a single crystal is being grown by a directional crystallization method from a melt made from the charge of the composition defined by mole ratio of oxides 51.9% (Lu 2 O 3 +Ce 2 O 3 )/48.1% SiO 2 .
4. A method of making the scintillating substance according to claim 1 , characterised in that a single crystal is being grown by Czochralski method from a melt made from the charge of the composition defined by mole ratio of oxides 51.9% (Lu 2 O 3 +Ce 2 O 3 )/48.1% SiO 2 .
5. A scintillation substance based on a silicate comprising a lutetium (Lu) and cerium (Ce) characterised in that the composition of the substance in the form of a single crystal is represented by the chemical formula
Ce x Lu 2+2y−x−z A z Si 1−y O 5+y ,
where A is at least one element selected from the group consisting of Gd, Sc, Y, La, Eu, Tb, and Ca,
x is a value between 1×10 −4 f.u. and 0.02 f.u.,
y is a value between 0.024 f.u. and 0.09 f.u.,
z is a value between 1×10 −4 f.u. and 0.05 f.u.
6. The scintillation substance according to claim 5 , characterised in that the composition of the substance in the form of a single crystal is represented by the chemical formula
Ce x Lu 2.076−x−z A z Si 0.962 O 5.038 ,
where A is at least one element selected from the group consisting of Gd, Sc, Y, La, Eu, Tb, and Ca,
x is a value between 1×10 −4 f.u. and 0.02 f.u.,
z is a value between 1×10 −4 f.u. and 0.05 f.u.
7. The scintillation substance according to claim 5 , characterised in that the composition of the substance in the form of a single crystal is represented by the chemical formula
Ce x Lu 2.076−x−m−n La m Y n Si 0.962 O 5.038 ,
x is a value between 1×10 −4 f.u. and 0.02 f.u.,
m is a value does not exceeding 0.05 f.u.,
n is a value between 1×10 −4 f.u. and 2.0 f.u.
8. A method of making the scintillating substance according to claim 5 , characterised in that a single crystal is being grown by a directional crystallization method from a melt made from the charge of the composition defined by mole ratio of oxides 51.9% (Lu 2 O 3 +A 2 O 3 +Ce 2 O 3 )/48.1% SiO 2, where A is at least one element selected from the group consisting of Gd, Sc, Y, La, Eu, Tb, and Ca.
9. A method of making the scintillating substance according to claim 5 , characterised in that an oversized crystal is being grown by Kyropoulos method from a melt made from the charge of the composition defined by mole ration of oxides 51.9% (Lu 2 O 3 +A 2 O 3 +Ce 2 O 3 )/48.1% SiO 2, where A is at least one element selected from the group consisting of Gd, Sc, Y, La, Eu, Tb, and Ca.
10. A scintillation substance based on a silicate comprising lutetium (Lu) and cerium (Ce) characterised in that it contains a lithium Li in a quantity that does not exceed 0.25 f.u. and its composition is represented by the chemical formula
Ce x Li q+p Lu 2−p+2y−x Si 1−y O 5+y−p
x is a value between 1×10 −4 f.u. and 0.02 f.u.,
y is a value between 0.024 f.u. and 0.09 f.u.,
q is a value between 1×10 −4 f.u. and 0.02 f.u.,
p is a value between 1×10 −4 f.u. and 0.05 f.u.
11. A scintillation substance according to claim 10 , characterised in that the composition of the substance in the form of a single crystal containing lithium Li in a quantity that does not exceed 0.25 f.u. and is represented by the chemical formula
Ce x Li q+p Lu 2.076−p−x Si 0.962 O 5.038−p ,
x is a value between 1×10 −4 f.u. and 0.02 f.u.,
q is a value between 1×10 −4 f.u. and 0.2 f.u.,
p is a value between 1×10 −4 f.u. and 0.05 f.u.
12. A method of making the scintillating substance according to claim 10 , characterised in that a single crystal is being grown by a directional crystallization method from a melt made from the charge of the composition defined by mole ratio of oxides 51.9% (Lu 2 O 3 +Li 2 O+Ce 2 O 3 )/48.1% SiO 2 .
13. A scintillation substance based on a silicate comprising lutetium (Lu) and cerium (Ce) characterised in that it contains a lithium Li in a quantity that does not exceed 0.25 f.u. and its composition is represented by the chemical formula
Ce x Li q+p Lu 2−p+2y−x−z A z Si 1−y O 5+y−p ,
where A is at least one element selected from the group consisting of Gd, Sc, Y, La, Eu, and Tb,
x is a value between 1×10 −4 f.u. and 0.02 f.u.,
y is a value between 0.024 f.u. and 0.09 f.u.,
z is a value between 1×10 −4 f.u. and 0.05 f.u.,
q is a value between 1×10 −4 f.u. and 0.2 f.u.,
p is a value between 1×10 −4 f.u. and 0.05 f.u.
14. The scintillation substance according to claim 13 , characterised in that the composition of the substance in the form of a single crystal containing lithium Li in a quantity that does not exceed 0.25 f.u. and is represented by the chemical formula
Ce x Li q+p Lu 2.076−p−x−z A z Si 0.962 O 5.038−p ,
where A is at least one element selected from the group consisting of Gd, Sc, Y, La, Eu, and Tb,
x is a value between 1×10 −4 f.u. and 0.02 f.u.,
z is a value between 1×10 −4 f.u. and 0.05 f.u.,
q is a value between 1×10 −4 f.u. and 0.2 f.u.,
p is a value between 1×10 −4 f.u. and 0.05 f.u.
15. A method of making the scintillating substance according to claim 13 , characterised in that a single crystal is being grown by a directional crystallization method from a melt made from the charge of the composition defined by mole ratio of oxides 51.9% (Lu 2 O 3 +Li 2 O+A 2 O 3 +Ce 2 O 3 )/48.1% SiO 2 .
16. A scintillation substance based on a silicate comprising lutetium (Lu) and cerium (Ce) characterised in that it contains lithium Li and its composition is represented by the chemical formula
Ce x Li q+p Lu 9.33−x−p □ 0.67 Si 6 O 26−p ,
x is a value between 1×10 −4 f.u. and 0.1 f.u.,
q is a value between 1×10 −4 f.u. and 0.3 f.u.,
p is a value between 1×10 −4 f.u. and 0.25 f.u.
17. A scintillation substance based on a silicate comprising lutetium (Lu) and cerium (Ce) characterised in that it contains lithium Li and its composition is represented by the chemical formula
Ce x Li q+p Lu 9.33−x−p−z □ 0.67 A z Si 6 O 26−p ,
where A is at least one element selected from the group consisting of Gd, Sc, Y, La, Eu, and Tb,
x is a value between 1×10 −4 f.u. and 0.1 f.u.,
q is a value between 1×10 −4 f.u. and 0.3 f.u.,
p is a value between 1×10 −4 f.u. and 0.25 f.u.,
z is a value between 5×10 −4 f.u. and 8.9 f.u.
18. A scintillation substance based on a silicate comprising lutetium (Lu) and cerium (Ce) characterised in that it contains lithium Li and its composition is represented by the chemical formula
Ce x LiLu 9−x Si 6 O 26 ,
x is a value between 1×10 −4 f.u. and 0.1 f.u.
19. A scintillation substance based on a silicate comprising lutetium (Lu) and cerium (Ce) characterised in that it contains lithium Li in a quantity exceeding 1.0 f.u. and its composition is represented by the chemical formula
Ce x Li 1+q+p Lu 9−x−p Si 6 O 26−p ,
x is a value between 1×10 −4 f.u. and 0.1 f.u.,
q is a value between 1×10 −4 f.u. and 0.3 f.u.,
p is a value between 1×10 −4 f.u. and 0.25 f.u.
20. A scintillation substance based on a silicate comprising lutetium (Lu) and cerium (Ce) characterised in that it contains lithium Li in a quantity exceeding 1.0 f.u. and its composition is represented by the chemical formula
Ce x Li 1+q+p Lu 9−x−p−z A z Si 6 O 26−p ,
where A is at least one element selected from the group consisting of Gd, Sc, Y, La, Eu, and Tb,
x is a value between 1×10 −4 f.u. and 0.1 f.u.,
q is a value between 1×10 −4 f.u. and 0.3 f.u.,
p is a value between 1×10 −4 f.u. and 0.25 f.u.,
z is a value between 5×10 −4 f.u. and 8.9 f.u.