Flame retardant composition and flame retardant resin composition containing the composition
A flame retardant composition includes, as essential components having two specified types of phosphate compounds; silicon dioxide or metal oxides; and at least one member selected from among higher aliphatic carboxylic acids, metal salts of higher aliphatic carboxylic acid, higher fatty acid amide compounds, and esters between mono- or polyhydric alcohols and higher aliphatic carboxylic acids. This flame retarder composition is free from secondary agglomeration, and does not need incorporation of a halogenated flame retarder that when blended in a synthetic resin, releases harmful gas at combustion. The flame retardant composition enables imparting flame retardant properties to synthetic resins with the use of a small amount of flame retarder.
1 - 13 . (canceled)
14 . A flame retardant composition comprising:
(A) a phosphate compound (a) represented by general formula (1):
wherein n represents a number of 1 to 100; X 1 represents ammonia or a triazine derivative represented by formula (2): and 0<p≦n+2:
wherein Z 1 and Z 2 , which may be the same or different, each represents a group selected from the group consisting of —NR 5 R 6 (wherein R 5 and R 6 , which may be the same or different, each represents a hydrogen atom, a straight-chain or branched alkyl group having 1 to 6 carbon atoms or a methylol group), a hydroxy group, a mercapto group, a straight-chain or branched alkyl group having 1 to 10 carbon atoms, a straight-chain or branched alkoxy group having 1 to 10 carbon atoms, a phenyl group, and a vinyl group;
(B) a phosphate compound (b) represented by general formula (3):
wherein r represents a number of 1 to 100; Y 1 represents [R 1 R 2 N(CH 2 ) m NR 3 R 4 ], piperazine or a diamine containing a piperazine ring; R 1 , R 2 , R 3 , and R 4 , which may be the same or different, each represents a hydrogen atom or a straight-chain or branched alkyl group having 1 to 5 carbon atoms; m represents an integer of 1 to 10; and 0<q≦r+2;
(C) silicon dioxide
(D) at least one member selected from higher aliphatic carboxylic acids, metal salts of higher aliphatic carboxylic acid, higher fatty acid amide compounds, and esters between mono- or polyhydric alcohols and higher aliphatic carboxylic acids.
15 . The flame retardant composition according to claim 14 , wherein the compounding ratio of component (A) represented by general formula (1) to component (B) represented by general formula (3) is 20/80 to 60/40 by mass, and components (C) and (D) are each present in an amount of 0.01 to 10 parts by mass per 100 parts by mass of the total of components (A) and (B).
16 . The flame retardant composition according to claim 14 , wherein component (A) is melamine pyrophosphate of general formula (1) in which n is 2, p is 2, and X 1 is melamine of general formula (2) in which Z 1 and Z 2 are each —NH 2 .
17 . The flame retardant composition according to claim 14 , wherein component (B) is a piperazine polyphosphate of general formula (3) in which q is 1, and Y 1 is piperazine.
18 . The flame retardant composition according to claim 17 , wherein the piperazine polyphosphate is piperazine pyrophosphate.
19 . The flame retardant composition according to claim 14 , wherein the silicon dioxide as component (C) is hydrophobic silica.
20 . The flame retardant composition according to claim 14 , wherein component (D) is stearic acid.
21 . The flame retardant composition according to claim 14 , wherein component (D) is ethylenebis(stearamide).
22 . A flame-retardant resin composition comprising a synthetic resin having incorporated therein the flame retardant composition according to claim 14 .
23 . The flame-retardant resin composition according to claim 22 , wherein the flame retardant composition is present in an amount of 5 to 50 parts by mass per 100 parts by mass of the synthetic resin.
24 . The flame-retardant resin composition according to claim 22 , wherein the synthetic resin is polyolefin resin.
25 . The flame-retardant resin composition according to claim 24 , wherein the polyolefin resin is polypropylene resin or polyethylene resin.
26 . A flame-retardant resin composition comprising a synthetic resin having incorporated therein the flame retardant composition according to claim 15 .
27 . A flame-retardant resin composition comprising a synthetic resin having incorporated therein the flame retardant composition according to claim 16 .
28 . A flame-retardant resin composition comprising a synthetic resin having incorporated therein the flame retardant composition according to claim 17 .
29 . A flame-retardant resin composition comprising a synthetic resin having incorporated therein the flame retardant composition according to claim 18 .
30 . A flame-retardant resin composition comprising a synthetic resin having incorporated therein the flame retardant composition according to claim 19 .
31 . A flame-retardant resin composition comprising a synthetic resin having incorporated therein the flame retardant composition according to claim 20 .
32 . A flame-retardant resin composition comprising a synthetic resin having incorporated therein the flame retardant composition according to claim 21.