Low work function metal complexes and uses thereof
View Patent ↗The present invention provides conductive metal-ligand coordination complexes that are useful in a variety of electronic devices. For example, such complexes are useful in organic light emitting devices composed of one or more layers of organic material between two conductors. The use of metal-ligand coordination complexes of the present invention as the cathode, replaces the more typically employed reactive metals, which function as the electron injecting contact, and provides for improved or longer-lived devices.
1. An electrode composition comprising:
a current conducting material; and
a heteroaryl-metal complex in contact with said current conducting material, wherein said heteroaryl-metal complex is of the formula:
[M-(L) a ] m Y n
wherein
a is an integer from 1 to 6;
m and n are absolute value of oxidation state of Y or [M-(L) a ], respectively; or if [M-(L) a ] is not charged Y is not present and said heteroaryl-metal complex is of the formula M(L) a ;
M is a metal;
Y is a counterion; and
each L is independently a heteroaryl moiety containing one or more coordinating heteroatoms.
2. The electrode composition of claim 1 having work function of about 3.5 eV or less.
3. The electrode composition of claim 1 , wherein said heteroaryl-metal complex is of the formula M-(L) a .
4. The electrode composition of claim 3 , wherein a is an integer of 2 or 3.
5. The electrode composition of claim 4 , wherein M is a transition metal.
6. The electrode composition of claim 5 , wherein M is selected from the group consisting of Ru, Cr, Fe, Zn, Co, Mn, Cu, Os, Rh, and Ni.
7. The electrode composition of claim 6 , wherein M is selected from the group consisting of Ru and Cr.
8. The electrode composition of claim 5 , wherein L is a polypyridyl or phenanthroline moiety.
9. The electrode composition of claim 8 , wherein L is selected fiom the group consisting of optionally substituted 2,2′-bipyridyl, optionally substituted 1,10-phenanthroline, optionally substituted 2,2′,6′,2″-terpyridyl and a derivative thereof.
10. The electrode composition of claim 8 , wherein L is a polypyridyl moiety.
11. The electrode composition of claim 10 , wherein L is selected from the group consisting of 4,4′,5 ,5′-tetramethyl-2,2′-bipyridyl; 2,2′-bipyridyl; and 2,2′, 6′, 2″-terpyridy.
12. The electrode composition of claim 1 , wherein said current conducting material is a metal or a metal alloy.
13. The electrode composition of claim 12 , wherein said current conducting material comprises silver, gold or a mixture thereof.
14. An electronic device comprising an electrode of claim 1 .
15. A composition comprising a metal or a metal alloy in contact with a heteroaryl-metal coordination complex, wherein said heteroaryl-metal coordination complex is of the formula:
M-(L) a
wherein
a is an integer from 1 to 6;
M is a metal;
and
each L is independently a heteroaryl moiety containing one or more coordinating heteroatoms.