IP Library Granted Patent US 8,536,396
Granted Patent B2
US 8,536,396 · App. 10/524,640 · Granted Sep 17, 2013

Production of olefins

Inventors: Jean-Pierre Dath (Beloeil, BE); Walter Vermeiren (Houthalen, BE)
Assignee: Total Petrochemicals Research Feluy
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Quick Facts
Patent No.
US 8,536,396
App. No.
10/524,640
Granted
Sep 17, 2013
Kind
B2
Abstract

A process for converting a hydrocarbon feedstock to provide an effluent containing light olefins, the process comprising passing a hydrocarbon feedstock, the feedstock containing at least one C 1 to C 6 aliphatic hetero compound selected from alcohols, ethers, carbonyl compounds and mixtures thereof and steam in an amount whereby the feedstock contains up to 80 weight % steam, through a reactor containing a crystalline silicate catalyst to produce an effluent including propylene, the crystalline silicate having been subjected to de-alumination by a steaming step and being selected from at least one of an MFI-type crystalline silicate having a silicon/aluminium atomic ratio of from 250 to 500 and an MEL-type crystalline silicate having a silicon/aluminium atomic ratio or from 150 to 800.

Claims (22)

1. A process for converting a carbon containing feedstock to provide an effluent containing light olefins, the process comprising:

forming a catalyst, wherein the catalyst is formed by

supplying an MEL crystalline silicate catalyst;

steam treating the MEL crystalline silicate catalyst;

after steam treating, contacting the MEL crystalline silicate catalyst with a complexing agent for aluminum;

after contact with the complexing agent, reducing the sodium content of the MEL crystalline silicate catalyst by subjecting the MEL crystalline silicate catalyst to ion exchange with a salt;

calcining the MEL crystalline silicate catalyst after reducing the sodium content of the MEL crystalline silicate catalyst;

passing a feedstock containing carbon containing compounds consisting essentially of C 1 to C 6 aliphatic hetero compounds selected from the group consisting of alcohols, ethers, carbonyl compounds and mixtures thereof and containing steam in an amount up to 80 weight % of said feedstock, through a reactor containing the catalyst to produce an effluent including propylene which is recovered from the reactor, wherein the feedstock is passed over the crystalline silicate at a reactor inlet temperature of about 550° C.

2. A process according to claim 1 wherein the carbon containing feedstock contains at least one hetero compound selected from the group consisting of methanol, ethanol, dimethyl ether, diethyl ether and mixtures thereof.

3. A process according to claim 1 wherein the carbon containing feedstock is passed over the crystalline silicate at a WHSV of from 0.5 to 30 h −1 ,the WHSV being based on the weight of the at least one C 1 to C 6 aliphatic hetero compound in the feedstock.

4. A process according to claim 3 wherein the partial pressure of the at least on C 1 to C 6 aliphatic hetero compound in the feedstock when passed over the crystalline silicate is from 20 to 400 kPa.

5. The process of claim 1 wherein said feedstock comprises methanol and said reactor is operated under conversion conditions comprising an inlet temperature within the range of 450-550° C.

6. The process of claim 5 wherein said reactor is operated under conversion conditions providing a product containing propylene and ethylene and having a propylene/ethylene ratio which is greater than the propylene/ethylene ratio of a conversion product produced by the conversion of a methanol-containing feedstock operated at an inlet temperature in said reactor of 400° C.

7. The process of claim 5 wherein said reactor is operated under conversion conditions providing a product containing propylene and propane and having a propylene/propane ratio which is greater than the propylene/propane ratio of a conversion product produced by the conversion of a methanol-containing feedstock operated at an inlet temperature of 400° C.

8. The process of claim 1 , wherein the effluent comprises a propylene/ethylene weight ratio ranging from 2 to 10.

9. The process of claim 1 , wherein the effluent comprises a propylene/ethylene weight ratio ranging from 2 to 5.

10. The process of claim 1 , wherein the salt comprises ammonium ions.

11. The process of claim 1 , wherein the complexing agent comprises an acid in an aqueous solution, a salt of the acid in aqueous solution, or combinations thereof.

12. The process of claim 1 , wherein the propylene yield is above 35wt %.

13. The process of claim 12 , wherein the time on stream is about 61 minutes.

14. The process of claim 12 , wherein the time on stream is about 123 minutes.

15. The process of claim 12 , wherein the time on stream is about 185 minutes.

Assignments (2)
CHANGE OF NAME Recorded May 12, 2014
From: TOTAL PETROCHEMICALS RESEARCH FELUY
To: TOTAL RESEARCH & TECHNOLOGY FELUY
Reel/Frame 032874/0565 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 12, 2007
From: DATH, JEAN-PIERRE; VERMEIREN, WALTER
To: TOTAL PETROCHEMICALS RESEARCH FELUY
Reel/Frame 018774/0664 →
Priority Claims (1)
EP 02078355 · Aug 14, 2002 · regional
Continuity (1)
Related Publication 20060235251A1 · Oct 19, 2006