High-molecular aliphatic polyester and process for producing the same
Disclosed herein are a high-molecular weight aliphatic polyester, whose molecular weight has been highly increased by a chain-lengthening reaction of a ring-opening (co)polymer of at least one cyclic ester selected from the group consisting of glycolide and lactide with an oxazoline compound, and a production process thereof. The molecular weight of the high-molecular weight aliphatic polyester is highly increased to the extent that a rate of increase in molecular weight represented by a ratio (Mw 2 /Mw 1 ) of a weight average molecular weight (Mw 2 ) of a ring-opening (co)polymer after the chain lengthening to a weight average molecular weight (Mw 1 ) of the ring-opening (co)polymer before the chain lengthening amounts to at least 1.10.
1 . A high-molecular weight aliphatic polyester, whose molecular weight has been highly increased by a chain-lengthening reaction of a ring-opening (co)polymer of at least one cyclic ester selected from the group consisting of glycolide and lactide with an oxazoline compound to the extent that a rate of increase in molecular weight represented by a ratio (Mw 2 /Mw 1 ) of a weight average molecular weight (Mw 2 ) of a ring-opening (co)polymer after the chain lengthening to a weight average molecular weight (Mw 1 ) of the ring-opening (co)polymer before the chain lengthening amounts to at least 1.10.
2 . The high-molecular weight aliphatic polyester according to claim 1 , wherein the molecular weight is highly increased to the extent that the rate of increase in molecular weight amounts to at least 1.20.
3 . The high-molecular weight aliphatic polyester according to claim 1 , wherein the molecular weight is highly increased to the extent that the rate of increase in molecular weight amounts to at least 1.35.
4 . The high-molecular weight aliphatic polyester according to claim 1 , wherein the weight average molecular weight (Mw) of the ring-opening (copolymer, whose molecular weight has been increased by the chain-lengthening reaction, is at least 120,000.
5 . The high-molecular weight aliphatic polyester according to claim 1 , wherein the ring-opening (co)polymer having a weight average molecular weight of at most 110,000 before the chain lengthening is subjected to the chain-lengthening reaction into a high-molecular weight ring-opening (co)polymer having a weight average molecular weight of at least 150,000.
6 . The high-molecular weight aliphatic polyester according to claim 1 , wherein a difference (T 2 -T 1 ) between a 1%-weight loss-starting temperature T 2 on heating of the ring-opening (co)polymer after the chain lengthening and a 1%-weight loss-starting temperature T 1 on heating of the ring-opening (co)polymer before the chain lengthening is at least 3° C.
7 . The high-molecular weight aliphatic polyester according to claim 6 , wherein the 1%-weight loss-starting temperature T 2 on heating of the ring-opening (co)polymer after the chain lengthening is at least 233° C.
8 . The high-molecular weight aliphatic polyester according to claim 1 , wherein a molecular weight distribution (Mw/Mn) represented by a ratio of a weight average molecular weight (Mw) of the ring-opening (co)polymer, whose molecular weight has been highly increased by the chain-lengthening reaction, to a number average molecular weight (Mn) thereof is at least 1.90.
9 . The high-molecular weight aliphatic polyester according to claim 1 , wherein the oxazoline compound is an oxazoline compound having at least two oxazoline ring structures in its molecule.
10 . The high-molecular weight aliphatic polyester according to claim 9 , wherein the oxazoline compound having at least two oxazoline ring structures in its molecule is 2,2′-m-phenylene-bis(2-oxazoline).
11 . A process for producing a high-molecular weight aliphatic polyester, which comprises subjecting a ring-opening (co)polymer of at least one cyclic ester selected from the group consisting of glycolide and lactide to a chain-lengthening reaction with an oxazoline compound to highly increase the molecular weight thereof to the extent that a rate of increase in molecular weight represented by a ratio (Mw 2 /Mw 1 ) of a weight average molecular weight (Mw 2 ) of a ring-opening (co)polymer after the chain lengthening to a weight average molecular weight (Mw 1 ) of the ring-opening (co)polymer before the chain lengthening amounts to at least 1.10.
12 . The production process according to claim 11 , wherein the molecular weight is highly increased to the extent that the rate of increase in molecular weight amounts to at least 1.20.
13 . The production process according to claim 11 , wherein the molecular weight is highly increased to the extent that the rate of increase in molecular weight amounts to at least 1.35.
14 . The production process according to claim 11 , wherein the ring-opening (co)polymer and the oxazoline compound are subjected to the chain-lengthening reaction at a temperature within a range of 100 to 300° C.
15 . The production process according to claim 11 , wherein the ring-opening (co)polymer and the oxazoline compound are subjected to the chain-lengthening reaction under conditions that the reaction temperature is not lower than the melting temperature of the ring-opening (co)polymer, but not higher than 300° C., and the reaction time is 5 to 40 minutes.
16 . The production process according to claim 11 , wherein the oxazoline compound is an oxazoline compound having at least two oxazoline ring structures in its molecule.
17 . The production process according to claim 11 , wherein the chain-lengthening reaction is conducted in the presence of the oxazoline compound in a proportion within a range of 0.005 to 10 parts by weight per 100 parts by weight of the ring-opening (co)polymer.
18 . The production process according to claim 11 , wherein the ring-opening (co)polymer having a weight average molecular weight of at most 110,000 before the chain lengthening is subjected to the chain-lengthening reaction into a high-molecular weight ring-opening (co)polymer having a weight average molecular weight of at least 150,000.
19 . The production process according to claim 11 , wherein a difference (T 2 -T 1 ) between a 1%-weight loss-starting temperature T 2 on heating of the ring-opening (co)polymer after the chain lengthening and a 1%-weight loss-starting temperature T 1 on heating of the ring-opening (co)polymer before the chain lengthening is made at least 3° C. by the chain-lengthening reaction.
20 . The production process according to claim 11 , wherein a molecular weight distribution (Mw/Mn) represented by a ratio of a weight average molecular weight (Mw) of the ring-opening (co)polymer, whose molecular weight has been highly increased by the chain-lengthening reaction, to a number average molecular weight (Mn) thereof is at least 1.90.