Lubricant coated sheet metal with improved deformation properties
View Patent ↗The invention relates to sheet metal or a sheet metal blank provided with a lubricant coating, especially an anti-corrosion oil of the Pre-Lube or Dry Lube variety. The sheet metal or sheet metal blank comprises a layer which is formed by applying a solution containing an organic phosphoric acid ester to the metal surface of the sheet metal. Sheet metal provided with said coating has excellent tribological properties.
1. A metal sheet or metal sheet section comprising a lubricant coating,
wherein
the metal sheet or the metal sheet section comprises a first layer and a second layer, the first layer being formed by the application onto the metallic surface of the metal sheet or metal sheet section of a solution containing an organic phosphoric acid ester, wherein the organic phosphoric acid ester is a compound of the general formula
X 3-n PO 4 R n
where X stands for hydrogen, Na, K, —NH 2 , —NHR, —NR 2 , —NH(R′—OH) 2 or NR(R′—OH), R stands for a straight-chain or branched alkyl group with 1 to 8 carbon atoms, R′ stands for a straight-chain or branched alkylene group with 1 to 14 carbon atoms, R and R′ can in each case be equal or different, and n is a number from 0 to 3, with the proviso that n is not 0 if X stands exclusively for hydrogen, the solution containing phosphoric acid ester having a pH from 6.5 to 11, and the second layer including a lubricant and being arranged on the first layer.
2. The metal sheet or metal sheet section according to claim 1
wherein
the organic phosphoric acid ester is a mixture of (C 4 H 9 —O)OP(OH) 2 and (OH)PO(O—C 4 H 9 ) 2 .
3. The metal sheet or metal sheet section according claim 1 ,
wherein
the solution containing the organic phosphoric acid ester contains, as further components, a water-soluble organic sulphur compound and/or an organic molybdenum compound.
4. The metal sheet or metal sheet section according to claim 3
wherein
the organic sulphur compound is selected from the group consisting of thiadiazolene, dithiocarbamates and dithiopropionates as well as salts and derivatives thereof.
5. The metal sheet or metal sheet section according to claim 3 ,
wherein
the organic sulphur compound is selected from the group consisting of Sodium-2-mercaptobenzothiazole, 2,5-dimercapto-1,3,4-thiadiazole, as well as salts and derivatives thereof, sodium dimethyl dithiocarbamate, potassium dimethyl dithiocarbamate and monoethanol amine dithiopropionate.
6. The metal sheet or metal sheet section according to claim 3 ,
wherein
the organic molybdenum compound can be obtained by the conversion of molybdenum trioxide and/or molybdeneic acid with an amine and/or alkanolamine.
7. The metal sheet or metal sheet section according to claim 1
wherein
the solution containing the phosphoric acid ester contains, as further components, at least one inorganic compound selected from the group consisting of polyphosphates, borates, molybdates and wolframates.
8. The metal sheet or metal sheet section according to claim 7 ,
wherein
the inorganic compound is selected from the group consisting of ammonium tripolyphosphate, sodium tetraborate, ammonium molybdate, sodium wolframate, potassium wolframate and sodium wolframate.
9. The metal sheet or metal sheet section according to claim 1 ,
wherein
the first layer is formed as a thin layer in the nano range.
10. The metal sheet or metal sheet section according to claim 1 ,
wherein
the second layer is formed in a thickness from 0.3 to 3.0 g/m 2 .
11. The metal sheet or metal sheet section according to claim 1 ,
wherein
the second layer includes the organic phosphoric acid ester in a quantity from 0.01 to 50% by weight.
12. The metal sheet or metal sheet section according to claim 1 ,
wherein
the lubricant of the second layer contains a water-soluble organic sulphur compound in a quantity from 0.005 to 30% by weight.
13. The metal sheet or metal sheet section according to claim 1 ,
wherein
the lubricant of the second layer contains an organic molybdenum compound in a quantity from 0.005 to 30% by weight.
14. The metal sheet or metal sheet section according to claim 1 ,
wherein
the lubricant of the second layer contains an organic compound in a quantity from 0.005 to 30% by weight.
15. The metal sheet or metal sheet section according to claim 1
wherein
the sheet is a coated or uncoated steel sheet.
16. The method for the manufacture of a metal sheet section according to claim 1 ,
wherein
application of a solution including an organic phosphoric acid ester on the upper and/or lower side of the sheet, and
applications of a lubricant onto the sheet coated in this way.
17. The method according to claim 16 ,
wherein
the application of the solution including the organic phosphoric acid ester is effected by immersion, spraying, brushing, or roll coating.
18. The method according to claim 16 ,
wherein
the application of the solution including the organic phosphoric acid ester is effected during the coating of the sheet in the flushing bath of a coating system or during the cooling of the sheet in the bath of a water cooling system.
19. The method according to claim 16 ,
wherein
an aqueous solution of the organic phosphoric acid ester is applied.
20. The method according to claim 16 ,
wherein the solution applied includes the organic phosphoric acid ester in a concentration from 0.1 to 15% by weight.
21. The method according to claim 16 ,
wherein
the solution applied includes as further components a water-soluble organic sulphur compound and/or an organic molybdenum compound.
22. The method according to claim 21 ,
wherein
the solution applied includes the water-soluble organic sulphur compound(s) and/or organic molybdenum compound(s) in a quantity from 1 to 50% by weight related to the quantity of phosphoric acid ester.
23. The method according to claim 16 ,
wherein
the solution applied includes as further components at least one inorganic compounds from the group consisting of polyphosphates, borates, molybdates and wolframates.
24. The method according to claim 23 ,
wherein
the solution applied includes the inorganic compounds in a quantity from 1 to 50% by weight related to the quantity of phosphoric acid ester.
25. The method according to claim 16 ,
wherein
the sheet is dried before the lubricant is applied.
26. The method according to claim 16
wherein
the lubricant is selected from the group consisting of corrosion protection oil, pre-lube, dry-lube, and combinations thereof.
27. The method according to claim 16 ,
wherein
the lubricant is applied in a quantity from 0.3 to 3.0 g/m 2 .
28. An aqueous solution for the treatment of metal surfaces comprising the organic phosphoric acid ester of claim 1 , a water-soluble organic sulphur compound selected from the group consisting of thiadiazolene, dithiocarbamates and dithiopropionates as well as salts and derivatives thereof, and an organic molybdenum compound obtainable by the conversion of molybdenum trioxide and/or molybdeneic acid with an anime and/or alkanolamine.
29. The aqueous solution according to claim 28 , further comprising at least one organic compounds selected from the group consisting of polyphosphates, borates, molybdates and wolframates.
30. A concentrate for the manufacture of a solution for the treatment of metal surfaces according to claim 28 .