Medical container
A medical container produced from a film or sheet having at least one resin layer comprising a polyolefin resin composition, wherein the polyolefin resin composition comprises includes (A) at least one propylene-base polymer which is (A) a specific propylene-base polymer composition, (A) a propylene-base block copolymer and (A) a specific propylene-base block copolymer composition, and (B) an ethylene-base copolymer including an ethylene and at least one α-olefin having 4 or more carbon atoms, and the refractive index of the xylene-soluble portion of the mixture of polymers (A) and (B) is from 1.480 to 1.495.
1. A medical container produced from a film or sheet having at least one resin layer comprising a polyolefin resin composition,
wherein said polyolefin resin composition comprises (A) at least one propylene-base polymer selected from the group consisting of (A1) a propylene-base polymer composition as a mixture of (A11) a propylene polymer and (A12) an ethylene-propylene copolymer elastomer, (A2) a propylene-base block copolymer, and (A3) a propylene-base block copolymer composition as a mixture of (A2) a propylene-base block copolymer and (A12) an ethylene-propylene copolymer elastomer, and (B) an ethylene-base copolymer comprising an ethylene and at least one α-olefin having 4 or more carbon atoms, and
the refractive index of the xylene-soluble portion of the mixture of polymers (A) and (B) is from 1.480 to 1.495; and
the film or sheet further comprises at least one of a first high-density polyethylene layer, which comprises a high-density polyethylene and is disposed in an inner side of the film or sheet, and a second high-density polyethylene layer, which comprises a high-density polyethylene and is disposed in an outer side of the film or sheet.
2. The medical container as claimed in claim 1 , wherein said polyolefin resin composition has a xylene-soluble portion content of 20 to 70 mass%.
3. The medical container as claimed in claim 1 , wherein in said polyolefin resin composition, the ratio (MFR A /MFR B ) of the melt flow rate (MFR A ) of propylene-base polymer (A) to the melt flow rate (MFR B ) of ethylene-base copolymer (B) is from 0.3 to 3.0.
4. The medical container as claimed in claim 1 , wherein said first high-density polyethylene layer contains 20 mass% or more of a high-density polyethylene having a density of 0.950 g/cm 3 or more.
5. The medical container as claimed in claim 1 , wherein said second high-density polyethylene layer contains 20 mass% or more of a high-density polyethylene having a density of 0.950 g/cm 3 or more.
6. The medical container as claimed in claim 1 , wherein the thickness of the resin layer comprising a polyolefin resin composition occupies 60% or more of the entire thickness of the film or sheet.
7. The medical container as claimed in claim 4 , wherein the density of the high-density polyethylene is a value which is measured according to JIS K 7112 Method D.
8. The medical container as claimed in claim 5 , wherein the density of the high-density polyethylene is a value which is measured according to JIS K 7112 Method D.
9. The medical container as claimed in claim 3 , wherein the MFR is obtained as a value which is measured at 230° C. with a load of 21.18 N according to JIS K 7210.
10. The medical container as claimed in claim 2 , wherein the xylene-soluble portion content is determined by a method including:
adding 10 g of a polyolefin resin composition to 1 L of an orthoxylene;
stirring the mixture at a temperature of a boiling point of the orthoxylene to dissolve the resin composition completely to obtain a solution;
cooling the solution while stirring until the temperature of the solution is 100° C. or less and keeping the solution in a constant-temperature bath at 25° C. for 2 hours;
separating a xylene-insoluble portion deposited in the solution by filtration to obtain a filtrate;
removing xylene from the filtrate by conducting drying at 60° C. under reduced pressure for one day subsequent to heating at a temperature of 140° C. in a nitrogen stream, to obtain a xylene-soluble-portion;
measuring the mass of the xylene-soluble portion; and
obtaining the xylene-soluble portion content by the formula: (a mass of the xylene-soluble portion)/(mass of the added polyolefin resin composition).
11. The medical container as claimed in claim 1 , wherein a refractive index of the xylene-soluble portion is determined by a method comprising:
forming a film having a thickness of 50 to 80 μm with a press-molding machine by preheating the xylene-soluble portion at 230° C. for 5 minutes, degassing for 30 seconds, pressing the xylene-soluble portion at 6 MPa for 1 minute and cooling at 30° C. for 3 minutes;
standing the film at ordinary temperature for 24 hours; and
measuring a refractive index of the xylene-soluble portion as a refractive index for sodium D line at 23° C. by an Abbe refractive index meter using ethyl salicylate as the intermediate solution.