IP Library Granted Patent US 7,659,218
Granted Patent B2
US 7,659,218 · App. 10/543,246 · Granted Feb 9, 2010

Stretch nonwoven fabric and method for production thereof

Assignee: Mitsui Chemicals, Inc
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Quick Facts
Patent No.
US 7,659,218
App. No.
10/543,246
Granted
Feb 9, 2010
Kind
B2
Abstract

A spunbonded elastic nonwoven fabric according to the invention comprises fibers formed from a polymer comprising a thermoplastic polyurethane elastomer, wherein the thermoplastic polyurethane elastomer has a starting temperature for solidifying of 65° C. or above as measured by a differential scanning calorimeter (DSC) and contains 3.00×10 6 or less polar-solvent-insoluble particles per g as counted on a particle size distribution analyzer, which is based on an electrical sensing zone method, equipped with an aperture tube having an orifice of 100 μm in diameter, and wherein the fibers have diameters such that the standard deviation of fiber diameters (Sn) divided by the average fiber diameter (X ave ) (Sn/X ave ) gives a value of 0.15 or less.

Claims (19)

1. A spunbonded elastic nonwoven fabric comprising fibers formed from a polymer comprising a thermoplastic polyurethane elastomer,

said thermoplastic polyurethane elastomer having a starting temperature for solidifying of 65° C. or above as measured by a differential scanning calorimeter (DSC) and containing 3.00×10 4 or more and 3.00×10 6 or less polar-solvent-insoluble particles per gram as counted on a particle size distribution analyzer, which is based on an electrical sensing zone method, equipped with an aperture tube having an orifice of 100 μm in diameter, and

said fibers having diameters such that the standard deviation of fiber diameters (Sn) divided by the average fiber diameter (X ave ) (Sn/X ave ) gives a value of 0.15 or less.

2. The elastic nonwoven fabric according to claim 1 , wherein the polymer contains the thermoplastic polyurethane elastomer in an amount of 10 wt % or more.

3. The elastic nonwoven fabric according to claim 1 , wherein on the thermoplastic polyurethane elastomer, a total heat of fusion (a) determined from endothermic peaks within the temperature range of from 90 to 140° C. and a total heat of fusion (b) determined from endothermic peaks within the temperature range of from above 140 to 220° C., which are measured by a differential scanning calorimeter (DSC), satisfy the following relation (1):

a /( a+b )×100≦80  (1).

4. A hygiene material comprising the elastic nonwoven fabric described in claim 1 .

5. A production method for an elastic nonwoven fabric comprising fibers formed from a polymer comprising a thermoplastic polyurethane elastomer by spunbonding the polymer,

wherein the thermoplastic polyurethane elastomer has a starting temperature for solidifying of 65° C. or above as measured by a differential scanning calorimeter (DSC) and contains 3.00×10 4 or more and 3.00×10 6 or less polar-solvent-insoluble particles per gram as counted on a particle size distribution analyzer, which is based on an electrical sensing zone method, equipped with an aperture tube having an orifice of 100 μm in diameter, and

wherein the fibers have diameters such that the standard deviation of fiber diameters (Sn) divided by the average fiber diameter (X ave ) (Sn/X ave ) gives a value of 0.15 or less.

6. A spunbonding processible thermoplastic polyurethane elastomer that has a starting temperature for solidifying of 65° C. or above as measured by a differential scanning calorimeter (DSC), contains 3.00×10 4 or more and 3.00×10 6 or less polar-solvent-insoluble particles per gram as counted on a particle size distribution analyzer, which is based on an electrical sensing zone method, equipped with an aperture tube having an orifice of 100 μm in diameter, and enables production of spunbonded elastic nonwoven fabrics in which the standard deviation of fiber diameters (Sn) divided by the average fiber diameter (X ave ) (Sn/X ave ) gives a value of 0.15 or less.

7. The elastic nonwoven fabric according to claim 2 , wherein on the thermoplastic polyurethane elastomer, a total heat of fusion (a) determined from endothermic peaks within the temperature range of from 90 to 140° C. and a total heat of fusion (b) determined from endothermic peaks within the temperature range of from above 140 to 220° C., which are measured by a differential scanning calorimeter (DSC), satisfy the following relation (1):

a /( a+b )×100≦80  (1).

8. A hygiene material comprising the elastic nonwoven fabric described in claim 2 .

9. A hygiene material comprising the elastic nonwoven fabric described in claim 3 .

10. A hygiene material comprising the elastic nonwoven fabric described in claim 7 .

11. A spunbonded elastic nonwoven fabric comprising fibers formed from a polymer comprising a thermoplastic polyurethane elastomer,

said thermoplastic polyurethane elastomer having a starting temperature for solidifying of 65° C. or above as measured by a differential scanning calorimeter (DSC) and containing 3.00×10 4 or more and 3.00×10 6 or less polar-solvent-insoluble particles per gram as counted on a particle size distribution analyzer, which is based on an electrical sensing zone method, equipped with an aperture tube having an orifice of 100 μm in diameter, and

said fibers having diameters such that the standard deviation of fiber diameters (Sn) divided by the average fiber diameter (X ave ) (Sn/X ave ) gives a value of 0.12 or less.

Assignments (3)
MERGER Recorded Jan 21, 2010
From: MITSUI CHEMICALS POLYURETHANES, INC.; MITSUI CHEMICALS, INC.
To: MITSUI CHEMICALS, INC.
Reel/Frame 023825/0417 →
CHANGE OF NAME Recorded Jan 6, 2010
From: MITSUI TAKEDA CHEMICALS, INC.
To: MITSUI CHEMICALS POLYURETHANES, INC.
Reel/Frame 023829/0853 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 22, 2005
From: NISHIGUCHI, DAISUKE; SUZUKI, KENICHI; YAMASAKI, SATOSHI; MOTOMURA, SHIGEYUKI; KAWANABE, HISASHI
To: MITSUI CHEMICALS, INC.; MITSUI TAKEDA CHEMICALS, INC.
Reel/Frame 017511/0506 →
Priority Claims (1)
JP 2003-016803 · Jan 24, 2003 · national
Continuity (1)
Related Publication 20060141883A1 · Jun 29, 2006