Low gloss thermoformable flooring structure
A novel flooring composition was developed based on a blend comprising: a) an elastomer; b) a random propylene/alpha-olefin copolymer; c) a cross linking agent; and optionally d) a melt strength enhancing polymer. This composition achieves a unique balance of properties, exhibiting often-conflicting performance requirements. These include low gloss and excellent pattern duplication in embossing, low modulus, minimal odor, excellent grain acceptance and abrasion resistance, while remaining thermoformable and maintaining minimal shift in viscosity during recycle.
1. A polymer blend consisting of the following:
A) an elastomer selected from a homogeneously- or a heterogeneously-branched ethylene/alpha-olefin interpolymer having a density of less than, or equal to, 0.905 g/cm 3 ;
B) a random propylene/ethylene copolymer having a melting point (Tm) by Differential Scanning Calorimetry (as measured by ASTM D-3417) of less than 160° C.;
C) from 200 ppm to 1300 ppm, based on the weight of the composition, of a peroxide crosslinking agent; and
D) a melt strength enhancing polymer which is a is low density polyethylene (LDPE) with a melt strength of greater than 3 cN; and
E) at least one additive selected from the group consisting of antioxidants, phosphites, U.V. stabilizers, cling additives, slip agents, antiblock additives, plasticizers, colorants, pigments, carbon black masterbatch, organic fillers, inorganic fillers, silicon polymer, and combinations thereof; and
wherein the blend has an Embossability Index (EI) greater than 0.48, at thermoforming temperatures from 144° C. to 156° C., and
wherein the blend does not contain a free radical coagent.
2. The blend of claim 1 , wherein
A) said elastomer, Component A, is present in an amount from 20 to 80 weight percent (based on the total weight of Components A, B, C, and D);
B) said random propylene copolymer, Component B, is present in an amount from 15 to 45 weight percent (based on the total weight of Components A, B, C, and D), and has a melting point (Tm), as measured by ASTM D-3417, of less than 160° C.;
C) said cross linking agent, Component C, is employed in an amount, so as to result in a reduction in 600 gloss at 150° C., by ASTM D523-89 (1999), of at least 20 percent, as compared to the same blend composition, but absent the cross linking agent, and
D) said melt strength enhancing polymer, Component D, is present in an amount from 15 to 35 weight percent (based on the total weight of Components A, B, C, and D); and wherein
E) said blend has a peak melting point, (Tm), as measured by Differential Scanning Calorimetry, DSC, using ASTM D-3417, of less than 165° C., and has a lowest Tg peak of less than −10° C.
3. The blend of claim 1 , wherein
A) said elastomer, Component A, is present in an amount from 30 to 70 weight percent (based on the total weight of Components A, B, C, and D);
B) said random propylene copolymer, Component B, is present in an amount from 20 to 40 weight percent (based on the total weight of Components A, B, C, and D), and has a melting point (Tm), as measured by ASTM D-3417, of less than 155° C.;
C) said cross linking agent, Component C, is employed in an amount, so as to result in a reduction in 600 gloss at 150° C., by ASTM D523-89 (1999), of at least 30 percent, as compared to the same blend composition, but absent the cross linking agent; and
D) said melt strength enhancing polymer, Component D is present in an amount from 15 to 35 weight percent (based on the total weight of Components A, B, C, and D); and wherein
E) said blend has a peak melting point (Tm), as measured by Differential Scanning Calorimetry, DSC, using ASTM D-3417, of less than 160° C., and has a lowest Tg peak of less than −20° C.
4. The blend of claim 1 , wherein
A) said elastomer, Component A, is present in an amount from 35 to 65 weight percent (based on the total weight of Components A, B, C, and D);
B) said random propylene copolymer, Component B, is present in an amount from 20 to 35 weight percent (based on the total weight of Components A, B, C, and D), and has a melting point (Tm), as measured by ASTM D-3417, of less than 150° C.;
C) said cross linking agent, Component C, is employed in an amount, so as to result in a reduction in 600 gloss at 150° C., by ASTM D523-89 (1999), when compared to the same blend composition, but absent the cross linking agent, of at least 40 percent; and
D) said melt strength enhancing polymer, Component D is present in an amount from 20 to 35 weight percent (based on the total weight of Components A, B, C, and D); and wherein
E) said blend has a peak melting point, (Tm), as measured by Differential Scanning Calorimetry, DSC, using ASTM D-3417, of less than 155° C., and has a lowest Tg peak of less than −30° C.
5. A polymer blend consisting of the following:
A) an elastomer selected from a homogeneously- or a heterogeneously-branched ethylene/alpha-olefin interpolymer having a density of less than, or equal to, 0.905 g/cm 3 ;
B) a mixture of polypropylene homopolymer and random propylene/ethylene copolymer having a melting point (Tm) by Differential Scanning Calorimetry (as measured by ASTM D-3417) of less than 160° C.;
C) from 200 ppm to 1300 ppm, based on the weight of the composition, of a peroxide crosslinking agent;
D) a melt strength enhancing polymer which is a is low density polyethylene (LDPE) with a melt strength of greater than 3 cN; and
E) at least one additive selected from the group consisting of antioxidants, phosphites, U.V. stabilizers, cling additives, slip agents, antiblock additives, colorants, pigments, plasticizers, carbon black masterbatch, organic fillers, inorganic fillers, silicon polymer, and combinations thereof; and
wherein the blend has an Embossability Index (EI) greater than 0.48, at thermoforming temperatures from 144° C. to 156° C., and
wherein the blend does not contain a free radical coagent.
6. The polymer blend of claim 1 or claim 5 , wherein the at least one additive is selected from the group consisting of a siloxane polymer, carbon black or inorganic filler, or a combination thereof.
7. A molded part comprising the blend of claim 1 or 5 .
8. A thermoformed part comprising the blend of claim 1 or 5 .
9. A wire and cable jacket comprising the blend of claim 1 or 5 .
10. The part of claim 8 , wherein the part is in the form of an automotive floor or floor mat.
11. A polymer blend consisting of
A) an elastomer selected from a homogeneously- or a heterogeneously-branched ethylene/alpha-olefin interpolymer having a density of less than, or equal to, 0.905 g/cm 3 ;
B) a random propylene/ethylene copolymer having a melting point (Tm), by Differential Scanning Calorimetry DSC (as measured by ASTM D3417), of less than 160° C.;
C) from 200 ppm to 1300 ppm, based on the weight of the composition, of a peroxide crosslinking agent;
D) at least one additive selected from the group consisting of antioxidants, phosphites, U.V. stabilizers, cling additives, slip agents, antiblock additives, colorants, pigments, plasticizers, carbon black masterbatch, organic fillers, inorganic fillers, silicon polymer, and combinations thereof; and
optionally, E) a melt strength enhancing polymer which is a is low density polyethylene (LDPE) with a melt strength of greater than 3 cN; and
wherein the blend has an Embossability Index (EI) greater than 0.48, at thermoforming temperatures from 144° C. to 156° C., and
wherein the blend does not contain a free radical coagent.
12. An article comprising at least one component formed from the composition of claim 1 .
13. An article comprising at least one component formed from the composition of claim 11 .
14. A polymer blend consisting of the following:
A) an elastomer selected from a homogeneously- or a heterogeneously-branched ethylene/alpha-olefin interpolymer having a density of less than, or equal to, 0.905 g/cm 3 ;
B) a mixture of a polypropylene homopolymer and a random propylene/ethylene copolymer having a melting point (Tm), by Differential Scanning Calorimetry DSC (as measured by ASTM D3417), of less than 160° C.;
C) from 200 ppm to 1300 ppm, based on the weight of the composition, of a peroxide crosslinking agent;
D) at least one additive selected from the group consisting of antioxidants, phosphites, U.V. stabilizers, cling additives, slip agents, antiblock additives, colorants, pigments, plasticizers, carbon black masterbatch, organic fillers, inorganic fillers, silicon polymer, and combinations thereof; and
optionally, E) a melt strength enhancing polymer which is a is low density polyethylene (LDPE) with a melt strength of greater than 3 cN; and
wherein the blend has an Embossability Index (EI) greater than 0.48, at thermoforming temperatures from 144° C. to 156° C., and
wherein the blend does not contain a free radical coagent.
15. The blend of claim 1 , wherein the random propylene/ethylene copolymer has a melting point (Tm) by Differential Scanning Calorimetry (as measured by ASTM D-3417) of less than 150° C.
16. The composition as in claims 1 , 5 , 11 or 14 , wherein the elastomer is a homogeneously branched ethylene/alpha-olefin interpolymer having a density of less than, or equal to, 0.905 g/cm 3 .
17. The composition as in claims 1 , 5 , 11 or 14 , wherein, for the elastomer, the alpha-olefin is selected from propylene, 1-butene, 1-hexene, 4-methyl-1-pentene or 1-octene.