IP Library Granted Patent US 7,442,434
Granted Patent B2
US 7,442,434 · App. 10/551,938 · Granted Oct 28, 2008

Epoxy resin composition

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Quick Facts
Patent No.
US 7,442,434
App. No.
10/551,938
Granted
Oct 28, 2008
Kind
B2
Abstract

A solvent-free epoxy resin matrix composition comprising: (a) a liquid epoxy resin or a liquid mixture of epoxy resins, (b) a benzylidenamine compound, (c) an aliphatic or cycloaliphatic primary monoamine and/or disecondary diamine; and (d) a catalytically curing tertiary amine. The epoxy resin matrix composition is used as an impregnating resin to form impregnated fiber composite materials.

Claims (21)

1. A fibre composite impregnated with a curable, solvent-free epoxy resin matrix composition, said composition comprising:

(a) a liquid epoxy resin or a liquid mixture of epoxy resins,

(b) a benzylidenamine compound obtained by reacting a benzaldehyde of the formula (I)

 in which R 1 is hydrogen, C 1 -C 5 alkyl or C 1 -C 5 alkoxy, with a primary amine,

(c) an aliphatic or cycloaliphatic primary monoamine and/or disecondary diamine, and

(d) a catalytically curing tertiary amine,

the curable epoxy resin matrix composition containing from 0.15 to 0.8 amine hydrogen equivalent of the amine component (c) and from 0.01 to 0.1 mol of the tertiary amine (d) per epoxide equivalent of the epoxy resin (a).

2. The fibre composite according to claim 1 , containing from 0.3 to 20% by weight, based on components (a), (c) and (d), of the benzylidenamine compound.

3. The fibre composite according to claim 1 , containing from 0.2 to 0.7 amine hydrogen equivalent of the amine component (c) and from 0.02 to 0.06 mol of the tertiary amine (d) per epoxide equivalent.

4. The fibre composite according to claim 1 , wherein component (c) is an aliphatic or cycloaliphatic primary monoamine.

5. The fibre composite according to claim 1 , wherein the benzylidenamine compound is benzylidenebenzylamine.

6. A fibre composite system, produced from the fibre composite according to claim 1 together with wood or plastics having a low softening point.

7. A solvent-free epoxy resin matrix composition comprising:

(a) a liquid epoxy resin or a liquid mixture of epoxy resins,

(b) a benzylidenamine compound obtained by reacting a benzaldehyde of the formula (I)

 in which R 1 is hydrogen, C 1 -C 5 alkyl or C 1 -C 5 alkoxy with a primary amine,

(c) an aliphatic or cycloaliphatic primary monoamine and/or disecondary diamine, and

(d) a catalytically curing tertiary amine.

the curable epoxy resin matrix composition containing from 0.15 to 0.8 amine hydrogen equivalent of the amine component (c) and from 0.01 to 0.1 mol of the tertiary amine (d) per epoxide equivalent of the epoxy resin (a).

8. The epoxy resin matrix according to claim 7 , containing, based on the total amount of epoxy resin and curing agent, from 0.3 to 20% by weight of the benzylidenamine compound obtained by reacting a benzaldehyde of the formula (I)

in which R 1 is hydrogen, C 1 -C 5 alkyl or C 1 -C 5 alkoxy with a primary amine.

Assignments (5)
TERMINATION AND RELEASE OF SECURITY INTEREST IN UNITED STATES TRADEMARKS AND PATENTS Recorded Jun 13, 2018
From: JPMORGAN CHASE BANK, N.A.
To: HUNTSMAN ADVANCED MATERIALS AMERICAS INC. (N/K/A HUNTSMAN ADVANCED MATERIALS AMERICAS LLC)
Reel/Frame 046352/0893 →
CORRECTIVE ASSIGNMENT TO CORRECT THE NATURE OF CONVEYANCE FROM ASSIGNMENT TO SECURITY AGREEMENT PREVIOUSLY RECORDED ON REEL 025855 FRAME 0192. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded Jun 28, 2011
From: DEUTSCHE BANK TRUST AG NEW YORK BRANCH, AS RESIGNING ADMINISTRATIVE AGENT AND COLLATERAL AGENT
To: JPMORGAN CHASE BANK, N.A., AS COLLATERAL AGENT
Reel/Frame 026515/0735 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 28, 2011
From: DEUTSCHE BANK TRUST AG NEW YORK BRANCH, AS RESIGNING ADMINISTRATIVE AGENT AND COLLATERAL AGENT
To: JPMORGAN CHASE BANK, N.A., AS COLLATERAL AGENT
Reel/Frame 025855/0192 →
SECURITY INTEREST Recorded Jan 20, 2006
From: HUNTSMAN ADVANCED MATERIALS AMERICAS, INC.
To: DEUTSCHE BANK AG NEW YORK BRANCH, AS AGENT
Reel/Frame 017164/0639 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 4, 2005
From: SETIABUDI, FRANS; WEIDMANN, ULRICH; MICHAUD, PHILIPPE
To: HUNTSMAN ADVANCED MATERIALS AMERICAS INC.
Reel/Frame 017825/0165 →