Magnetic powder, a magnetic recording medium using the magnetic powder, and a method of surface treating a magnetic powder
View Patent ↗A magnetic powder composed primarily of Fe that has been surface-treated with a silane coupling agent, which magnetic powder is characterized in that it contains Co such that Co/Fe expressed in atomic percent is 20-50 at. %, Al such that Al/Fe expressed in atomic percent is 5-30 at. %, and one or more rare earth elements R (including Y) such that R/Fe expressed in atomic percent is 4-20 at. %, and has average particle diameter of smaller than 80 nm, TAP density of 0.7 g/cm 3 or greater, ignition point of 165° C. or higher, and oxygen content of 26 wt % or less.
1. A magnetic powder composed primarily of Fe that has been surface-treated with a silane coupling agent, which magnetic powder is made up of acicular particles and is characterized in that:
it contains
Co such that Co/Fe expressed in atomic percent is 20-50 at. %,
Al such that Al/Fe expressed in atomic percent is 5-30 at. %, and
one or more rare earth elements R (including Y) such that R/Fe expressed in atomic percent is 4-20 at. %,
and has
average particle diameter of smaller than 80 nm,
TAP density of 0.7 g/cm 3 or greater,
ignition point of 165° C. or higher,
oxygen content of 26 wt % or less, and
satisfies the relation of Formula 1 below between its coercive force and particle volume:
Hc ≧325 ×In ( V )−900, Formula 1
where, in Formula 1, Hc represents coercive force (Oe) and V represents particle volume (nm 3 ) calculated from a transmission electron micrograph.
2. A magnetic powder according to claim 1 , wherein the shape of the particles is flat acicular.
3. A magnetic powder according to claim 1 , whose magnetic powder sedimentation rate is 1 cm/5 hr or less when 3 g of the powder is dispersed in 500 mL of toluene and left to stand.
4. A magnetic powder according to claim 1 , whose vinyl chloride (MR-110) adsorption amount is 0.6 mg/m 2 or greater and whose urethane (UR-8200) adsorption amount is 1.1 mg/m 2 or greater.
5. A magnetic powder according to claim 1 , whose tape ΔBm (amount of change (%) in Bm during storage for seven days under constant temperature and humidity at a temperature of 60° C. and relative humidity of 90%) is 15% or less as per a test method for evaluating tape properties.
6. A magnetic powder according to claim 5 , which satisfies the relationship of Formula 4 between ΔBm and particle volume (V) of the magnetic powder:
Δ Bm ≦−3.6 ×In ( V )+40.5. Formula 4
7. A magnetic powder according to claim 1 , which, as per a test method for evaluating tape properties, satisfies:
the relationship of Formula 5 between tape Hcx and particle volume (V) of the magnetic powder,
the relationship of Formula 6 between tape SFDx and particle volume (V) of the magnetic powder, and
the relationship of Formula 7 between tape SQx and particle volume (V) of the magnetic powder:
Hcx ≧630 ×In ( V )−3400 Formula 5
SFDx ≦0.2+506 V −0.79 Formula 6
SQx ≧0.065 In ( V )+0.15. Formula 7
8. A coating-type magnetic recording medium having a magnetic layer obtained by dispersing the magnetic powder of claim 1 in a resin at an orientation ratio of 2.5 or greater.
9. A coating-type magnetic recording medium according to claim 8 , whose magnetic layer exhibits ΔBm (amount of change (%) in Bm during storage for seven days under constant temperature and humidity at a temperature of 60° C. and relative humidity of 90%) of 15% or less.
10. A coating magnetic recording medium according to claim 8 , which satisfies the relationship of Formula 4 between ΔBm and particle volume (V) of the magnetic powder:
Δ Bm ≦−3.6 ×In ( V )+40.5. Formula 4
11. A coating magnetic recording medium according to claim 8 , which satisfies:
the relationship of Formula 5 between tape Hcx and particle volume (V) of the magnetic layer, the relationship of Formula 6 between tape SFDx and particle volume (V) of the magnetic layer, and the relationship of Formula 7 between tape SQx and particle volume (V) of the magnetic layer:
Hcx ≧630 ×In ( V )−3400 Formula 5
SFDx ≦0.2+506 ×V −0.79 Formula 6
SQx ≧0.065 ×In ( V )+0.15. Formula 7
12. A magnetic powder composed primarily of Fe, which is a magnetic powder that is made up of acicular particles and is for a coating-type magnetic recording medium that:
has
a particle volume (V) calculated from a transmission electron micrograph of not less than 1000 nm 3 and not greater than 15000 nm 3,
contains
Si such that Si/Fe expressed in atomic percent is 0.1-10 at. %, and
C such that C/Fe expressed in atomic percent is 0.5-40 at. %,
and has
oxygen content of 26 wt % or less
TAP density of 0.7 g/cm 3 or greater,
ignition point of 165° C. or higher,
Δσs (amount of change (%) in saturation magnetization value as during storage for seven days under constant temperature and humidity at a temperature of 60° C. and relative humidity of 90%) of 20% or less, and
saturation magnetization value as of less than 140 emu/g,
and satisfies
the relation of Formula 1 below between its coercive force and particle volume:
Hc≧ 325 ×In ( V )−900, Formula 1
where, in Formula 1, Hc represents coercive force (Oe) and V represents particle volume (nm 3 ) calculated from a transmission electron micrograph.
13. A magnetic powder according to claim 12 , which satisfies the relationship of Formula 2 between its Δσ and particle volume (V) and satisfies the relationship of Formula 3 between its oxygen content and particle volume (V):
Δσ s ≦−7.8 ×In ( V )+94, Formula 2
Oxygen content ≦−4.2 ×In ( V )+55. Formula 3
14. A magnetic powder according to claim 12 , which is composed of acicular iron alloy magnetic particles whose:
specific surface area by BET method is 60 m 2 /g or greater,
average major axis length is 20-80 nm,
Co content is such that Co/Fe expressed in atomic percent is 20-50 at. %,
Al content is such that Al/Fe expressed in atomic percent is 5-30 at. %, and
rare earth element R content including Y is such that RIFe expressed in atomic percent is 4-20 at. %.
15. A method of surface treating a magnetic powder according to claim 2 and characterized in that, in surface treating particle surfaces of a magnetic powder composed primarily of iron with a silane coupling agent, the magnetic powder and the silane coupling agent are reacted in an organic medium under a nonoxidizing atmosphere and in a state of dispersion up to where the degree of dispersion β according to the formula below becomes 10 or less:
Degree of dispersion β=Dfloc (particle average volume in solvent by dynamic light scattering)/DTEM (particle average volume observed by a transmission electron microscope).
16. A surface treating method according to claim 15 , wherein the magnetic powder is composed of particles on whose surfaces is distributed hydrophilic alumina or oxide of rare earth element(s) including Y.