Latently crimpable conjugate fiber and production method of the same, and fiber assembly, and nonwoven
A latently crimpable conjugate fiber is constructed using a first component containing an ethylene-α-olefin copolymer polymerized with a metallocene catalyst and a second component formed from a thermal plastic polymer having a melting point T 2 higher than a melting point T 1 of the first component, such that the first component is exposed with an exposed length of at least 20% relative to a peripheral length of the fiber, and which fiber has a single fiber dry heat shrinkage percentage of at least 50%, which is determined according to JIS-L-1015 (dry heat shrinkage percentage) at 100° C. under an initial tension of 0.018mn/dtex (2mg/d) for 15 minutes and a single fiber dry heat shrinkage percentage of at least 15%, which is determined under the same condition under an initial tension of 0.450mN/dtex (50mg/dtex) for 15 minutes. The latently crimpable conjugate fiber develops crimps and has thermal adhesiveness at a low temperature.
1. A latently crimpable conjugate fiber, comprising:
a conjugate fiber that includes
a first component comprising, as a thermal shrinkable component, a linear low-density polyethylene, the first component having a before-spinning melt index in a range of 1 g/10 min to 15 g/10 min, a ratio of a weight-average molecular weight (Mw) to a number average molecular weight (Mn) (a Q value) in range of 1.5 to 8 and a density in a range of 0.90 g/cm 3 to 0.93 g/cm 3 , and
a second component that is formed from a thermal plastic polymer, the second component having an after-spinning melting point TF 2 that is higher than an after-spinning melting point TF 1 of the first component,
wherein a surface of the first component is exposed with an exposed length viewed in cross section of not less than 20% relative to a peripheral length of the fiber,
wherein the fiber has: (1) a monofilament dry heat shrinkage percentage of not less than 50%, which is determined according to JIS-L-1015 (dry heat shrinkage percentage) at a temperature of 100° C. under an initial tension of 0.018 mN/dtex (2 mg/d) for a time of 15 minutes; and (2) a monofilament dry heat shrinkage percentage of not less than 15%, which is determined according to JIS-L-1015 (dry heat shrinkage percentage) at a temperature of 100° C. under an initial tension of 0.450 mN/dtex (50 mg/d) for a time of 15 minutes.
2. The latently crimpable conjugate fiber according to claim 1 , wherein a section of the conjugate fiber is (1) an eccentric sheath-core section wherein the first component is a sheath component and the second component is a core component and a center position of the second component is shifted from a center position of the fiber, or (2) a side-by-side section.
3. The latently crimpable conjugate fiber according to claim 1 , wherein the liner low-density polyethylene is a resin polymerized with a metallocene catalyst.
4. The latently crimpable conjugate fiber according to claim 1 , wherein the after-spinning temperature TF 1 of the first component is in a range of 105° C. to 125° C.
5. The latently crimpable conjugate fiber according to claim 1 , wherein the ratio of the weight-average molecular weight (Mw) to number average molecular weight (Mn) of the linear low-density polyethylene is in a range of 1.5 to 3.5.
6. A fiber assembly which comprises the latently-crimpable conjugate fibers according to claim 1 in an amount of not less than 20 mass % and the latently crimps have been developed in the latently crimpable conjugate fibers.
7. A nonwoven which comprises the latently-crimpable conjugate fibers according to claim 1 in an amount of not less than 20 mass % and the latently crimps have been developed in the latently crimpable conjugate fibers.
8. A method for producing a latently crimable conjugate fiber which comprise
obtaining a spun filament by composite-spinning a first component containing, as a thermal shrinkable component, a linear low-density polyethylene whose melting point T 1 is in a range of 100° C. to 125° C., a density is in a range of 0.90 g/cm 3 to 0.93 g/cm 3 , a Q value is a range of 1.5 to 8 and a before-spinning melt index is in a range of 1 g/10 min to 15 g/10 min and a second component consisting of a thermal plastic polymer whose melting point T 2 is higher than the melting point T 1 , such that they form an eccentric section of a side-by-side section and the first component is exposed with an exposed length of not less than 20% relative to the peripheral length of the fiber,
drawing the filament at a temperature within a range of 60° C. to (T 1 −10)° C. at a draw ratio of not less than 2 times,
giving mechanical crimps to the drawn filament with a number of crimps in a range of 12 peaks/25 mm to 19 peaks/25 mm, and
subjecting the crimped filament to an annealing treatment at a temperature in a range of 40° C. to 100° C.