Optical functional film, antireflection film, polarizing plate and image display device
Provided are an optical functional film including at least one functional layer, where the functional layer comprises a copolymer having a polymerization unit derived from a fluoroaliphatic group-containing monomer in a content of 10 weight % or more and the fluoroaliphatic group-containing copolymer is localized on the surface of the functional layer; an optical functional film obtained by coating an upper layer on the functional layer; an antireflection film, where the upper layer is a low refractive index layer; a polarizing plate using such a film for one of two protective sheets of a polarizer; and an image display device using the above-described optical functional film, antireflection film or polarizing plate for the outermost surface of the display.
1. A method for producing an optical functional film, comprising at least a first functional layer and a second functional layer, which are adjacently formed in this order on a transparent support,
wherein a coating composition for forming the first functional layer contains a fluoroaliphatic group-containing copolymer which has a polymerization unit derived from a fluoroaliphatic group-containing monomer represented by formula (2), an amount of the fluoroaliphatic group-containing monomer being 50 weight % or more based on an entire monomer amount of the fluoroaliphatic group-containing copolymer, the fluoroaliphatic group-containing copolymer is localized on a surface of the first functional layer when the coating composition for forming the first functional layer is coated, and the fluoroaliphatic group-containing copolymer dissolves out into a coating composition for forming the second functional layer when the second functional layer is coated,
wherein the coating composition for forming the second functional layer is applied onto the first functional layer after the first functional layer is cured by ionizing radiation:
wherein R 1 represents a hydrogen atom, a halogen atom or a methyl group; X represents an oxygen atom, a sulfur atom or —N(R 12 )—; R 12 represents a hydrogen atom or an alkyl group having from 1 to 8 carbon atoms, which may have a substituent; R f represents —CF 2 H; m represents an integer of 1 to 6; and n represents an integer of 1 to 17, and
wherein the fluoroaliphatic group-containing copolymer may contain two or more polymerization units derived from the fluoroaliphatic group-containing monomer represented by formula (2).
2. The method according to claim 1 , wherein the fluoroaliphatic group-containing copolymer comprises a polymerization unit derived from a monomer represented by formula (3):
wherein R 13 represents a hydrogen atom, a halogen atom or a methyl group; Y represents an oxygen atom, a sulfur atom or —N(R 15 )—; R 15 represents a hydrogen atom or an alkyl group having from 1 to 8 carbon atoms; and R 1′ represents a linear, branched or cyclic alkyl group having from 1 to 60 carbon atoms, which may have a substituent, or an aromatic group which may have a substituent.
3. The method according to claim 1 , wherein the coating composition for forming the first functional layer contains the fluoroaliphatic group-containing copolymer in an amount of from 0.001 to 1 weight %.
4. The method according to claim 1 , wherein the fluoroaliphatic group-containing copolymer contained in the coating composition for forming the first functional layer has a weight average molecular weight of from 3,000 to 100,000.
5. The method according to claim 1 , wherein the fluoroaliphatic group-containing copolymer contained in the coating composition for forming the first functional layer further comprises a polymerization unit derived from a monomer represented by the formula 3:
wherein R 13 represents a hydrogen atom, a halogen atom or a methyl group, Y represents an oxygen atom, a sulfur atom or —N(R 15 )—, R 15 represents a hydrogen atom or an alkyl group having from 1 to 8 carbon atoms, R 14 represents a linear, branched or cyclic alkyl group having from 1 to 60 carbon atoms which may have a substituent or an aromatic group which may have a substituent.
6. The method according to claim 5 , wherein the aromatic group is a phenyl group or a naphthyl group.
7. The method according to claim 1 , wherein the second functional layer is a low refractive index layer containing a cured composition of a crosslinking fluorine-containing polymer different from the fluoroaliphatic group-containing copolymer.