Liquid-crystal polyester resin
The present invention provides a liquid-crystalline polyester resin, essentially consisting of the repeating units represented by formulae [I]-[IV]: wherein p, q, r and s satisfy the following formulae: 0.4≦p/q≦2.0, 2≦r≦15, 2≦s≦15, and p+q+r+s=100, provided that the liquid-crystalline polyester resin has a melting point of 190-250° C. determined by differential scanning calorimetry. The liquid-crystalline polyester resin of the present invention exhibits a good molding processability at low temperatures and excellent mechanical properties.
1 . A liquid-crystalline polyester resin, essentially consisting of the repeating units represented by formulae [I]-[IV]:
wherein Ar 1 and Ar 2 independently represent one or more bivalent aromatic group;
p, q, r and s represent relative molar proportions (mol %) of the repeating units based on the total repeating units represented by formulae [I]-[IV] in the liquid-crystalline polyester resin and satisfy the following formulae:
0.4≦ p/q≦ 2.0,
2≦r≦15,
2≦s≦15, and
p+q+r+s= 100,
provided that the liquid-crystalline polyester resin has a melting point of 190-205° C. determined by differential scanning calorimetry.
2 . The liquid-crystalline polyester resin according to claim 1 , wherein p, q, r and s satisfy the following formulae:
35≦p≦48,
35≦q≦48,
2≦r≦15,
2≦s≦15, and
p+q+r+s= 100.
3 . The liquid-crystalline polyester resin according to claim 1 , wherein:
Ar 1 represents:
Ar 2 represents:
4 . The liquid-crystalline polyester resin according to claim 1 , wherein both Ar 1 and Ar 2 represent:
5 . A liquid-crystalline polyester resin composition comprising 100 parts by weight of the liquid-crystalline polyester resin according to claim 1 and 0.1-200 parts by weight of one or more of fibrous, plate or particulate filler and/or reinforcement.
6 . A molded article obtained by molding the liquid-crystalline polyester resin or the liquid-crystalline polyester resin composition according to claim 1 .
7 . The liquid-crystalline polyester resin according to claim 2 , wherein:
Ar 1 represents:
Ar 2 represents:
8 . The liquid-crystalline polyester resin according to claim 2 , wherein both Ar 1 and Ar 2 represent: