Fungicidal mixtures based on carbamate derivatives and insecticides
The present invention relates to mixtures comprising as active components a) carbamate derivatives of the formula (I) in which the substituents and the index have the following meaning: T is CH or N n is 0, 1 or 2 R is halogen, C 1 -C 4 -alkyl or C 1 -C 4 -haloalkyl, it being possible for the radicals R to be different when n is 2, and b) at least one compound of the formula (II).
1. A mixture for crop protection, comprising as active components
a) carbamate derivatives of the formula I
in which the substituents and the index have the following meaning:
T is CH or N;
n is 0, 1 or 2; and
each R is independently halogen, C 1 -C 4 -alkyl or C 1 -C 4 -haloalkyl, it being possible for the radicals R to be different when n is 2,
and
b) at least one compound of the formulae II
in which R 1 is C 1 -C 4 -alkyl or C 1 -C 4 -haloalkyl.
2. A mixture as claimed in claim 1 , wherein R 1 is trifluoromethyl.
3. A mixture as claimed in claim 1 , wherein R 1 is ethyl.
4. A mixture as claimed in claim 1 , further comprising a fungicide.
5. A mixture as claimed in claim 4 , wherein the fungicide is metalaxyl, triticonazole, carbetazin, boscalid or thiophanate-methyl.
6. A mixture as claimed in claim 1 , wherein the weight ratio of the compound of formula I to compound of formula II is from 100:1 to 1:100.
7. A mixture as claimed in claim 4 , wherein the weight ratio of the compounds of formula I to the fungicide is from 1000:1 to 1:1000.
8. A composition comprising a solid or liquid carrier and a mixture comprising:
a) carbamate derivatives of the formula I
in which the substituents and the index have the following meaning:
T is CH or N;
n is 0, 1 or 2; and
each R is independently halogen, C 1 -C 4 -alkyl or C 1 -C 4 -haloalkyl, it being possible for the radicals R to be different when n is 2,
and
b) at least one compound of the formulae II
in which R 1 is C 1 -C 4 -alkyl or C 1 -C 4 -haloalkyl.
9. A method for controlling phytopathogenic harmful fungi, which comprises treating the harmful fungi, their habitat or the plants, seeds, soils, areas, materials or spaces to be kept free from them with a mixture as set forth in claim 1 .
10. The method as claimed in claim 9 , wherein the mixture is applied in an amount of from 5 g/ha to 2,000 g/ha.
11. The method as claimed in claim 9 , wherein the mixture is applied in an amount of from 1 to 1,000 g/100 kg of seed.
12. A method for controlling harmful insects, which comprises treating an insect, arachnid or nematode or their food supply, habitat or breeding grounds with a mixture as set forth in claim 1 .
13. The method as claimed in claim 12 , wherein the mixture is applied in an amount of from 5 g/ha to 2,000 g/ha.
14. The method as claimed in claim 12 , wherein the mixture is applied in an amount of from 1 to 1,000 g/100 kg of seed.
15. A method for controlling phytopathogenic harmful fungi and harmful insects, which comprises treating the harmful fungi, their habitat or the plants, seeds, soils, areas, materials or spaces to be kept free from them or the insect or nematode or their food supply, habitat or breeding grounds with a mixture as set forth in claim 1 .
16. The method as claimed in claim 15 , wherein the mixture is applied in an amount of from 5 g/ha to 2,000 g/ha.
17. The method as claimed in claim 15 , wherein the mixture is applied in an amount of from 1 to 1,000 g/100 kg of seed.
18. A method for controlling phytopathogenic harmful fungi, which comprises treating the harmful fungi, their habitat or the plants, seeds, soils, areas, materials or spaces to be kept free from them with a composition as set forth in claim 8 .
19. The method as claimed in claim 18 , wherein the composition is applied in an amount of from 5 g/ha to 2,000 g/ha.
20. The method as claimed in claim 18 , wherein the composition is applied in an amount of from 1 to 1,000 g/100 kg of seed.
21. A method for controlling harmful insects, which comprises treating an insect, arachnid or nematode or their food supply, habitat or breeding grounds with a composition as set forth in claim 8 .
22. The method as claimed in claim 21 , wherein the composition is applied in an amount of from 5 g/ha to 2,000 g/ha.
23. The method as claimed in claim 21 , wherein the composition is applied in an amount of from 1 to 1,000 g/100 kg of seed.
24. A method for controlling phytopathogenic harmful fungi and harmful insects, which comprises treating the harmful fungi, their habitat or the plants, seeds, soils, areas, materials or spaces to be kept free from them or the insect or nematode or their food supply, habitat or breeding grounds with a composition as set forth in claim 8 .
25. The method as claimed in claim 24 , wherein the composition is applied in an amount of from 5 g/ha to 2,000 g/ha.
26. The method as claimed in claim 24 , wherein the composition is applied in an amount of from 1 to 1,000 g/100 kg of seed.