Micro-reactor and method of manufacturing the same
A structure of a microreactor includes a joined body having a pair of substrates joined together, a flow path formed by a microchannel portion formed on a joining surface of at least one of the substrates, and a catalyst carrying member disposed in the flow path. In the production of such a microreactor, the catalyst carrying member is produced separately from formation of the joined body and the catalyst carrying member is disposed in the flow path at the time of forming the joined body.
1. A microreactor for producing hydrogen by reforming a feed material, comprising:
a joined body including a first substrate and a second substrate that are joined together;
a flow path formed by a microchannel portion formed on a joining surface of at least one of said first or second substrates; and
a catalyst carrying member disposed in said flow path and including a reforming catalyst,
wherein said reforming catalyst is supported independent of wall surfaces of said microchannel portion that define said flow path so as to be suspended in the microchannel portion, free of contact with the wall surfaces,
wherein the catalyst carrying member is wire shaped, and
wherein said wall surfaces of said microchannel portion that define said flow path are free of any film or catalyst.
2. A microreactor according to claim 1 , wherein said catalyst carrying member comprises a metal base body, a metal oxide film covering said metal base body, and said reforming catalyst supported on said metal oxide film.
3. A microreactor according to claim 2 , wherein said metal oxide film is formed by anodic oxidation of said metal base body.
4. A microreactor according to claim 2 , wherein said metal oxide film is formed by a boehmite treatment.
5. A microreactor according to claim 2 , wherein said metal base body is circular in section.
6. A microreactor according to claim 1 , wherein at least one of said first or second substrates of said joined body is provided with a heater.
7. A microreactor according to claim 6 , wherein said heater is provided on said substrate via an insulating layer.
8. A microreactor according to claim 1 , wherein said catalyst carrying member comprises an electric heater, a metal oxide film covering said electric heater, and said reforming catalyst supported on said metal oxide film.
9. A microreactor according to claim 8 , wherein said metal oxide film is formed by a boehmite treatment.
10. A microreactor according to claim 1 , wherein said catalyst carrying member comprises an electric heater, a metal film covering said electric heater, a metal oxide film covering said metal film, and said reforming catalyst supported on said metal oxide film.
11. A microreactor according to claim 10 , wherein said metal oxide film is formed by anodic oxidation of said metal film.
12. A microreactor according to claim 10 , wherein said metal oxide film is formed by a boehmite treatment.
13. A microreactor for producing hydrogen by reforming a feed material, comprising:
a joined body including a first substrate and a second substrate that are joined together;
a flow path formed by a microchannel portion formed on a joining surface of at least one of said first or second substrates;
a catalyst carrying member disposed in said flow path and including a reforming catalyst, said reforming catalyst is supported independent of wall surfaces of said microchannel portion that define said flow path so as to be suspended in the microchannel portion, free of contact with the wall surfaces;
wherein said catalyst carrying member comprises a metal base body, a metal oxide film covering said metal base body, and said catalyst supported on said metal oxide film,
wherein said metal body includes a wavelike plate shape in section, and
wherein said wall surfaces of said microchannel portion that define said flow path are free from any film or catalyst.