IP Library Granted Patent US 6,972,302
Granted Patent B2
US 6,972,302 · App. 10/653,363 · Granted Dec 6, 2005

Casting sand cores and expansion control methods therefor

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Quick Facts
Patent No.
US 6,972,302
App. No.
10/653,363
Granted
Dec 6, 2005
Kind
B2
Abstract

Thermal expansion of sand cores and the formation of vein defects during metal casting operations can be substantially eliminated, with substantially reduced costs, by using an anti-veining material comprising less than about 4% by weight of a lithia-containing material, and at least about 1% by weight of ferric oxide (Fe 2 O 3 ), said anti-veining material preferably comprising 2.5% Li 2 O, 10–25% of TiO 2 , 15–25% Al 2 O 3 , 10–25% of Fe 3 O 4 , and 60–70% of SiO 2 mixed with about 1% by weight of Fe 2 O 3 , preferably red iron oxide.

Claims (15)

1. A method of making a sand core for casting, comprising uniformly mixing together a core sand, an effective amount of binder, about 1% to about 3.5% by weight of a lithia-containing material including 2–5% of Li 2 O, 10–25% of TiO 2 , 15–25% of Al 2 O 3 , 10–20% of Fe 3 O 4 , and 60–70% of SiO2, and about 1% by weight of Fe 2 O 3 as a core-forming material, and forming the core-forming material into a sand core.

2. The method of claim 1 wherein the amount of Fe 2 O 3 comprises about 1% by weight of red iron oxide.

3. The method of claim 2 comprising about 2.5% by weight of the lithia-containing material and wherein the core sand comprises a silica sand.

4. The method of claim 1 comprising equal amounts by weight of the lithia-containing material and Fe 2 O 3 , and wherein the core sand comprises lake sand.

5. The method of claim 1 wherein the core-forming material contains about 1% by weight of a lithia-containing material.

6. The method of claim 1 wherein the step of uniformly mixing comprises 2% by weight of said lithia-containing material.

7. A method of making a sand core for casting, comprising uniformly mixing together a core sand, an effective amount of core sand binder, an anti-veining material comprising less than 4% by weight of a lithia-containing material comprising 2–5% of Li 2 O, 10–25% of TiO 2 , 15–25% of Al 2 O 3 , 10–20% of Fe 3 O 4 , and 60–70% of SiO2, and about 1% or more by weight of Fe 2 O 3 as a core-forming mixture, and thereafter forming the core-forming mixture into a sand core.

8. The method of claim 7 wherein the amount of Fe 2 O 3 comprises about 1% by weight of red iron oxide.

9. The method of claim 8 wherein the lithia-containing material comprises about 1% by weight and wherein the core sand comprises lake sand.

10. The method of claim 7 wherein the lithia-containing material comprises about 1% to about 2.5% by weight.

11. The method of claim 10 wherein the lithia-containing material comprises about 2.5% by weight, and wherein the core sand comprises a silica sand.

12. The method of claim 7 comprising about 2% by weight of lithia-containing material and about 1.5% by weight of iron oxide (Fe 2 O 3 ).

13. The method of claim 7 wherein the lithia-containing materials is selected from a group consisting of .α.-spodumene, amblygonite, montebrasite, petalite, lepidolite, zinnwaldite, eucryptite and lithium carbonate.

14. The method of claim 7 wherein the Fe 2 O 3 comprises red iron oxide.

15. In a method of making a sand core for casting, comprising uniformly mixing together a core sand, an effective amount of core sand binder and an anti-veining material, and thereafter forming from the resulting mixture a sand core, the improvement wherein the anti-veining material comprises about 1% to about 3.5% by weight of a mixture including 2–5% of Li 2 O, 10–25% of TiO 2 , 15–25% of Al 2 O 3 , 10–25% of Fe 3 O 4 , and 60–70% of SiO 2 , and about 1.5% by weight of red iron oxide (Fe 2 O 3 ).

Assignments (9)
RELEASE OF SECURITY INTEREST RECORDED AT REEL/FRAME 53545/443 Recorded Jul 15, 2021
From: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A.
To: NAVISTAR INTERNATIONAL CORPORATION; INTERNATIONAL TRUCK INTELLECTUAL PROPERTY COMPANY, LLC; INTERNATIONAL ENGINE INTELLECTUAL PROPERTY COMPANY, LLC; NAVISTAR, INC.
Reel/Frame 057441/0404 →
RELEASE OF SECURITY INTEREST Recorded Jul 2, 2021
From: JPMORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT
To: INTERNATIONAL ENGINE INTELLECTUAL PROPERTY COMPANY, LLC; NAVISTAR, INC. (F/KA/ INTERNATIONAL TRUCK AND ENGINE CORPORATION); INTERNATIONAL TRUCK INTELLECTUAL PROPERTY COMPANY, LLC
Reel/Frame 056757/0136 →
SECURITY INTEREST Recorded Apr 27, 2020
From: NAVISTAR INTERNATIONAL CORPORATION; INTERNATIONAL ENGINE INTELLECTUAL PROPERTY COMPANY, LLC; INTERNATIONAL TRUCK INTELLECTUAL PROPERTY COMPANY, LLC; NAVISTAR, INC. (F/K/A INTERNATIONAL TRUCK AND ENGINE CORPORATION)
To: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A., AS COLLATERAL AGENT
Reel/Frame 053545/0443 →
CORRECTIVE ASSIGNMENT TO CORRECT THE CONVEYING PARTY DATA PREVIOUSLY RECORDED AT REEL: 052483 FRAME: 0742. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY INTEREST.. Recorded Apr 27, 2020
From: NAVISTAR INTERNATIONAL CORPORATION; INTERNATIONAL ENGINE INTELLECTUAL PROPERTY COMPANY, LLC; INTERNATIONAL TRUCK INTELLECTUAL PROPERTY COMPANY, LLC; NAVISTAR, INC. (F/K/A INTERNATIONAL TRUCK AND ENGINE CORPORATION)
To: JPMORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 053457/0001 →
SECURITY INTEREST Recorded Apr 23, 2020
From: INTERNATIONAL TRUCK INTELLECTUAL PROPERTY COMPANY, LLC; INTERNATIONAL ENGINE INTELLECTUAL PROPERTY COMPANY, LLC; NAVISTAR, INC. (F/K/A INTERNATIONAL TRUCK AND ENGINE CORPORATION)
To: JPMORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 052483/0742 →
RELEASE OF SECURITY INTEREST Recorded Nov 10, 2017
From: JPMORGAN CHASE BANK, N.A., AS COLLATERAL AGENT
To: INTERNATIONAL ENGINE INTELLECTUAL PROPERTY COMPANY, LLC; INTERNATIONAL TRUCK INTELLECTUAL PROPERTY COMPANY, LLC; NAVISTAR, INC.; NAVISTAR INTERNATIONAL CORPORATION
Reel/Frame 044416/0867 →
SECURITY INTEREST Recorded Nov 10, 2017
From: NAVISTAR INTERNATIONAL CORPORATION; NAVISTAR, INC.
To: JPMORGAN CHASE BANK, N.A., AS COLLATERAL AGENT
Reel/Frame 044418/0310 →
RELEASE OF SECURITY INTEREST Recorded Nov 10, 2017
From: JPMORGAN CHASE BANK, N.A., AS COLLATERAL AGENT
To: NAVISTAR INTERNATIONAL CORPORATION; INTERNATIONAL TRUCK INTELLECTUAL PROPERTY COMPANY, LLC; INTERNATIONAL ENGINE INTELLECTUAL PROPERTY COMPANY, LLC
Reel/Frame 044780/0456 →
SECURITY AGREEMENT Recorded Sep 15, 2015
From: NAVISTAR INTERNATIONAL CORPORATION; INTERNATIONAL TRUCK INTELLECTUAL PROPERTY COMPANY, LLC; INTERNATIONAL ENGINE INTELLECTUAL PROPERTY COMPANY, LLC
To: JPMORGAN CHASE BANK N.A., AS COLLATERAL AGENT
Reel/Frame 036616/0243 →