IP Library Granted Patent US 7,328,805
Granted Patent B2
US 7,328,805 · App. 10/657,730 · Granted Feb 12, 2008

Method and system for beneficiating gasification slag

Assignee: Charah Enviromental, Inc.
View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 7,328,805
App. No.
10/657,730
Granted
Feb 12, 2008
Kind
B2
Abstract

The present invention provides a method of beneficiating slag, including mixing the slag with water to form a slurry. The slurry is screened through a first screen to remove a first portion of material and then screened through a second screen to remove a second portion of material. In one embodiment, the second portion of material has a carbon content less than about 5% and, more preferably, a carbon content less than about 1%.

Claims (104)

1. A method for beneficiating slag from coal gasification, comprising:

mixing the slag from coal gasification with water to form a slurry;

screening the slurry through a substantially planar first screen to remove a first portion of material, wherein the first portion of material has a particle size exceeding approximately 0.5 inches;

screening the slurry subsequent to said first screening step through a substantially planar second screen to remove a second portion of material, wherein the second portion of material has a particle size of between approximately 0.5 inches and approximately 840 μm; and

wherein the second portion of material has a carbon content less than about 5%.

2. A method according to claim 1 wherein the second portion of material has a carbon content less than about 1%.

3. A method according to claim 1 further comprising dewatering a slurry prior to said mixing step.

4. A method according to claim 1 wherein said mixing step comprises agitating the slurry.

5. A method according to claim 1 further comprising spraying a fluid onto at least one of the first and second screens concurrently with said corresponding first and second screening steps.

6. A method according to claim 1 further comprising vibrating at least one of the first and second screens concurrently with said corresponding first and second screening steps.

7. A method according to claim 1 further comprising screening the slurry subsequent to said second screening step through a centrifuge to remove a third portion of material.

8. A method according to claim 7 wherein the third portion of material has a particle size of between approximately 840 μm and approximately 45 μm.

9. A method according to claim 7 further comprising using the third portion of material as at least one of a carbon-based combustible fuel and an adsorbent carbon.

10. A method according to claim 7 further comprising thickening the slurry subsequent to said third screening step using an anionic flocculant selected from the group consisting of polyacrylamide and acrylamide copolymers to thereby remove a fourth portion of material from the slurry.

11. A method according to claim 10 further comprising using a pH modifier selected from the group consisting of sodium hydroxide and ammonium hydroxide to clarify the water.

12. A method according to claim 10 wherein the fourth portion of material has a particle size of less than approximately 45 μm.

13. A method according to claim 10 further comprising processing the fourth portion of material using a belt filtering press.

14. A method according to claim 13 further comprising using the processed fourth portion of material as a carbon-based combustible fuel.

15. A method according to claim 1 further comprising screening the slurry subsequent to said second screening step using a hydrocyclone to remove a third portion of material from the slurry.

16. A method according to claim 15 wherein the third portion of material has a particle size of between approximately 840 νm to approximately 75 νm.

17. A method according to claim 15 further comprising dewatering the third portion of material subsequent to said third screening step using a centrifuge.

18. A method according to claim 15 further comprising using the third portion of material as at least one of an absorbent carbon and fuel product.

19. A method according to claim 15 further comprising thickening the slurry subsequent to said third screening step using an anionic flocculant selected from the group consisting of polyacrylamide and acrylamide copolymers to thereby remove a fourth portion of material from the slurry.

20. A method according to claim 19 wherein the fourth portion of material has a particle size of less than approximately 75 νm.

21. A method according to claim 19 further comprising using a pH modifier selected from the group consisting of sodium hydroxide and ammonium hydroxide to clarify the water.

22. A method according to claim 19 further comprising processing the fourth portion of material using a belt filtering press.

23. A method according to claim 22 further comprising using the processed fourth portion of material as a fuel product.

24. A method for beneficiating slag from coal gasification, comprising:

mixing the slag from coal gasification with water to form a slurry;

screening the slurry through a substantially planar first screen to remove a first portion of material, wherein the first portion of material has a particle size exceeding approximately 0.5 inches;

screening the slurry subsequent to said first screening step through a substantially planar second screen to remove a second portion of material, wherein the second portion of material has a particle size of between approximately 0.5 inches and approximately 840 μm;

screening the slurry subsequent to said second screening step through a centrifuge to remove a third portion of material, wherein the third portion of material has a particle size of between approximately 840 μm and approximately 45 μm; and

wherein the second portion of material has a lower carbon content than the third portion of material.

25. A method according to claim 24 wherein the second portion of material has a carbon content less than about 5%.

26. A method according to claim 24 further comprising dewatering a slurry prior to said mixing step.

27. A method according to claim 24 wherein said mixing step comprises agitating the slurry.

28. A method according to claim 24 further comprising spraying a fluid onto at least one of the first and second screens concurrently with said corresponding first and second screening steps.

29. A method according to claim 24 further comprising vibrating at least one of the first and second screens concurrently with said corresponding first and second screening steps.

30. A method according to claim 24 further comprising using the third portion of material as at least one of a carbon-based combustible fuel and an adsorbent carbon.

31. A method according to claim 24 further comprising thickening the slurry subsequent to said third screening step using an anionic flocculant selected from the group consisting of polyacrylamide and acrylamide copolymers to thereby remove a fourth portion of material from the slurry.

32. A method according to claim 31 further comprising using a pH modifier selected from the group consisting of sodium hydroxide and sodium hydroxide to clarify the water.

33. A method according to claim 31 wherein the fourth portion of material has a particle size less than approximately 45 μm.

34. A method according to claim 31 further comprising processing the fourth portion of material using a belt filtering press.

35. A method according to claim 34 further comprising using the processed fourth portion of material as at least one of a carbon-based combustible fuel and a adsorbent carbon.

36. A method for beneficiating slag, comprising:

mixing the slag with water to form a slurry;

screening the slurry through a first screen to remove a first portion of material;

screening the slurry subsequent to said first screening step through a second screen to remove a second portion of material;

screening the slurry subsequent to said second screening step using a hydrocyclone to remove a third portion of material from the slurry; and

wherein the second portion of material has a lower carbon content than the third portion of material.

37. A method according to claim 36 , wherein the second portion of material has a carbon content less than about 5%.

38. A method according to claim 36 further comprising dewatering a slurry prior to said mixing step.

39. A method according to claim 36 wherein said mixing step comprises agitating the slurry.

40. A method according to claim 36 further comprising spraying a fluid onto at least one of the first and second screens concurrently with said corresponding first and second screening steps.

41. A method according to claim 36 further comprising vibrating at least one of the first and second screens concurrently with said corresponding first and second screening steps.

42. A method according to claim 36 further comprising dewatering the third portion of material subsequent to said third screening step using a centrifuge.

43. A method according to claim 36 further comprising using the third portion of material as at least one of an adsorbent carbon and a fuel product.

44. A method according to claim 36 further comprising thickening the slurry subsequent to said fourth screening step using an anionic flocculant selected from the group consisting of polyacrylamide and acrylamide copolymers to thereby remove a fourth portion of material from the slurry.

45. A method according to claim 44 wherein the fourth portion of material has a particle size of less than approximately 75 νm.

46. A method according to claim 44 further comprising using a pH modifier selected from the group consisting of sodium hydroxide and ammonium hydroxide to clarify the water.

47. A method according to claim 44 further comprising processing the fourth portion of material using a belt filtering press.

48. A method according to claim 47 further comprising using the processed fourth portion of material as at least one of a fuel product or adsorbent carbon.

49. A system for beneficiating a slag slurry comprising slag from coal gasification into usable portions, comprising:

a substantially planar first screen for removing a first portion of material from the slurry, wherein the slurry comprises slag from coal gasification and wherein the first portion of material has a particle size exceeding approximately 0.5 inches;

a substantially planar second screen for removing a second portion of material from the slurry, wherein the second portion of material has a particle size of between approximately 0.5 inches and approximately 840 μm; and

wherein the second portion of material has a carbon content of less than about 5%.

50. A system according to claim 49 wherein the second portion of material has a carbon content less than about 1%.

51. A system according to claim 49 further comprising a blunger for agitating the slurry.

52. A system according to claim 49 further comprising at least one sprayer for spraying fluid onto at least one of the first and second screens.

53. A system according to claim 49 further comprising at least one vibrator for vibrating at least one of said first and second screens.

54. A system according to claim 49 further comprising a centrifuge for removing a third portion of material from the slurry.

55. A system according to claim 54 wherein the third portion of material has a particle size of between approximately 840 μm to approximately 45 μm.

56. A system according to claim 49 further comprising a thickener for removing a fourth portion of material from the slurry.

57. A system according to claim 56 further comprising a belt filtering press for dewatering the fourth portion of material.

58. A system according to claim 49 further comprising a hydrocyclone for removing a third portion of material from the slurry.

59. A system according to claim 58 wherein the third portion of material has a particle size of between approximately 840 νm to approximately 75 νm.

60. A system according to claim 58 further comprising a centrifuge for dewatering the third portion of material.

61. A system according to claim 58 further comprising a thickener for removing a fourth portion of material from the slurry.

62. A system according to claim 61 further comprising a belt filtering press for dewatering the fourth portion of material.

63. A system for beneficiating a slag slurry comprising slag from coal gasification into usable portions, comprising:

a substantially planar first screen for removing a first portion of material from the slurry, wherein the slurry comprises slag from coal gasification and wherein the first portion of material has a particle size exceeding approximately 0.5 inches;

a substantially planar second screen for removing a second portion of material from the slurry, wherein the second portion of material has a particle size of between approximately 0.5 inches and approximately 840 μm;

a centrifuge for removing a third portion of material from the slurry; and

wherein the second portion of material has a lower carbon content than the third portion of material.

64. A system according to claim 63 wherein the second portion of material has a carbon content less than about 5%.

65. A system according to claim 63 further comprising a blunger for agitating the slurry.

66. A system according to claim 63 further comprising at least one sprayer for spraying fluid onto at least one of the first and second screens.

67. A system according to claim 63 further comprising at least one vibrator for vibrating at least one of said first and second screens.

68. A system according to claim 63 wherein the third portion of material has a particle size of between approximately 840 μm and approximately 45 μm.

69. A system according to claim 63 further comprising a thickener for removing a fourth portion of material from the slurry.

70. A system according to claim 69 further comprising a belt filtering press for dewatering the fourth portion of material.

71. A system for beneficiating a slag slurry into usable portions, comprising:

a first screen for removing a first portion of material from the slurry;

a second screen for removing a second portion of material from the slurry;

a hydrocyclone for removing a third portion of material from the slurry; and

wherein the second portion of material has a lower carbon content than the third portion of material.

72. A system according to claim 71 wherein the second portion of material has a carbon content less than about 5%.

73. A system according to claim 71 further comprising a blunger for agitating the slurry.

74. A system according to claim 71 further comprising at least one sprayer fluid onto at least one of the first and second screens.

75. A system according to claim 71 further comprising at least one vibrator for vibrating at least one of said first and second screens.

76. A system according to claim 71 wherein the third portion of material has a particle size between approximately 840 νm to approximately 75 νm.

77. A system according to claim 71 further comprising a centrifuge for dewatering the third portion of material.

78. A system according to claim 71 further comprising a thickness for removing a fourth portion of material from the slurry.

79. A system according to claim 78 further comprising a belt filtering press for dewatering the fourth portion of material.

Assignments (14)
RELEASE OF SECURITY INTEREST Recorded Apr 25, 2024
From: JPMORGAN CHASE BANK, N.A.
To: CHARAH, LLC; SCB INTERNATIONAL HOLDINGS, LLC; MERCURY CAPTURE INTELLECTUAL PROPERTY, LLC
Reel/Frame 067219/0039 →
SECURITY INTEREST Recorded Apr 25, 2024
From: CHARAH, LLC; SCB INTERNATIONAL HOLDINGS, LLC; MERCURY CAPTURE INTELLECTUAL PROPERTY, LLC
To: SIENA LENDING GROUP LLC
Reel/Frame 067218/0735 →
SECURITY INTEREST Recorded Nov 9, 2021
From: CHARAH, LLC; SCB INTERNATIONAL HOLDINGS, LLC; MERCURY CAPTURE INTELLECTUAL PROPERTY, LLC
To: JPMORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 058066/0164 →
RELEASE OF SECURITY INTEREST Recorded Aug 27, 2021
From: BANK OF AMERICA, N.A.
To: CHARAH, LLC
Reel/Frame 057312/0950 →
RELEASE OF SECURITY INTEREST Recorded Sep 24, 2018
From: REGIONS BANK
To: CHARAH, LLC
Reel/Frame 046949/0228 →
RELEASE OF SECURITY INTEREST Recorded Sep 24, 2018
From: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH
To: CHARAH, LLC
Reel/Frame 046950/0194 →
SECURITY INTEREST Recorded Sep 21, 2018
From: CHARAH, LLC
To: BANK OF AMERICA, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 046938/0888 →
RELEASE OF SECURITY INTEREST Recorded Oct 25, 2017
From: BANK OF AMERICA, N.A.
To: CHARAH, LLC (FORMERLY KNOWN AS CHARAH, INC.)
Reel/Frame 043951/0314 →
SECURITY INTEREST Recorded Oct 25, 2017
From: CHARAH, LLC
To: REGIONS BANK
Reel/Frame 043950/0656 →
PATENT SECURITY AGREEMENT Recorded Oct 25, 2017
From: CHARAH, LLC
To: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS COLLATERAL AGENT
Reel/Frame 044292/0938 →
CONVERSION OF ENTITY (INC. TO LLC) AND CHANGE OF NAME Recorded Jan 11, 2017
From: CHARAH, INC.
To: CHARAH, LLC
Reel/Frame 041329/0460 →
CHANGE OF NAME Recorded Dec 15, 2016
From: CHARAH ENVIRONMENTAL, INC.
To: CHARAH, INC.
Reel/Frame 040974/0158 →
SECURITY INTEREST Recorded Jun 30, 2015
From: CHARAH, INC.
To: BANK OF AMERICA, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 035997/0236 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 5, 2004
From: PRICE, CHARLES E.; BARNWELL, WILLIAM LEE; GROPPO JR., JOHN G.
To: CHARAH ENVIRONMENTAL, INC.
Reel/Frame 014309/0411 →
Continuity (1)
Related Publication 20050051500A1 · Mar 10, 2005