Heat-sensitive lithographic printing plate and image forming method
A negative-working CTP plate which is superior in resolution and printing resistance of the image area of a press plate is provided, which is obtained by forming a latent image on a heat-sensitive layer in a heat-sensitive lithographic printing plate comprising a substrate having a hydrophilic surface and a heat-sensitive layer made of an alkali-soluble polymer formed on the surface of the substrate, using heat generated upon irradiation with laser light, and developing the heat-sensitive layer using an alkaline developing solution. In the heat-sensitive lithographic printing plate comprising a substrate having a hydrophilic surface, and a heat-sensitive layer made of an alkali-soluble polymer formed on the surface of the substrate, an advancing contact angle (θ f1 ) of the surface of the heat-sensitive layer with water at 25° C. is within a range from 70° to 110°, a receding contact angle (θ b2 ) of the surface of the heat-sensitive layer with water at 25° C. after heating at 150° C. for 3 minutes is larger than a receding contact angle (θ b1 ) of the surface of the heat-sensitive layer with water at 25° C. before heating, and a difference in receding contact angle before and after heating, (θ b2 −θ b1 ), is larger than 1° and is smaller than 40°.
1. A heat-sensitive lithographic printing plate comprising
a substrate having a hydrophilic surface and
a heat-sensitive layer made of an alkali-soluble polymer formed on the surface of the substrate, wherein
an advancing contact angle (θ f1 ) of the surface of the heat-sensitive layer with water at 25° C. is within a range from 70° to 110°, a receding contact angle (θ b2 ) of the surface of the heat-sensitive layer with water at 25° C. after heating at 150° C. for 3 minutes is larger than a receding contact angle (θ b1 ) of the surface of the heat-sensitive layer with water at 25° C. before heating, and a difference in receding contact angle before and after heating, (θ b2 −θ b1 ), is larger than 1° and is smaller than 40°.
2. The heat-sensitive lithographic printing plate according to claim 1 , wherein the receding contact angle (θ b1 ) is within a range from 5° to 50° and the receding contact angle (θ b2 ) is within a range from 30° to 60°.
3. The heat-sensitive lithographic printing plate according to claim 1 , wherein the alkali-soluble polymer is a copolymer of a monomer having a carboxyl group and a hydrophobic monomer, and the heat-sensitive layer is formed by applying a heat-sensitive composition, which is prepared by dissolving the copolymer in an aqueous alkaline solution, on the surface of the substrate and drying the heat-sensitive composition.
4. The heat-sensitive lithographic printing plate according to claim 3 , wherein the alkali-soluble polymer has an acid value of 40 to 500 and a weight-average molecular weight of 5,000 to 200,000.
5. The heat-sensitive lithographic printing plate according to claim 3 , wherein the monomer having a carboxyl group is acrylic acid or methacrylic acid, and the hydrophobic monomer is at least one type of a monomer selected from the group consisting of styrene, styrene derivatives and methyl methacrylate.
6. The heat-sensitive lithographic printing plate according to claim 3 , wherein the monomer having a carboxyl group is acrylic acid, the hydrophobic monomer is styrene, and a weight ratio of acrylic acid to styrene is within a range from 40:60 to 15:85.
7. The heat-sensitive lithographic printing plate according to claim 3 , wherein the monomer having a carboxyl group is acrylic acid, the hydrophobic monomer is methyl methacrylate, and a weight ratio of acrylic acid to methyl methacrylate is within a range from 14:86 to 5:95.
8. An image forming method, which comprises forming a latent image on a heat-sensitive layer of the heat-sensitive lithographic printing plate of claim 1 using heat generated upon irradiation with laser light, and developing the heat-sensitive layer using an alkaline developing solution of pH 9 to 14.