Impact modified thermoplastic olefin compositions
View Patent ↗The present invention provides impact modified thermoplastic olefin (“TPO”) compositions that exhibit both stiffness and toughness. TPO compositions according to the invention include a polyolefin homopolymer resin such as polypropylene, from about 17% by weight to about 30% by weight of a rubbery copolymer comprising at least one alpha olefin, and from about 1.0% to about 8.0% by weight of a nonionic surfactant, which acts as an impact modifying fluid. The preferred nonionic surfactant for use in the invention is an ethoxylated sorbitan fatty acid ester such as ethoxylated sorbitan trioleate (“ESTO”).
1. An impact modified thermoplastic olefin composition consisting essentially of a blend of one or more polyolefin homopolymer resins, from about 17% by weight to about 30% by weight of one or more rubbery copolymers comprising at least one alpha olefin, from about 1.0% to about 8.0% by weight of one or more nonionic surfactants, and mineral oil or polybutene, provided that the mineral oil or polybutene is present in an amount that does not exceed 8% by weight.
2. The impact modified thermoplastic olefin composition according to claim 1 wherein the polyolefin homopolymer resin is a polypropylene homopolymer.
3. The impact modified thermoplastic olefin composition according to claim 1 wherein the nonionic surfactant is selected from the group consisting of ethoxylated ethers, ethoxylated alkylphenols, ethoxylated aryl phenols and ethoxylated sorbitan fatty acid esters.
4. The impact modified thermoplastic olefin composition according to claim 1 wherein the nonionic surfactant is selected from the group consisting of polyoxyethylene sorbitan monolaurate, polyoxyethylene sorbitan monopalmitate, polyoxyethylene sorbitan monostearate, polyoxyethylene sorbitan tristearate, polyoxyethylene sorbitan monooleate and polyoxyethylene sorbitan trioleate.
5. The impact modified thermoplastic olefin composition according to claim 4 wherein the nonionic surfactant is polyoxyethylene sorbitan trioleate.
6. The impact modified thermoplastic olefin composition according to claim 1 having an instrumented impact strength at −30° C. of 100 in-lbs or greater as measured in accordance with ASTM D 5420 and a flexural modulus of 1.4×10 5 psi or greater as measured in accordance with ASTM D 790.