IP Library Granted Patent US 7,078,785
Granted Patent B2
US 7,078,785 · App. 10/668,694 · Granted Jul 18, 2006

Semiconductor device and making thereof

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Quick Facts
Patent No.
US 7,078,785
App. No.
10/668,694
Granted
Jul 18, 2006
Kind
B2
Abstract

By forming a conductive smoothing layer over the bottom electrode and/or a capacitor dielectric, a MIM capacitor with improved reliability due to reduction of geometrically enhanced electric fields and electrode smoothing is formed. In one embodiment, layer including a refractory metal or a refractory metal-rich nitride, is formed over a first capping layer formed of a refractory nitride. In addition, a second refractory metal or a refractory metal-rich nitride layer may be formed on the capacitor dielectric. The smoothing layer could also be used in other semiconductor devices, such as transistors between a gate electrode and a gate dielectric.

Claims (38)

1. A semiconductor device comprising:

a semiconductor substrate;

a first electrode formed over the semiconductor substrate;

a first conductive smoothing layer formed over the first electrode, wherein the first conductive smoothing layer has a surface roughness less than that of the first electrode;

a dielectric layer formed on the first conductive smoothing layer;

a second electrode formed over the dielectric layer; and

a second conductive smoothing layer formed between the dielectric layer and the second electrode, wherein the second conductive smoothing layer has a roughness less than that of the second electrode and wherein the second conductive smoothing layer comprises a refractory metal.

2. The semiconductor device of claim 1 , wherein the first electrode comprises a first layer comprising a metal and a second layer comprising a refractory nitride and the second electrode comprises a metal.

3. The semiconductor device of claim 1 , wherein the first electrode and the second electrode comprise a refractory nitride.

4. The semiconductor device of claim 3 , wherein the refractory nitride comprises a material selected from the group consisting of titanium nitride and tantalum nitride.

5. The semiconductor device of claim 3 , wherein the first conductive smoothing layer comprises titanium rich nitride.

6. The semiconductor device of claim 1 , wherein the dielectric layer comprises a high dielectric constant material.

7. The semiconductor device of claim 1 , wherein the first electrode, the first conductive smoothing layer, the dielectric layer and the second electrode are part of a metal-insulator-metal (MIM) capacitor.

8. The he semiconductor device of claim 7 , further comprising:

a capping layer over the first electrode, wherein the capping layer comprises a refractory nitride and the first electrode comprises a metal.

9. A semiconductor device comprising:

a conductive layer;

a smoothing layer formed in contact with the conductive layer, wherein the smoothing layer has a surface roughness less than that of the conductive layer and the smoothing layer comprises titanium rich nitride; and

a dielectric layer formed above and in contact with the smoothing layer.

10. The semiconductor device of claim 9 , wherein the conductive layer comprises titanium nitride and the smoothing layer comprises titanium.

11. The semiconductor device of claim 9 , wherein the conductive layer, the smoothing layer and the dielectric layer are part of a device selected from the group consisting of a transistor and a capacitor.

12. The semiconductor device of claim 9 , wherein the conductive layer comprises a first layer comprising a metal and a second layer comprising a refractory nitride.

13. The semiconductor device of claim 9 , wherein the dielectric layer is a high dielectric constant material.

14. A semiconductor device comprising:

a semiconductor substrate;

a first electrode formed over the semiconductor substrate, wherein the first electrode comprises a first layer comprising metal and a second layer over the first layer, wherein the second layer comprises a refractory nitride;

a first smoothing layer formed over the first electrode, wherein the first smoothing layer comprises titanium rich nitride;

a dielectric layer formed on the first smoothing layer; and

a second electrode formed over the dielectric layer, wherein the second electrode comprises a third layer comprising a refractory nitride and a fourth layer over the third layer, wherein the fourth layer comprises a metal.

15. The semiconductor device of claim 14 , wherein the refractory nitride comprises a material selected from the group consisting of titanium nitride and tantalum nitride.

16. The semiconductor device of claim 15 , wherein the refractory metal comprises titanium.

17. A semiconductor device comprising:

a semiconductor substrate;

a first electrode formed over the semiconductor substrate;

a capping layer over the first electrode, wherein the capping layer comprises a refractory nitride and the first electrode comprises a metal;

a first conductive smoothing layer formed over the capping layer, wherein the first conductive smoothing layer has a surface roughness less than that of the capping layer;

a dielectric layer formed on the first conductive smoothing layer; and

a second electrode formed over the dielectric layer.

Assignments (14)
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 040925 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE RELEASE OF SECURITY INTEREST. Recorded Feb 17, 2020
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP, B.V. F/K/A FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 052917/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 040928 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE RELEASE OF SECURITY INTEREST. Recorded Jan 17, 2020
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 052915/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 037486 FRAME 0517. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS. Recorded Dec 10, 2019
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 053547/0421 →
CORRECTIVE ASSIGNMENT TO CORRECT THE TO CORRECT THE APPLICATION NO. FROM 13,883,290 TO 13,833,290 PREVIOUSLY RECORDED ON REEL 041703 FRAME 0536. ASSIGNOR(S) HEREBY CONFIRMS THE THE ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS.. Recorded Feb 20, 2019
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: SHENZHEN XINGUODU TECHNOLOGY CO., LTD.
Reel/Frame 048734/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE PATENTS 8108266 AND 8062324 AND REPLACE THEM WITH 6108266 AND 8060324 PREVIOUSLY RECORDED ON REEL 037518 FRAME 0292. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS. Recorded Feb 1, 2017
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 041703/0536 →
RELEASE OF SECURITY INTEREST Recorded Nov 7, 2016
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 040928/0001 →
RELEASE OF SECURITY INTEREST Recorded Sep 21, 2016
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP, B.V., F/K/A FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 040925/0001 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 4, 2016
From: FREESCALE SEMICONDUCTOR, INC.
To: NORTH STAR INNOVATIONS INC.
Reel/Frame 037694/0264 →
ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS Recorded Jan 13, 2016
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 037518/0292 →
ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS Recorded Jan 12, 2016
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 037486/0517 →
PATENT RELEASE Recorded Dec 21, 2015
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 037354/0225 →
PATENT RELEASE Recorded Dec 21, 2015
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 037356/0143 →
PATENT RELEASE Recorded Dec 21, 2015
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 037356/0553 →
SECURITY AGREEMENT Recorded Nov 6, 2013
From: FREESCALE SEMICONDUCTOR, INC.
To: CITIBANK, N.A., AS NOTES COLLATERAL AGENT
Reel/Frame 031591/0266 →