Method and apparatus for dry-etching half-tone phase-shift films, half-tone phase-shift photomasks and method for the preparation thereof, and semiconductor circuits and method for the fabrication thereof
View Patent ↗A chromium-containing half-tone phase-shift photomask comprising coarse and dense patterns coexisting in a plane is prepared by a series of pattern-forming steps including forming a resist layer on a photomask blank, exposing and patterning said resist layer, developing, etching said photomask blank and removing said resist layer. Patterns for transferring onto a wafer are formed on the photomask blank by a dry-etching method comprising dry-etching a chromium-containing half-tone phase-shift film utilizing etching gas comprised of mixed gas including (a) reactive ion etching gas, containing an oxygen-containing gas and a halogen-containing gas, and (b) reducing gas added to the gas component (a).
1. A chromium-containing half-tone phase-shift photomask comprising coarse and dense patterns coexisting in a plane which is prepared by performing a series of pattern-forming steps including a step for forming a resist layer on a photomask blank, a step for exposing and patterning said resist layer, a developing step, a step for etching said photomask blank and a step for removing said resist layer, wherein the photomask is characterized in that patterns to be transferred onto a wafer are formed on said photomask blank for the chromium-containing half-tone phase-shift photomask according to a dry-etching method comprising dry-etching a chromium-containing half-tone phase-shift film utilizing an etching gas comprised of a mixed gas including (a) a reactive ion etching gas, which contains an oxygen-containing gas and a hydrogen chloride gas, and (b) a reducing gas added to the gas component (a).
2. The chromium-containing half-tone phase-shift photomask of claim 1 wherein said chromium-containing half-tone phase-shift film consists of a chromium film, a chromium oxide film, a chromium nitride film, chromium oxynitride film, chromium fluoride film or a laminated film thereof.
3. A method for preparing the chromium-containing half-tone phase-shift photomask of claim 1 by performing a series of pattern-forming steps comprising a step for forming a resist layer on a photomask blank, a step for exposing and patterning said resist layer, a developing step, a step for etching said photomask blank and a step for removing the resist layer, wherein the method is characterized in that patterns, including coarse and dense portions of the patterns, to be transferred onto a wafer are formed on said photomask blank for the chromium-containing half-tone phase-shift photomask according to a dry-etching method comprising dry-etching a metal thin film as a chromium-containing half-tone phase-shift film, wherein the method is characterized by using, as an etching gas, a mixed gas including (a) a reactive ion etching gas, which contains an oxygen-containing gas and a hydrogen chloride gas, and (b) a reducing gas added to the gas component (a), in the process for dry-etching the metal thin film to thus give a photomask.
4. A method for preparing the chromium-containing half-tone phase-shift photomask of claim 2 by performing a series of pattern-forming steps comprising a step for forming a resist layer on a photomask blank, a step for exposing and patterning said resist layer, a developing step, a step for etching said photomask blank and a step for removing the resist layer, wherein the method is characterized in that patterns, including coarse and dense portions of the patterns, to be transferred onto a wafer are formed on said photomask blank for the chromium-containing half-tone phase-shift photomask according to a dry-etching method comprising dry-etching a metal thin film as a chromium-containing half-tone phase-shift film, wherein the method is characterized by using, as an etching gas, a mixed gas including (a) a reactive ion etching gas, which contains an oxygen-containing gas and a hydrogen chloride gas, and (b) a reducing gas added to the gas component (a), in the process for dry-etching the metal thin film, wherein said metal thin film is a chromium-containing half-tone phase-shift film consisting of a chromium film, a chromium oxide film, a chromium nitride film, chromium oxynitride film, chromium fluoride film or a laminated film thereof to thus give a photomask.