Corrosion resistant PEM fuel cell
View Patent ↗A PEM fuel cell having electrical contact elements comprising a corrosion-susceptible substrate metal coated with an electrically conductive, corrosion-resistant polymer containing a plurality of electrically conductive, corrosion-resistant filler particles. The substrate may have an oxidizable metal first layer (e.g., stainless steel) underlying the polymer coating.
1. In a PEM fuel cell having at least one cell comprising a pair of opposite polarity electrodes, a membrane electrolyte intedacent interjacent said electrodes for conducting ions therebetween, and an electrically conductive contact element having a working face confronting at least one of said electrodessfor electrodes for conducting electrical current from said one electrode, the improvement comprising: said contact element comprising a corrosion-susceptible metal substrate and an electrically conductive, corrosion-resistant protective coating on said face to protect said substrate from the corrosive environment of said fuel cell, said protective coating comprising a mixture of electrically conductive particles dispersed throughout an oxidation-resistant and acid-resistant, water-insoluble polymeric matrix and having a resistivity no greater than about 50 ohm-cm, said mixture comprising graphite particles having a first particle size and other electrically conductive particles selected from the group consisting of gold, platinum, nickel, palladium, rhodium, niobium, titanium carbide, titanium nitride, titanium diboride, chromium-alloyed titanium, nickel-alloyed titanium, rare earth metals and carbon, said other particles having a second particle size less than said first particle size to enhance the packing density of said particles.
2. A fuel cell according to claim 1 wherein said carbon comprises carbon black.
3. A fuel cell according to claim 1 wherein said coating is electrophoretically deposited onto said substrate from a suspension of said particles in an aqueous solution of acid-solubilized polymer.
4. A fuel cell according to claim 1 wherein a discrete film of said coating is laminated onto said substrate to form said electrically conductive contact element.
5. A fuel cell according to claim 1 wherein a precursor of said coating is deposited onto said substrate from a solution thereof, dried and cured to form said coating.
6. A fuel cell according to claim 1 wherein said substrate comprises a first acid-soluble metal underlying a second acid-insoluble, passivating metal layer susceptible to oxidation in said environment.
7. A fuel cell according to claim 1 wherein said polymer matrix is selected from the group consisting of epoxies, silicones, polyamide-imides, polyether-imides, polyphenols, fluro-elastomers, polyesters, phenoxy-phenolics, epoxide-phenolics, acrylics and urethanes.
8. In a PEM fuel cell having at least one cell comprising a pair of opposite polarity electrodes, a membrane electrolyte intedjacent interjacent said electrodes for conducting ions therebetween, and an electrically conductive contact element having a working face confronting at least one of said electrodes for conducting electrical current from said one electrode, the improvement comprising: said contact element comprising a corrosion-susceptible metal substrate and an electrically conductive, corrosion-resistant protective coating on said face to protect said substrate from the corrosive environment of said fuel cell, said protective coating comprising a plurality of electrically conductive particles dispersed throughout an oxidation-resistant and acid-resistant, water-insoluble polymeric matrix and having a resistivity no greater than about 50 ohm-cm, said substrate comprising a first acid-soluble metal underlying a second acid-insoluble, passivating layer susceptible to oxidation in said environment.