Method of surface treatment for manufacturing semiconductor device
View Patent ↗In a semiconductor device formed on a silicon surface which has a substantial (110) crystal plane orientation, the silicon surface is flattened so that an arithmetical mean deviation of surface Ra is not greater than 0.15 nm, preferably, 0.09 nm, which enables to manufacture an n-MOS transistor of a high mobility. Such a flattened silicon surface is obtained by repeating a deposition process of a self-sacrifice oxide film in an oxygen radical atmosphere and a removing process of the self-sacrifice oxide film, by cleaning the silicon surface in deaerated H 2 O or a low OH density atmosphere, or by strongly terminating the silicon surface by hydrogen or heavy hydrogen. The deposition process of the self-sacrifice oxide film may be carried out by isotropic oxidation.
1. A method of manufacturing a semiconductor device, comprising the steps of:
preparing a silicon semiconductor surface which has a predetermined crystal plane orientation;
cleaning the silicon surface with an RCA SC-1 cleaning liquid with a reduced OH concentration; and
forming an oxide film on the cleaned surface by oxidizing the cleaned silicon surface in an atmosphere containing oxygen radicals.
2. A method of manufacturing a semiconductor device, comprising the steps of:
preparing a silicon semiconductor surface which has a (110) plane as a predetermined crystal plane orientation; and
rinsing the silicon surface by the use of H 2 O added with deuterium and by applying high frequency vibration to said H 2 O to terminate silicon at the silicon surface by deuterium.
3. A method as claimed in claim 2 , wherein said high frequency is not less than 500 kHz and the concentration of said deuterium in said H 2 O is 0.1 ppm to 1.6 ppm.
4. A method as claimed in claim 2 , wherein the rinsing step is carried out in an atmosphere of nitrogen, hydrogen, deuterium or mixture of hydrogen and deuterium.
5. A method as claimed in claim 2 , wherein the rinsing step is carried out with the silicon surface being kept isolated from the air.
6. A method of manufacturing a semiconductor device, comprising the steps of:
preparing a silicon semiconductor surface which has a predetermined crystal plane orientation; and
cleaning the silicon surface,
wherein the cleaning step comprises:
a first step of rinsing the silicon surface by using pure water including ozone;
a second step of cleaning the silicon surface by the use of a cleaning solution which includes HF, H 2 O with dissolved oxygen of less than 100 ppb, and surface-active agent, providing a vibration of a frequency not lower than 500 kHz;
a third step of rinsing the silicon surface by the use of H 2 O including ozone;
a fourth step of cleaning the silicon surface by the use of a cleaning solution including HF and H 2 O with dissolved oxygen reduced so as to remove an oxide film; and
a fifth step of rinsing the silicon surface by the use of hydrogen or heavy hydrogen-added H 2 O.
7. A method as claimed in claim 6 , wherein the fifth step is carried out with vibrations of a frequency not lower than 500 kHz, so as to terminate the silicon surface by hydrogen or heavy hydrogen, respectively.
8. A method of manufacturing a semiconductor device, comprising the steps of:
preparing a silicon semiconductor surface which has a predetermined crystal plane orientation; and
cleaning the silicon surface,
wherein the cleaning step comprises:
processing the silicon surface by the use of a cleaning solution containing HF and H 2 O with dissolved oxygen of less than 100 ppb.
9. A method as claimed in claim 8 , wherein the cleaning step comprises the steps of:
preparing a cleaning solution which includes HF, H 2 O with dissolved oxygen of less than 100 ppb and hydrogen of 0.1 ppm to 1.6 ppm; and
providing the cleaning solution with a vibration of a frequency not lower than, 500 kHz.
10. A method as claimed in claim 8 , wherein the cleaning step is carried out without exposing the silicon surface to an air.